Manganese nitrate | 10377-66-9

• 物质功能分类: 无机化工 - 无机盐 - 金属硝酸盐及亚硝酸盐
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: Manganese nitrate
• 英文别名: manganese(2+);dinitrate
• CAS: 10377-66-9
• 化学式: Mn(NO3)2
• 分子量: 178.95
• InChiKey: MIVBAHRSNUNMPP-UHFFFAOYSA-N

物化性质

• 熔点：
  37°C
• 沸点：
  100°C
• 密度：
  1.536 g/mL at 25 °C
• 溶解度：
  极易溶于乙醇
• 暴露限值：
  ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3OSHA: Ceiling 5 mg/m3NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
• 物理描述：
  Manganese nitrate appears as a white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.
• 稳定性/保质期：
  1. 氧化剂。
  2. 加热时会释放二氧化锰并放出氧化氮，有毒！吸入其蒸气同样有害。
  3. 对眼睛、皮肤、黏膜及上呼吸道有刺激性，可引发呼吸道炎症和肺炎。

计算性质

• 辛醇/水分配系数(LogP)：
  -0.48
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  126
• 氢给体数：
  0
• 氢受体数：
  6

ADMET

毒理性

• 副作用

神经毒素 - 帕金森病

Neurotoxin - Parkinsonism

来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

安全信息

• TSCA：
  Yes
• 危险等级：
  5.1
• 危险品标志：
  O,C
• 安全说明：
  S17,S26,S27,S36,S36/37/39,S45
• 危险类别码：
  R36/37/38
• WGK Germany：
  1
• 海关编码：
  28342990
• 危险品运输编号：
  UN 3264 8/PG 3
• 危险类别：
  5.1
• 包装等级：
  III

SDS

Name:	Manganese(II) Nitrate Material Safety Data Sheet
Synonym:
CAS:	10377-66-9

Section 1 - Chemical Product MSDS Name:Manganese(II) Nitrate Material Safety Data Sheet
Synonym:

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
10377-66-9	Manganese(II) Nitrate	100.0	233-828-8

Hazard Symbols: O
Risk Phrases: 8

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Contact with combustible material may cause fire.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects was found.
Skin:
No information regarding skin irritation and other potential effects was found.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully investigated.
Chronic:
Effects may be delayed.

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Oxidizer. Greatly increases the burning rate of combustible materials. May accelerate burning if involved in a fire.
May explode from heat or contamination. Containers may explode when heated.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. Cool containers with flooding quantities of water until well after fire is out. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 10377-66-9: United Kingdom, WEL - TWA: (listed as manganese, inorganic compounds): 0.5 mg/m3 TWA United Kingdom, WEL - STEL: (listed as manganese, inorganic compounds): 1.5 mg/m3 STEL United States OSHA: 5 mg/m3 Ceiling (as Mn) (listed under Mangan compounds, n.o.s.).
Belgium - TWA: (listed as manganese compounds, n.o.s.): 0.2 mg/m3 (as Mn) Japan: (listed as manganese compounds, n.o.s.): 0.3 mg/m3 OEL (ex organic compounds, as Mn) Malaysia: (listed as manganese, inorganic compounds): 0.2 mg/m3 T (as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 3 mg/m3 STE (as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 1 mg/m3 MAC Mn) Spain: (listed as manganese, inorganic compounds): 0.2 mg/m3 VLA- (as Mn) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: N2O6.Mn
Molecular Weight: 124.0098

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials, organic materials, reducing agents, strong acids.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g. butyl acetate, ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), hydrocarbons (aromatic, e.g. benzene, chrysene, cumene, toluene), halogenated organics (e.g. dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other organic sulfides (e.g. butyl mercaptan, carbon disulfide, methanethiol), metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals as powders (e.g. hafnium, raney nickel), metals as non-powders (e.g. brass, bronze, iron), nitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl cyanide), nitro compounds (organic, e.g. nitrobenzene, nitroglycerine, picric acid, trinitrotoluene), hydrocarbons (aliphatic, unsaturated, e.g. cyclopentene, ethylene, heptene), hydrocarbons (aliphatic, saturated, e.g. butane, heptane, isooctane), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), phenols and cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol), organophosphates, phosphothioates (e.g. methylparathion, parathion, phorate, thionazin), sulfides (i.
Hazardous Decomposition Products:
Oxides of nitrogen.
Hazardous Polymerization: Has not been reported.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10377-66-9: QU9780000 LD50/LC50:
Not available.
Carcinogenicity:
Manganese(II) Nitrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: MANGANESE NITRATE
Hazard Class: 5.1
UN Number: 2724
Packing Group: III
IMO
Shipping Name: MANGANESE NITRATE
Hazard Class: 5.1
UN Number: 2724
Packing Group: III
RID/ADR
Shipping Name: MANGANESE NITRATE
Hazard Class: 5.1
UN Number: 2724
Packing group: III

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 10377-66-9: No information available.
Canada
CAS# 10377-66-9 is listed on Canada's DSL List.
CAS# 10377-66-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10377-66-9 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

水中溶解度(g/100ml)

不同温度(℃)时每100毫升水中的溶解克数：

• 0℃: 2g
• 10℃: 18g
• 20℃: 39g
• 30℃: 206g

化学性质

物化液体硝酸锰（50%）为淡红色或玫瑰色透明液体，相对密度1.54 (20°C)，溶于水和醇。加热时析出二氧化锰并释放氧化氮气体；六水硝酸锰为淡玫瑰色针状菱形结晶，熔点25.8°C，沸点129.5°C，密度1.82 (21°C)。它同样溶于水和醇，在160~200°C时分解而形成二氧化锰，并易潮解。

用途

• 用作制二氧化锰的原料
• 也可作为金属磷化剂、陶瓷着色剂及催化剂
• 用于微量分析测定银的试剂及氧化剂
• 也适用于稀土元素的分离和陶瓷工业

类别

• 氧化剂

毒性分级

高毒

急性毒性

腹腔注射 - 小鼠 LD50: 56毫克/公斤

爆炸物危险特性

与还原剂、硫、磷等混合受热、撞击或摩擦可能爆炸

可燃性危险特性

与有机物、还原剂、易燃物硫、磷混合可燃；受热分解产生有毒氧化氮和含锰化物气体

储运特性

应储存在通风良好且低温干燥的库房内，轻装轻卸，并确保与其他有机物、还原剂、硫、磷等易燃物品分开存放

灭火剂

使用雾状水或砂土进行灭火

职业标准

• 时间加权平均容许浓度 (TWA): 5毫克/立方米
• 短时间接触容许浓度 (STEL): 6毫克/立方米（锰）

反应信息

• 作为反应物：
  描述：

  Manganese nitrate 生成 二氧化锰
  参考文献：
  名称：

  BARROW, PETER;WRIGHT, MICHAEL LAWRENCE

  摘要：

  DOI：
• 作为产物：
  描述：

  硝酸 生成 Manganese nitrate
  参考文献：
  名称：

  BREKALOVA, Z. M.;TOROCHESHNIKOV, N. S.;DASHKO, S. P.;GORIZONTOVA, N. I., XIM. TEXNOL. I INZHINIRING PR-V NEORGAN. SOED. JODA, BROMA I MARGANTSA, M+

  摘要：

  DOI：
• 作为试剂：
  描述：

  叔丁基苯 、 氧气 在 Manganese nitrate 吡啶 、 钯(II)丙酸盐 、 uranium acetate 作用下， 以 溶剂黄146 为溶剂， 反应 20.0h， 以tert-Butylstyrene was yielded in a proportion of 1200 %的产率得到β-tert-butylstyrene
  参考文献：
  名称：

  Process for preparing tert-butylstyrene

  摘要：

  TERT-Butylstyrene是通过在金属钯或其脂肪酸盐与吡啶处理后制备的催化剂的存在下，使用叔丁基苯、乙烯和氧的一步反应制备的。通过同时使用由一种或多种金属或氧化物或其脂肪酸盐处理而成的促进剂，其中金属选自铜、镍、锰、铀和铊，可提高产量。反应在50℃至300℃的温度下，在100 kg/cm²的压力下进行。

  公开号：

  US03932549A1

文献信息

• Catalyst for addition polymerization and process for producing an addition polymer
  申请人：——

  公开号：US20030032743A1

  公开（公告）日：2003-02-13

  A catalyst obtained by contacting a specific transition metal compound (A) of Group 7 of the Periodic Table of the Elements, having a pyrazolyl group with an aluminum compound selected from organoaluminums and aluminoxanes and/or a specific boron compound, and a process for producing an addition polymer which comprises polymerizing an addition polymerizable monomer with the catalyst.

  一种催化剂，通过将元素周期表第7族的特定过渡金属化合物(A)中的吡唑基与有机铝化合物和/或特定硼化合物中的铝化合物接触而获得，以及生产加成聚合物的方法，该方法包括使用该催化剂聚合加成聚合可聚合单体。
• Method for producing manganese oxide nanoparticle dispersed material and electrode
  申请人：Taomoto Akira

  公开号：US20080008827A1

  公开（公告）日：2008-01-10

  The present invention provides a method for producing a manganese oxide nanoparticle dispersed material having steps of dissolving manganese nitrate in a polyamide acid solution (Step 1); forming a coating on the surface of the substrate using the polyamide acid solution containing manganese nitrate dissolved therein (Step 2); and carbonizing the polyamide acid and depositing manganese oxide nanoparticles by subjecting the coating to a heat treatment at a temperature not less than 600° C. but not more than 1200° C. (Step 3).

  本发明提供了一种制备锰氧化物纳米颗粒分散材料的方法，其步骤包括：在聚酰胺酸溶液中溶解硝酸锰（步骤1）；使用含有溶解硝酸锰的聚酰胺酸溶液在基底表面形成涂层（步骤2）；并通过在温度不低于600℃但不高于1200℃的热处理下碳化聚酰胺酸并沉积锰氧化物纳米颗粒来处理涂层（步骤3）。
• Process for preparing a positive electrode material for lithium ion battery
  申请人：BYD Company Limited

  公开号：US07887721B2

  公开（公告）日：2011-02-15

  A process for preparing lithium-nickel-manganese-cobalt composite oxide used as a positive electrode material for the lithium ion battery, comprising subjecting a mixture containing a lithium compound and nickel-manganese-cobalt hydroxide to a first-stage sintering and a second-stage sintering. The process includes adding a binder and/or binder solution after the first-stage sintering, and the mixture of the binder and/or binder solution and the product of first-stage sintering is sintered in the second-stage sintering. The tap density and volume specific capacity of the positive electrode material lithium-nickel-manganese-cobalt composite oxide prepared by the process, come up to 2.4 g/cm3 and 416.4 mAh/cm3, respectively. Besides, the positive electrode material lithium-nickel-manganese-cobalt composite oxide prepared by the process possesses the advantages of high specific capacity and good cycle stability.

  一种制备用作锂离子电池正极材料的锂镍锰钴复合氧化物的工艺，包括将含有锂化合物和镍锰钴羟矾土的混合物进行第一阶段烧结和第二阶段烧结。该工艺在第一阶段烧结后加入粘合剂和/或粘合剂溶液，然后将粘合剂和/或粘合剂溶液的混合物与第一阶段烧结产物在第二阶段烧结中烧结。通过该工艺制备的正极材料锂镍锰钴复合氧化物的敲击密度和体积比容量分别达到2.4 g/cm3和416.4 mAh/cm3。此外，通过该工艺制备的正极材料锂镍锰钴复合氧化物具有高比容量和良好的循环稳定性。
• Porous Lithium Mangaense Phosphate-Carbon Composite Material, Preparation Method and Application Thereof
  申请人：SUZHOU INSTITUTE OF NANO-TECH AND NANO-BIONICS OF CHINESE ACADEMY OF SCIENCES

  公开号：US20160013474A1

  公开（公告）日：2016-01-14

  A porous lithium manganese phosphate-carbon composite material, and a preparation and application thereof. Multiple nano-pores are distributed in the composite material, and the composite material includes a lithium manganese phosphate material and carbon. The method for preparing the porous lithium manganese phosphate-carbon composite material includes the steps of: mixing a porous pyrophosphate material with a doped metal source, a lithium source, phosphate and a carbon source and then drying them to obtain a reaction precursor, and calcining the reaction precursor at a constant temperature under a protective atmosphere to obtain the composite material. The lithium manganese phosphate material contains compounds in a general formula of LiMn x M 1−x PO 4 , and the porous pyrophosphate material contains compounds in a general formula of (Mn x M 1−x ) 2 P 2 O 7 and 0 wt % to 50 wt % of carbon, where M comprises a transition metal, and 0.6≦x≦1.

  一种多孔锂锰磷酸盐-碳复合材料及其制备和应用。该复合材料中分布着多个纳米孔，包括锂锰磷酸盐材料和碳。制备多孔锂锰磷酸盐-碳复合材料的方法包括以下步骤：将多孔焦磷酸盐材料与掺杂金属源、锂源、磷酸盐和碳源混合，然后干燥以获得反应前体，将反应前体在保护气氛下恒温煅烧以获得复合材料。锂锰磷酸盐材料包含通式为LiMnxM1-xPO4的化合物，多孔焦磷酸盐材料包含通式为(MnxM1-x)2P2O7的化合物和0 wt %至50 wt %的碳，其中M包括过渡金属，0.6≦x≦1。
• PROCESS FOR PREPARING A POSITIVE ELECTRODE MATERIAL FOR LITHIUM ION BATTERY
  申请人：Xiao Feng

  公开号：US20090146115A1

  公开（公告）日：2009-06-11

  A process for preparing lithium-nickel-manganese-cobalt composite oxide used as a positive electrode material for the lithium ion battery, comprising subjecting a mixture containing a lithium compound and nickel-manganese-cobalt hydroxide to a first-stage sintering and a second-stage sintering, wherein said process further comprises adding a binder and/or binder solution after the first-stage sintering, and the mixture of the binder and/or binder solution and the product of first-stage sintering is sintered in said second-stage sintering. The tap density and volume specific capacity of the positive electrode material lithium-nickel-manganese-cobalt composite oxide prepared by the present process, come up to 2.4 g/cm 3 and 416.4 mAh/cm 3 , respectively. Besides, the positive electrode material lithium-nickel-manganese-cobalt composite oxide prepared by the present process possesses the advantages of high specific capacity and good cycle stability.

  一种制备用于锂离子电池正极材料的锂镍锰钴复合氧化物的方法，包括将含有锂化合物和镍锰钴羟石的混合物经过第一阶段烧结和第二阶段烧结处理。在第一阶段烧结后，该方法还包括添加粘合剂和/或粘合剂溶液，然后在第二阶段烧结中将粘合剂和/或粘合剂溶液与第一阶段烧结产物混合物一起烧结。该方法制备的正极材料锂镍锰钴复合氧化物的轻敲密度和体积比容量分别为2.4 g/cm3和416.4 mAh/cm3。此外，该方法制备的正极材料锂镍锰钴复合氧化物具有高比容量和良好的循环稳定性的优点。