正丁基黄原酸锌 | 150-88-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 正丁基黄原酸锌
• 中文别名: 促进剂ZBX
• 英文名称: O-Butyl hydrogen dithiocarbonate, zinc salt
• 英文别名: zinc;butoxymethanedithioate
• CAS: 150-88-9
• 化学式: C10H18O2S4Zn
• 分子量: 363.9
• InChiKey: NEYNBSGIXOOZGZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.27
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  84.6
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 危险等级：
  4.3
• 包装等级：
  II
• 危险类别：
  4.3

制备方法与用途

用途

促进剂 ZBX 是一种超促进剂，用于丁腈橡胶、天然橡胶、氯丁橡胶、再生橡胶、丁苯橡胶以及胶乳等橡胶的生产中。它也可与二苄基胺和一苄基胺混合使用，作为低温超促进剂。

除了活性稍高外，促进剂 ZBX 的使用方法及应用与二硫化二丁基黄原酸钠基本相同，尤其适用于氯丁橡胶胶黏剂。

反应信息

• 作为产物：
  描述：

  丁基黄原酸钾 生成 正丁基黄原酸锌
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Halo-functional silane, process for its preparation, rubber composition containing same and articles manufactured therefrom
  申请人：Jiang Ping

  公开号：US20090111923A1

  公开（公告）日：2009-04-30

  A halo-functional silane possesses halogen functionality and alkanedioxysilyl functionality.

  一个具有卤素功能和烷二氧基硅烷功能的光环功能硅烷。
• Cyclic diol-derived blocked mercaptofunctional silane compositions
  申请人：Cruse W. Richard

  公开号：US20050245753A1

  公开（公告）日：2005-11-03

  Diol derived blocked mercaptofunctional silane compositions in which the silanes comprise cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and processes for their preparation are provided. Also provided are rubber compositions comprising the cyclic diol-derived blocked mercaptofunctional silanes, processes for their preparation and articles of manufacture comprising the rubber compositions, in particular, automotive tires and components thereof.

  提供了以氢碳基二醇衍生的环状和桥联烷氧基团组成的阻化巯基硅烷组合物，以及其制备过程。还提供了包含环状二醇衍生的阻化巯基硅烷的橡胶组合物，其制备过程以及包含该橡胶组合物的制品，特别是汽车轮胎及其组件。
• Mercaptofunctional silane and process for its preparation
  申请人：Chaves Antonio

  公开号：US20080083350A1

  公开（公告）日：2008-04-10

  A mercaptofunctional silane is provided of general Formula (1): [HSG 1 SiZ θ Z β ] m [HSG 2 SiZ β 3 ] n [HSG 3 SiZ β 2 X] o [[HSG 4 SiZ β X 2 ] p (1) wherein: each occurrence of G 1 , G 2 , G 3 , and G 4 is independently a hydrocarbylene group containing from 1 to 30 carbon derived by substitution of a hydrogen on alkyl, alkenyl, aryl, or aralkyl or a divalent heterocarbon group containing 2 to 30 carbon atoms and one or more etheric oxygen (—O—) and/or sulfur (—S—) atoms; each occurrence of X is independently selected from the group consisting of —Cl, —Br, RO—, RC(—O)O—, R 2 C═NO—, R 2 NO—, —R, (HO) d-1 G 5 O—, wherein each R is independently selected from the group consisting of hydrogen, straight, cyclic or branched alkyl that can or can not contain unsaturation, alkenyl groups, aryl groups, and aralkyl groups, wherein each R, other than hydrogen, contains from 1 to 18 carbon atoms, G 5 is independently a substituted hydrocarbon group from 2 to 15 carbon atoms or a substituted heterocarbon group from about 4 to 15 carbon atoms and contains one or more etheric oxygen atoms; each occurrence of Z β , which forms a bridging structure between two silicon atoms, is [—OG 5 (OH) d-2 O—] 0.5 , wherein each occurrence of G 5 is independently selected form the group consisting of a hydrocarbylene group of from 2 to 15 carbon atoms or a divalent heterocarbon group of from 4 to 15 carbon atoms containing one or more etheric oxygen atoms; each occurrence of Z θ , which forms a cyclic structure with a silicon atom, is independently given by —OG 5 (OH) d-2 O—, wherein G 5 is independently selected form the group consisting of a hydrocarbylene group of from 2 to 15 carbon atoms or a divalent heterocarbon group of from 4 to 15 carbon atoms containing one or more etheric oxygen atoms; and, each occurrence of subscripts d, m, n, o and p independently is an integer wherein d is from 2 to 6 in a first embodiment, 2 or 3 in a second embodiment and 2 in a third embodiment; m is 0 to 20; n is 0 to 18; o is 0 to 20; and, p is 0 to 20; with the proviso that m+n+o+p is equal to or greater than 2.

  提供了一种具有一般式（1）的巯基官能硅烷：[HSG1SiZθZβ]m[HSG2SiZβ3]n[HSG3SiZβ2X]o[[HSG4SiZβX2]p(1)其中：每次出现的G1、G2、G3和G4独立地是含有1至30个碳原子的烃基烯基、芳基或芳基烷基上氢原子的取代而得的烃基烯基、芳基或芳基烷基，或者是含有2至30个碳原子和一个或多个醚氧（—O—）和/或硫（—S—）原子的二价杂碳基团；每次出现的X独立地选自由—Cl、—Br、RO—、RC(—O)O—、R2C═NO—、R2NO—、—R、(HO)d-1G5O—组成的群，其中每个R独立地选自氢、直链、环状或支链烯烃基、芳基和芳基烷基组成的群，其中除氢外的每个R含有1至18个碳原子，G5独立地是从2至15个碳原子的取代烃基或从约4至15个碳原子的取代杂碳基，含有一个或多个醚氧原子；每次出现的Zβ，形成两个硅原子之间的桥接结构，为[—OG5(OH)d-2O—]0.5，其中每次出现的G5独立地选自由2至15个碳原子的烃基或4至15个碳原子的含有一个或多个醚氧原子的二价杂碳基；每次出现的Zθ，与硅原子形成一个环状结构，独立地由—OG5(OH)d-2O—给出，其中G5独立地选自由2至15个碳原子的烃基或4至15个碳原子的含有一个或多个醚氧原子的二价杂碳基；而且，每次出现的下标d、m、n、o和p独立地是整数，其中在第一实施例中d为2至6，在第二实施例中为2或3，在第三实施例中为2；m为0至20；n为0至18；o为0至20；p为0至20；但要求m+n+o+p等于或大于2。
• Blocked mercaptosilane coupling agents, process for making and uses in rubber
  申请人：Cruse Richard W.

  公开号：US20080161590A1

  公开（公告）日：2008-07-03

  The invention relates to sulfur silane coupling agents containing multiple blocked mercapto groups which are in a state of reduced activity until activated. The coupling agents are advantageously used in rubber formulations, for example, for fabricating tires with low rolling resistance.

  该发明涉及含有多个被封闭巯基的硫硅偶联剂，这些巯基在未被激活之前处于降低活性的状态。这种偶联剂在橡胶配方中具有优势应用，例如，用于制造具有低滚动阻力的轮胎。
• [EN] SULFUR-CONTAINING SILANE, FILLED ELASTOMERIC COMPOSITIONS CONTAINING SAME AND ARTICLES MADE THEREFROM<br/>[FR] SILANE CONTENANT DU SOUFRE, COMPOSITIONS ÉLASTOMÈRE CHARGÉES CONTENANT CET ÉLÉMENT ET ARTICLES FAITS DE CET ÉLÉMENT
  申请人：MOMENTIVE PERFORMANCE MAT INC

  公开号：WO2010014238A1

  公开（公告）日：2010-02-04

  Sulfur-containing silane, and/or the partially to substantially complete hydrolyzate(s) of sulfur-containing silane, of general Formula (1): [Y1SG1SiZθ]m[Y2SG2SiZθZβ]n[Y3SG3SiZβ3]o[Y4SG4SiZβ2X]p[Y5SG5SiZβX2]q[X]r (1) are provided wherein the variables have the values as indicated in the claims.

  提供了含硫硅烷和/或硫含硅烷的部分到完全的水解物，其通式为（1）：[Y1SG1SiZθ]m[Y2SG2SiZθZβ]n[Y3SG3SiZβ3]o[Y4SG4SiZβ2X]p[Y5SG5SiZβX2]q[X]r，其中变量的值如权利要求所示。