四(乙硫基)四硫富瓦烯[有机电子材料] | 104515-79-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 中文名称: 四(乙硫基)四硫富瓦烯[有机电子材料]
• 中文别名: 四(乙硫基)四硫富瓦烯
• 英文名称: tetraethylthiotetrathiafulvalene
• 英文别名: tetrathioethoxytetrathiafulvalene；tetrakis(ethylthio)terathiafulvalene；tetrakis(ethylthio)tetrathiafulvalene；2-[4,5-bis(ethylsulfanyl)-1,3-dithiol-2-ylidene]-4,5-bis(ethylsulfanyl)-1,3-dithiole
• CAS: 104515-79-9
• 化学式: C₁₄H₂₀S₈
• 分子量: 444.841
• InChiKey: LLDJYFLUQDMPQI-UHFFFAOYSA-N

物化性质

• 熔点：
  72 °C

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  202
• 氢给体数：
  0
• 氢受体数：
  8

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  四(乙硫基)四硫富瓦烯[有机电子材料] 、 copper(l) chloride 以 丙酮 、 乙腈 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  Syntheses and structures of one-and two-dimensional copper(I) coordination polymers with tetrakis(ethylthio)tetrathiafulvalene (TTC2-TTF) and the properties of their iodine-doped compounds

  摘要：

  Two copper(I) complexes with tetrakis(ethylthio)tetrathiafulvalene (TTC2-TTF), [(CuCl)(2)TTC2-TTF] (1) and [(CuBr)(2)TTC2-TTF] (2), have been synthesized and characterized by spectroscopic and X-ray crystallographic methods. Both 1 and 2 are neutral 2:1 (metal/ligand) complexes in which each metal ion is coordinated in a distorted tetrahedral geometry to two bridging halide ions and two sulphur atoms from TTC2-TTF. The crystal of 1 has a two-dimensional structure in which TTC2-TTF molecules are connected between novel helical CuCl frames, while the crystal of 2 has a one-dimensional polymeric chain structure. The average Cu-Cl and Cu-S bond lengths are 2.282(2) and 2,405(2) Angstrom in 1 and Cu-Br and Cu-S bond lengths are 2,445(2) and 2,349(1) Angstrom in 2, respectively. Compounds 1 and 2 were doped with iodine to afford [(CuCl)(2)TTC2-TTF]I (3) and [(CuBr)(2)TTC2-TTF]I (4) which exhibit electrical conductivities of 6 x 10(-7) and 3 x 10(-7) S cm(-1), respectively, at 25 degrees C for compacted pellets.

  DOI：

  10.1016/0277-5387(94)00396-v
• 作为产物：
  描述：

  双(羰基二硫代)四硫富瓦烯 生成 四(乙硫基)四硫富瓦烯[有机电子材料]
  参考文献：
  名称：

  WU, PEIJI;SAITO, GUNZI;IMAEDA, KENICHI;SHI, ZURONG;MORI, TAKEHIKO;ENOKI, +, CHEM. LETT., 1986, N 4, 441-444

  摘要：

  DOI：

文献信息

• The chemistry of C₆S₁₀: a channel structure for C₆S₁₀(CS₂)_0.5and access to the versatile DMAD·C₃S₄O (DMAD = dimethylacetylenedicarboxylate)
  作者：Xiaoguang Yang、Thomas B. Rauchfuss、Scott Wilson

  DOI：10.1039/c39900000034

  日期：——

  Treatment of (Et4N)2[Zn(C3S5)2] with SO2Cl2 gives molecular C6S10(1), structurally characterized as (1)·(CS2)0.5, which has a channel structure; a two step conversion affords bicyclic tetrathiaindenone OC3S4·C2(CO2Me)2 which is used to make new alkenedithiolate derivatives.

  用 SO2Cl2 处理 (Et4N)2[Zn(C3S5)2] 可得到分子 C6S10(1)，其结构特征为 (1)-(CS2)0.5，具有通道结构；通过两步转换可得到双环四噻吩酮 OC3S4-C2(CO2Me)2，用于制造新的烯二硫酸盐衍生物。
• Syntheses, structures and properties of linear copper(I) coordination polymers with tetrakis(ethylthio)tetrathiafulvalene and tetrakis(propylthio)tetrathiafulvalene
  作者：Mikiko Yamamoto、Xinmin Gan、Takayoshi Kuroda-Sowa、Masahiko Maekawa、Yusaku Suenaga、Megumu Munakata

  DOI：10.1016/s0020-1693(97)05478-9

  日期：1997.9

  Two-linear coordination polymers composed of copper(I) cations and tetrakis(ethylthio)tetrathiafulvalene (TTC2-TTF) and tetrakis(propylthio)tetrathiafulvalene (TTC3-TTF) molecules have been synthesized by the reaction of copper(I) tetrafluoroborate with TTC2-TTF and copper(I) perchlorate with TTC3-TTF, respectively, in acetone under argon. The compounds, [Cu(TTC2-TTF)]BF4(1) and [Cu(TTC3-TTF)]ClO4

  通过四氟硼酸铜（I）与四（乙硫基）四硫富瓦烯（TTC 2 -TTF）和四（丙硫基）四硫富瓦烯（TTC 3 -TTF）分子组成的双线性配位聚合物TTC 2 -TTF和高氯酸铜（I）与TTC 3 -TTF分别在氩气中的丙酮中。化合物[Cu（TTC 2 -TTF）] BF 4（1）和[Cu（TTC 3 -TTF）] ClO 4（2），通过光谱和X射线晶体学方法表征。它们是1：1的金属-配体络合物，其中每个铜（I）离子都被来自桥接TTC 2 -TTF或TTC 3 -TTF分子的四个硫原子四面体配位，形成配位聚合物链。1和2分别用碘掺杂以得到[铜（TTC 2 -TTF）] BF 4 }（I 3）0.33和[铜（TTC 3 -TTF）] CLO 4 }（I 3）0.33，其显示出电导率2×10 -5和4×10 -5 S cm -1分别在25°C下压实粒料。
• Copper(I) Iodide Coordination Polymer with Tetrakis(ethylthio)tetrathiafulvalene (TTC₂-TTF) and the Iodine-Doped Compound
  作者：Xinmin Gan、Megumu Munakata、Takayoshi Kuroda-Sowa、Masahiko Maekawa

  DOI：10.1246/bcsj.67.3009

  日期：1994.11

  The title complex was synthesized by the reaction of copper(I) iodide and tetrakis(ethylthio)tetrathiafulvalene (TTC2-TTF) in acetonitrile under argon atmosphere. The new compound, [(CuI)2TTC2-TTF], crystallizes in the monoclinic system, space group P21/m with unit-cell dimensions a = 9.843(2), b = 12.946(2), c = 10.079(1) Å, β = 99.91(1)°, V = 1265.2(4) Å3, and Z = 2. It is a neutral 2 : 1 (metal/ligand) complex in which each metal ion is tetrahedrally coordinated by two bridging iodide ions and two sulfur atoms from TTC2-TTF to form coordination polymeric chains. The average Cu–I and Cu–S bond lengths are 2.601 and 2.369 Å, respectively. The complex was doped with iodine to afford [(CuI)2TTC2-TTF]I1.5 which exhibits a conductivity of 2 × 10−3 S cm−1 at 25 °C for a compacted pellet.

  在氩气环境下，碘化铜（I）和四(乙硫基)四硫杂戊烯（TTC2-TTF）在乙腈中发生反应，合成了标题复合物。新化合物[(CuI)2TTC2-TTF]在单斜晶系中结晶，空间群为 P21/m，单位晶胞尺寸为 a = 9.843(2)，b = 12.946(2)，c = 10.079(1)埃，β = 99.91(1)°，V = 1265.2(4)埃3，Z = 2。它是一种 2:1（金属/配体）的中性复合物，其中每个金属离子都通过两个桥接碘离子和 TTC2-TTF 的两个硫原子进行四面体配位，形成配位聚合物链。Cu-I 和 Cu-S 键的平均长度分别为 2.601 和 2.369 Å。该复合物掺杂了碘，得到了[(CuI)2TTC2-TTF]I1.5，25 °C时，压实颗粒的电导率为 2 × 10-3 S cm-1。
• MULTISENSOR ARRAY FOR DETECTION OF ANALYTES OR MIXTURES THEREOF IN GAS OR LIQUID PHASE
  申请人：Jeppesen Jan Oskar

  公开号：US20130096030A1

  公开（公告）日：2013-04-18

  The present invention relates to a multisensor array for detection of analytes in the gas phase or in the liquid phase, comprising at least two different chemo-selective compounds represented by the general formula (I) wherein the hetero atoms X 1 -X 4 and the substituents R 1 -R 4 are defined in the specification and the dashed bonds represent independently of each other either a single bond or a double bond. Said chemo-selective compounds are capable of individually changing physicochemical properties when exposed to analytes or analyte mixtures and these changes can be detected by a transducer or an array of transducers. The present invention does also relate to the use of at least two different chemo-selective compounds in a sensor array, a method for preparation of such sensor arrays and the use of said sensor arrays. Furthermore the present invention relates to methods for detecting and identifying analytes or mixtures thereof in the gas phase or in the liquid phase.

  本发明涉及一种多传感器阵列，用于检测气相或液相中的分析物，包括至少两种不同的化学选择性化合物，由一般式（I）表示，其中杂原子X1-X4和取代基R1-R4在说明书中定义，虚线键独立地表示单键或双键。所述化学选择性化合物在暴露于分析物或分析物混合物时能够单独改变物理化学性质，这些变化可以被传感器或传感器阵列检测到。本发明还涉及在传感器阵列中使用至少两种不同的化学选择性化合物，制备这种传感器阵列的方法以及使用该传感器阵列的方法。此外，本发明还涉及检测和鉴定气相或液相中的分析物或混合物的方法。
• New synthesis of phenyl-substituted 2,3-dihydro-1,3-dithiolo[4,5-e][1,4]dithiin-6-thione
  作者：Dong-Youn Noh、Ha-Jin Lee、Jongki Hong、Allan E Underhill

  DOI：10.1016/0040-4039(96)01672-3

  日期：1996.10

  The facile synthesis of 4 and (±)-6 was carried out via a Diels-Alder type [2+4] cycloaddition reaction of oligomeric dien 8 with styrene or t-stilbene, respectively, as a dienophile by a thermal reaction and/or photoreaction. (±)-6 crystallized as a racemic compound composed of (2R,3R) and (2S,3S) enantiomers.

  的简便合成4和（±） - 6进行经由狄尔斯-阿尔德型[2 + 4]的低聚二烯的环加成反应8与苯乙烯或吨通过热反应分别芪，作为亲双烯体和/或光反应。（±）-6结晶为由（2R，3R）和（2S，3S）对映异构体组成的外消旋化合物。