8-methylbenzo[b]naphtho[2,1-d]thiophene | 83821-53-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8-methylbenzo[b]naphtho[2,1-d]thiophene
• 英文别名: Benzo(b)naphtho(2,1-d)thiophene, 8-methyl-；8-methylnaphtho[1,2-b][1]benzothiole
• CAS: 83821-53-8
• 化学式: C₁₇H₁₂S
• 分子量: 248.348
• InChiKey: VLPKNFOLGLSAFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  naphthalen-1-yl(p-tolyl)sulfane 在 palladium(II) trifluoroacetate 、 silver(I) acetate 、 potassium carbonate 作用下， 反应 24.0h， 以60%的产率得到8-methylbenzo[b]naphtho[2,1-d]thiophene
  参考文献：
  名称：

  二苯并噻吩的合成钯催化双Ç ？二芳基硫醚的H活化

  摘要：

  据报道，钯通过氧化脱氢环化反应，使二芳基硫醚的双CH官能化形成二苯并噻吩（DBT）。该协议以中等到良好的产量提供了各种DBT，并具有对多种底物的耐受性。通过该方法成功合成了苯并[1,2- b：4,5- b '] bis [ b ]苯并噻吩，用作场效应晶体管的有机半导体。

  DOI：

  10.1002/chem.201402265

文献信息

• CONDENSED CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20180083196A1

  公开（公告）日：2018-03-22

  A condensed cyclic compound and an organic light-emitting device including the same, the condensed cyclic compound being represented by Formula 1:

  一种紧凑的环状化合物以及包括该化合物的有机发光器件，所述紧凑的环状化合物由公式1表示：
• Organic Compound, Light-Emitting Device, Light-Emitting Apparatus, Electronic Device, Display Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20210139445A1

  公开（公告）日：2021-05-13

  A novel organic compound is provided. Alternatively, an organic compound that exhibits light emission with favorable chromaticity is provided. Alternatively, an organic compound that exhibits blue light emission with favorable chromaticity is provided. Alternatively, a light-emitting device with favorable emission efficiency is provided. Alternatively, an organic compound having a high carrier-transport property is provided. Alternatively, an organic compound with favorable reliability is provided. An organic compound having at least one amino group in which any one of a substituted or unsubstituted dibenzofuranyl group, a substituted or unsubstituted dibenzothiophenyl group, and a substituted or unsubstituted carbazolyl group is bonded to any one of a substituted or unsubstituted naphthobisbenzofuran skeleton, a substituted or unsubstituted naphthobisbenzothiophene skeleton, and a substituted or unsubstituted naphthobenzothienobenzofuran skeleton is provided.

  提供了一种新型有机化合物。或者提供一种表现出有利色度的光发射的有机化合物。或者提供一种表现出有利色度的蓝光发射的有机化合物。或者提供一种具有良好发射效率的发光装置。或者提供一种具有高载流子传输性能的有机化合物。或者提供一种具有良好可靠性的有机化合物。提供了一种有机化合物，其中任何一种取代或未取代的二苯并呋喃基团，取代或未取代的二苯并噻吩基团和取代或未取代的咔唑基团中的至少一个氨基与取代或未取代的萘并苯并呋喃骨架、取代或未取代的萘并苯并噻吩骨架和取代或未取代的萘苯并噻吩苯并呋喃骨架中的任何一个键合。
• Condensed cyclic compound and organic light-emitting device including the same
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10411191B2

  公开（公告）日：2019-09-10

  A condensed cyclic compound and an organic light-emitting device including the same, the condensed cyclic compound being represented by Formula 1:

  一种缩合环状化合物和包括其在内的有机发光器件，缩合环状化合物由式 1 表示：
• Tominaga, Yoshinori; Pratap, Ram; Castle, Raymond N., Journal of Heterocyclic Chemistry, 1982, vol. 19, p. 859 - 863
  作者：Tominaga, Yoshinori、Pratap, Ram、Castle, Raymond N.、Lee, Milton L.

  DOI：——

  日期：——
• Synthesis of Dibenzothiophenes by Pd-Catalyzed Dual CH Activation from Diaryl Sulfides
  作者：Rui Che、Zhiqing Wu、Zhengkai Li、Haifeng Xiang、Xiangge Zhou

  DOI：10.1002/chem.201402265

  日期：2014.6.10

  Palladium‐catalyzed dual CH functionalization of diaryl sulfides to form dibenzothiophenes (DBTs) by oxidative dehydrogenative cyclization is reported. This protocol afforded various DBTs in moderate to good yields with tolerance of a wide variety of substrates. Benzo[1,2‐b:4,5‐b′]bis[b]benzothiophene was successfully synthesized by this method, which was used as an organic semiconductor for field‐effect

  据报道，钯通过氧化脱氢环化反应，使二芳基硫醚的双CH官能化形成二苯并噻吩（DBT）。该协议以中等到良好的产量提供了各种DBT，并具有对多种底物的耐受性。通过该方法成功合成了苯并[1,2- b：4,5- b '] bis [ b ]苯并噻吩，用作场效应晶体管的有机半导体。