tetrakis(3-(trichlorosilyl) propyl)silane | 211635-40-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: tetrakis(3-(trichlorosilyl) propyl)silane
• 英文别名: Silane, tetrakis[3-(trichlorosilyl)propyl]-；tetrakis(3-trichlorosilylpropyl)silane
• CAS: 211635-40-4
• 化学式: C₁₂H₂₄Cl₁₂Si₅
• 分子量: 734.186
• InChiKey: RNGMXONQPNPDFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.62
• 重原子数：
  29
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tetrakis(3-(trichlorosilyl) propyl)silane 、 烯丙基溴化镁 以90%的产率得到Tetrakis[3-tris(prop-2-enyl)silylpropyl]silane
  参考文献：
  名称：

  Synthesis of Calixarene-Capped Carbosilane Dendrimers

  摘要：

  A new class of polycalix[4]arene hosts has been constructed based oil a carbosilane dendrimer architecture, in which each dendritic branch terminates with a calix[4]arene entity. This study reports the synthesis and characterization of the zeroth generation example with four calix[4]arenes and or the first generation example with 12 calix[4]arenes.

  DOI：

  10.1021/jo802714q
• 作为产物：
  描述：

  四烯丙基硅烷 在 dihydrogen hexachloroplatinate 、 三氯硅烷 作用下， 以 四氢呋喃 为溶剂， 反应 4.25h， 生成 tetrakis(3-(trichlorosilyl) propyl)silane
  参考文献：
  名称：

  Synthesis of Highly Charged Organometallic Dendrimers and Their Characterization by Electrospray Mass Spectrometry and Single-Crystal X-ray Diffraction

  摘要：

  Four new carbosilane dendrimers terminated with 12, 24, 36, and 72 benzyl groups have been synthesized and characterized by matrix-assisted laser desorption/ionization-time-of-flight mass spectrometry. These dendrimers were capped with Cp*Ru+ to yield polycations containing charges of 12+, 24+, 36+, and 72+. The charged dendrimers comprise the largest such structures thus far characterized by electrospray ionization (ESI) mass spectrometry. Additionally, for the first time full resolution of individual isotopic distributions has been achieved using ESI FT-ICR techniques, thereby providing unambiguous confirmation of the charges and nuclearities of the dendrimers. The first-generation, ruthenium-containing dendrimer (G1-Ru-12) was also characterized by single-crystal X-ray diffraction. This polycation has a molecular volume significantly larger than any dendrimer thus far characterized by this technique.

  DOI：

  10.1021/ja981610q

文献信息

• Synthesis of Highly Charged Organometallic Dendrimers and Their Characterization by Electrospray Mass Spectrometry and Single-Crystal X-ray Diffraction
  作者：Joshua W. Kriesel、Stefan König、Michael A. Freitas、Alan G. Marshall、Julie A. Leary、T. Don Tilley

  DOI：10.1021/ja981610q

  日期：1998.12.1

  Four new carbosilane dendrimers terminated with 12, 24, 36, and 72 benzyl groups have been synthesized and characterized by matrix-assisted laser desorption/ionization-time-of-flight mass spectrometry. These dendrimers were capped with Cp*Ru+ to yield polycations containing charges of 12+, 24+, 36+, and 72+. The charged dendrimers comprise the largest such structures thus far characterized by electrospray ionization (ESI) mass spectrometry. Additionally, for the first time full resolution of individual isotopic distributions has been achieved using ESI FT-ICR techniques, thereby providing unambiguous confirmation of the charges and nuclearities of the dendrimers. The first-generation, ruthenium-containing dendrimer (G1-Ru-12) was also characterized by single-crystal X-ray diffraction. This polycation has a molecular volume significantly larger than any dendrimer thus far characterized by this technique.
• Silane dendrimers
  作者：Alexander W. van der Made、Piet W. N. M. van Leeuwen

  DOI：10.1039/c39920001400

  日期：——

  A wide variety of silane dendrimers with up to 972 end groups has been synthesised in excellent yields using repetitive alkenylation-hydrosilylation cycles.
• Synthesis of Calixarene-Capped Carbosilane Dendrimers
  作者：Joseph B. Lambert、Seung-Hyun Kang、Kuangbiao Ma、Chunqing Liu、Allison G. Condie

  DOI：10.1021/jo802714q

  日期：2009.3.20

  A new class of polycalix[4]arene hosts has been constructed based oil a carbosilane dendrimer architecture, in which each dendritic branch terminates with a calix[4]arene entity. This study reports the synthesis and characterization of the zeroth generation example with four calix[4]arenes and or the first generation example with 12 calix[4]arenes.