申请人:EASTMAN KODAK COMPANY
公开号:EP1014186A1
公开(公告)日:2000-06-28
A photographic element comprises a light sensitive silver halide emulsion layer having associated therewith an open chain α-carbonyl acetanilide yellow dye-forming coupler having the formula:
wherein
R1 is selected from the group consisting of alkyl, aryl, heterocyclic, and amino groups, provided that R1 may form a ring bonded to another carbon atom which is a member of Ring "A";
each R2 is independently selected from the group consisting of those substituents having a Hammett's sigma value of 0 or less, and m is from 0 to 4;
each R3 and R4 for each of the n carbon atoms is independently selected from the group consisting of hydrogen, alkoxy, aryl, heterocyclic, aryloxy, and alkyl groups, and n is 0 to 16;
each R5 independently selected from the group consisting of amino, alkyl groups, and groups linked to the "B" ring by oxygen or sulfur, and p is 1 to 3, provided that two R5 groups may join to form a ring;
R6 is selected from the group consisting of alkyl, aryl, and amino groups;
each L is independently a divalent linking group and q is 0 to 3; and
Ring "A" is bonded indirectly to the 3-, 4-, or 5-position of Ring "B"; and
Z is hydrogen, or a group capable of coupling-off when the coupler reacts with an oxidized color developing agent.
一种摄影元素包括具有与之相关联的开链α-酮基乙酰苯胺黄色染料生成偶联剂的感光性银卤化物乳胶层,其具有以下结构式:其中R1选自烷基、芳基、杂环基和氨基组成的群,前提是R1可能形成与另一个碳原子结合的环,该碳原子是“A”环的成员;每个R2独立地选自具有Hammett的sigma值为0或更低的取代基的群,m为0至4;每个R3和R4对于n个碳原子中的每个碳原子,独立地选自氢、烷氧基、芳基、杂环基、芳氧基和烷基组成的群,n为0至16;每个R5独立地选自氨基、烷基和通过氧或硫连接到“B”环的基团,p为1至3,前提是两个R5基团可以结合形成环;R6选自烷基、芳基和氨基组成的群;每个L独立地是二价连接基团,q为0至3;和“A”环间接连接到“B”环的3-、4-或5-位置;Z是氢,或者是在偶联剂与氧化的着色显影剂发生反应时能够偶联脱落的基团。