4-hexylbenzoyloxy-4'-aniline | 202828-24-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-hexylbenzoyloxy-4'-aniline
• 英文别名: (4-Aminophenyl) 4-hexylbenzoate
• CAS: 202828-24-8
• 化学式: C₁₉H₂₃NO₂
• 分子量: 297.397
• InChiKey: MXOXVXXENOOBEM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  52.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-hexylbenzoyloxy-4'-aniline 、 4-hexylbenzoyloxy-4'-benzaldehyde 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  The Synthesis and Mesomorphism of Mesogenic Imines with Fluorocarbon Chains and their Complexes with Rhenium(I): New Materials with Cubic Phases

  摘要：

  In this paper, we describe the synthesis of some imine ligands bearing fluorinated chains and their metal complexes with Re(I). Whereas related ligands with hydrocarbon chains show nematic and S-C phases, the new ligands show S-A and S-C phases. However, when both terminal chains are fully fluorinated, then the ligand additionally show a cubic phase. Metal complexes of the fluorinated ligands show a S-A phase before decomposing.The mesomorphism of both the complexes and the ligands is discussed and the formation of cubic phases in these imines is explored in relation to other materials showing a cubic phase.

  DOI：

  10.1080/10587250108025766
• 作为产物：
  描述：

  4-hexylbenzoyloxy-4'-nitrobenzene 在 palladium on activated charcoal 氢气 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 以89%的产率得到4-hexylbenzoyloxy-4'-aniline
  参考文献：
  名称：

  The Synthesis and Mesomorphism of Mesogenic Imines with Fluorocarbon Chains and their Complexes with Rhenium(I): New Materials with Cubic Phases

  摘要：

  In this paper, we describe the synthesis of some imine ligands bearing fluorinated chains and their metal complexes with Re(I). Whereas related ligands with hydrocarbon chains show nematic and S-C phases, the new ligands show S-A and S-C phases. However, when both terminal chains are fully fluorinated, then the ligand additionally show a cubic phase. Metal complexes of the fluorinated ligands show a S-A phase before decomposing.The mesomorphism of both the complexes and the ligands is discussed and the formation of cubic phases in these imines is explored in relation to other materials showing a cubic phase.

  DOI：

  10.1080/10587250108025766

文献信息

• US3997242A
  申请人：——

  公开号：US3997242A

  公开（公告）日：1976-12-14
• US4058476A
  申请人：——

  公开号：US4058476A

  公开（公告）日：1977-11-15