[Co{SSi(OtBu)₃}₂(dmpda)] | 1542741-02-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: [Co{SSi(OtBu)₃}₂(dmpda)]
• 英文别名: [Co{SSi(OtBu)₃}₂(3-(dimethylamino)-1-propylamine)]
• CAS: 1542741-02-5
• 化学式: C₂₉H₆₈CoN₂O₆S₂Si₂
• 分子量: 720.165
• InChiKey: BEJVSDPAPOIBIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Co(μ-SSi(O-tert-C4H9)3)(SSi(O-tert-C4H9)3)(NH3)]2 、 N,N-二甲基-1,3-二氨基丙烷 以 甲醇 为溶剂， 生成 [Co{SSi(OtBu)₃}₂(dmpda)]
  参考文献：
  名称：

  Mono- and polynuclear Co(II) silanethiolates with aliphatic diamines

  摘要：

  Four Co(II) complexes, [Co{SSi(OtBu)(3)}(2)(dmpda)] 1, [Co{SSi(OtBu)(3)}(2)(bda)(2)](n) 2[Co{SSi(OtBu)(3)}(2)(pda)(2)](n) 3 and [Co{SSi(OtBu)(3)}(2)(hda)(2)](n) 4 [dmpda = 3-(dimethylamino)-1-propylamine; bda = 1.4-butanediamine; pda = 1.5-pentanediamine; had = 1.6-hexanediamine] have been synthesized and characterized using X-ray diffraction. Complex 1 is mononuclear and contains Co(II) coordinated by dmpda molecule in chelating mode, whereas compounds 3 and 4 are one-dimensional polymers with pda and hda diamines as bridges between the metallic centers respectively. In all complexes tri-tert-butoxysilanethiolate residue acts as terminal S-donor ligand. Full characterization of obtained compounds 1-4 was additionally carried out with the use of IR and UV-vis spectroscopy, elemental and thermal analysis. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2013.11.020