1,3,5-tris(3-oxahexa-5-ynyl)-1,3,5-triazinane-2,4,6-trione | 1234387-26-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,3,5-tris(3-oxahexa-5-ynyl)-1,3,5-triazinane-2,4,6-trione
• 英文别名: 1,3,5-Tris(2-prop-2-ynoxyethyl)-1,3,5-triazinane-2,4,6-trione；1,3,5-tris(2-prop-2-ynoxyethyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 1234387-26-8
• 化学式: C₁₈H₂₁N₃O₆
• 分子量: 375.381
• InChiKey: RPLHDSWOVUVTKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  27
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  88.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,3,5-tris(3-oxahexa-5-ynyl)-1,3,5-triazinane-2,4,6-trione 在 N-溴代丁二酰亚胺(NBS) 、 silver nitrate 作用下， 以 丙酮 为溶剂， 以73%的产率得到1,3,5-tris(6-bromo-3-oxahexa-5-ynyl)-1,3,5-triazinane-2,4,6-trione
  参考文献：
  名称：

  Synthesis of Podands with Cyanurate or Isocyanurate Cores and Terminal Triple Bonds

  摘要：

  报告了以氰尿酸或异氰尿酸核为核心、带有末端三键或溴化三键的聚氧乙烯侧臂的穴状配体合成。氰尿酸衍生穴状配体的起始原料为市售氰尿酸，而异氰尿酸衍生物则通过相应氰尿酸盐的热异构化获得。

  DOI：

  10.1055/s-0029-1218724
• 作为产物：
  描述：

  2,4,6-tris(3-oxahexa-5-ynyloxy)-1,3,5-triazine 在 Bu₄XBr, X = P or N 作用下， 生成 1,3,5-tris(3-oxahexa-5-ynyl)-1,3,5-triazinane-2,4,6-trione
  参考文献：
  名称：

  Synthesis of Podands with Cyanurate or Isocyanurate Cores and Terminal Triple Bonds

  摘要：

  报告了以氰尿酸或异氰尿酸核为核心、带有末端三键或溴化三键的聚氧乙烯侧臂的穴状配体合成。氰尿酸衍生穴状配体的起始原料为市售氰尿酸，而异氰尿酸衍生物则通过相应氰尿酸盐的热异构化获得。

  DOI：

  10.1055/s-0029-1218724

文献信息

• PROCESSES FOR PREPARING CURED FILMS, THE RESULTING FILMS, AND PLASMA-INITIATED POLYMERIZABLE COMPOSITIONS
  申请人：FUJIFILM Corporation

  公开号：US20140170405A1

  公开（公告）日：2014-06-19

  Provided are novel plasma-assisted processes for preparing cured films having excellent heat resistance and moisture resistance. A process for preparing a cured film, comprising at least: applying a composition containing (A) at least one conductive polymer precursor on a substrate to form a coating layer, and irradiating the coating layer with a plasma to polymerize the conductive polymer precursor (A).

  提供了一种新型等离子体辅助制备固化膜的工艺，该固化膜具有优异的耐热性和耐潮性。一种制备固化膜的工艺，包括至少以下步骤：在基板上涂布含有（A）至少一种导电聚合物前体的组合物以形成涂层层，然后用等离子体照射涂层层以聚合导电聚合物前体（A）。
• Cholate-Based Synthesis of Size-Tunable Cage Compounds
  作者：Lingling Peng、Fanyang Mo、Qinghai Zhang

  DOI：10.1021/jo5023734

  日期：2015.1.16

  We describe cholate-based cage amphiphiles with a unique architecture that combines elements of structural rigidity and flexibility. The cage compounds are built by extending and bridging three polar chains underneath the concave steroid rings of cholate and capping with another rigid, symmetrically trifunctionalized cyanuric acid moiety. The connecting chains are varied to include, for instance, oligo(ethylene glycol) or chains containing 1,2,3-triazole units to present flexibility in the chemical and structural space and potentially deliver functional molecules for molecular recognition applications.
• Cryptands and bismacrocycles with cyanuric and isocyanuric units: synthesis and structural investigations
  作者：Flavia Pop、Crina Socaci、Anamaria Terec、Eric Condamine、Richard Attila Varga、Ciprian I. Raţ、Jean Roncali、Ion Grosu

  DOI：10.1016/j.tet.2012.07.100

  日期：2012.10

  Hay synthesis of cryptands and bismacrocycles starting from tripodands with cyanuric and isocyanuric cores is reported. The structure of the compounds is revealed by X-ray diffraction, NMR spectrometry and MS investigations. DNMR experiments carried out with bismacrocycles indicated the flipping of the rings and the free-energy barrier for the conformational process could be determined in one case. (C) 2012 Elsevier Ltd. All rights reserved.
• Synthesis of Podands with Cyanurate or Isocyanurate Cores and Terminal Triple Bonds
  作者：Crina Cismaş、Ion Grosu、Flavia Piron、Cornelia Oprea、Anamaria Terec、Jean Roncali

  DOI：10.1055/s-0029-1218724

  日期：2010.5

  The synthesis of podands with cyanuric or isocyanuric acid cores and oligoethyleneoxy pendant arms exhibiting terminal triple bonds or brominated triple bonds is reported. The starting material for cyanuric acid derived podands is commercially available cyanuric acid, while the isocyanuric derivatives are obtained by thermal isomerization of the corresponding cyanurates.

  报告了以氰尿酸或异氰尿酸核为核心、带有末端三键或溴化三键的聚氧乙烯侧臂的穴状配体合成。氰尿酸衍生穴状配体的起始原料为市售氰尿酸，而异氰尿酸衍生物则通过相应氰尿酸盐的热异构化获得。