2-N,2-N-dibutyl-6-chloro-4-N-[4-[[4-chloro-6-(dibutylamino)-1,3,5-triazin-2-yl]amino]phenyl]-1,3,5-triazine-2,4-diamine | 33193-12-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2-N,2-N-dibutyl-6-chloro-4-N-[4-[[4-chloro-6-(dibutylamino)-1,3,5-triazin-2-yl]amino]phenyl]-1,3,5-triazine-2,4-diamine
• CAS: 33193-12-3
• 化学式: C₂₈H₄₂Cl₂N₁₀
• 分子量: 589.614
• InChiKey: DNANHFGDCJKUQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  40
• 可旋转键数：
  18
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  108
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  二正丁胺 在 cesium fluoride 作用下， 以 四氢呋喃 、 N-甲基吡咯烷酮 为溶剂， 反应 3.0h， 生成 N2-(4-aminophenyl)-N4,N4-dibutyl-6-chloro-1,3,5-triazine-2,4-diamine 、 2-N,2-N-dibutyl-6-chloro-4-N-[4-[[4-chloro-6-(dibutylamino)-1,3,5-triazin-2-yl]amino]phenyl]-1,3,5-triazine-2,4-diamine
  参考文献：
  名称：

  Synthesis of polyguanamines from 2-N,N-dibutylamino-4,6-dichloro-1,3,5-triazine with aromatic diamines

  摘要：

  Solution polycondensation of 2-N,N-dibutylamino-4,6-dichloro-1,3,5-triazine (BDCT) with various aromatic diamines, including 4,4'-oxydianiline (ODA), p-phenylenediamine (pPDA), m-phenylenediamine (mPDA), o-tolidine (oTh), 4,4'-(9-fluorenylidene)dianiline (BAFL), and 2,4-diamino-6-(N,N-dibutylamino)-1,3,5-triazine (DABT), was investigated. High molecular weight (>10,000) polyguanamines (PGs) were obtained via the polymerization of BDCT with ODA, pPDA, oTD, and BAFL at 150-180 C in N-methylpyrrolidone (NMP) for 6 h. The polymerizability with BDCT was determined on the basis of the molecular weights of the polymers and the chemical shifts of the NMR data as follows: ODA > oTD > BAFL > pPDA > mPDA >> DABT. PGs were obtained from the reaction of BDCT with ODA and mPDA in only 55-77% yield, which may be attributed to the formation of cyclic oligomers. All of the polymers showed high thermostability (5% weight-loss temperature in N-2 greater than 444 degrees C), and the polymers generated from reaction of BDCT with ODA, mPDA, and BAFL exhibited good solubility in tetrahydrofuran and polar aprotic solvents such as NMP. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2013.03.005

文献信息

• Synthesis of polyguanamines from 2-N,N-dibutylamino-4,6-dichloro-1,3,5-triazine with aromatic diamines
  作者：Kyohei Saito、Naoya Nishimura、Shigeko Sasaki、Yoshiyuki Oishi、Yuji Shibasaki

  DOI：10.1016/j.reactfunctpolym.2013.03.005

  日期：2013.5

  Solution polycondensation of 2-N,N-dibutylamino-4,6-dichloro-1,3,5-triazine (BDCT) with various aromatic diamines, including 4,4'-oxydianiline (ODA), p-phenylenediamine (pPDA), m-phenylenediamine (mPDA), o-tolidine (oTh), 4,4'-(9-fluorenylidene)dianiline (BAFL), and 2,4-diamino-6-(N,N-dibutylamino)-1,3,5-triazine (DABT), was investigated. High molecular weight (>10,000) polyguanamines (PGs) were obtained via the polymerization of BDCT with ODA, pPDA, oTD, and BAFL at 150-180 C in N-methylpyrrolidone (NMP) for 6 h. The polymerizability with BDCT was determined on the basis of the molecular weights of the polymers and the chemical shifts of the NMR data as follows: ODA > oTD > BAFL > pPDA > mPDA >> DABT. PGs were obtained from the reaction of BDCT with ODA and mPDA in only 55-77% yield, which may be attributed to the formation of cyclic oligomers. All of the polymers showed high thermostability (5% weight-loss temperature in N-2 greater than 444 degrees C), and the polymers generated from reaction of BDCT with ODA, mPDA, and BAFL exhibited good solubility in tetrahydrofuran and polar aprotic solvents such as NMP. (C) 2013 Elsevier Ltd. All rights reserved.