1,1-Diethylpropyl-methylcarbanat | 34949-09-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: 1,1-Diethylpropyl-methylcarbanat
• 英文别名: 3-ethylpentan-3-yl methyl carbonate；1,1-diethylpropyl methyl carbonate
• CAS: 34949-09-2
• 化学式: C₉H₁₈O₃
• 分子量: 174.24
• InChiKey: DIYNTABPBZGUHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  氯甲酸甲酯 、 Et3CONa 以 乙醚 为溶剂， 生成 1,1-Diethylpropyl-methylcarbanat
  参考文献：
  名称：

  Conformations of the Esters. V. The Conformations of Carbonates

  摘要：

  在烷基或芳基碳酸盐中，红外光谱和核磁共振光谱技术已证实存在构象异构体（s-顺式和s-反式）。偶极矩测量也为光谱数据所得结论提供了支持。

  DOI：

  10.1246/bcsj.44.3419

文献信息

• Lanthanum(III) Isopropoxide Catalyzed Chemoselective Transesterification of Dimethyl Carbonate and Methyl Carbamates
  作者：Manabu Hatano、Sho Kamiya、Katsuhiko Moriyama、Kazuaki Ishihara

  DOI：10.1021/ol102754y

  日期：2011.2.4

  carbonate and much less reactive methyl carbamates with primary (1°), secondary (2°), and tertiary (3°) alcohols was established with the use of a lanthanum(III) complex, which was prepared in situ from lanthanum(III) isopropoxide (3 mol %) and 2-(2-methoxyethoxy)ethanol (6 mol %). In particular, corresponding carbonates and carbamates obtained were of synthetic utility from the viewpoint of the selective protection

  使用镧（III）配合物，建立了反应性较低的碳酸二甲酯和反应性较低的氨基甲酸甲酯与伯（1°），仲（2°）和叔（3°）醇的实际酯交换反应原位由异丙醇镧（III）（3摩尔％）和2-（2-甲氧基乙氧基）乙醇（6摩尔％）原位制备。特别地，从对1°-，2°-和3°-醇的选择性保护和/或脱保护的观点来看，获得的相应的碳酸盐和氨基甲酸酯具有合成用途。
• COSMETIC COMPOSITION COMPRISING AT LEAST ONE APROTIC HYDROCARBON-BASED VOLATILE SOLVENT
  申请人：L'Oréal

  公开号：EP2083789A1

  公开（公告）日：2009-08-05
• Cosmetic composition comprising at least one volatile carbonic acid ester
  申请人：Fouron Jean-Yves

  公开号：US20080161394A1

  公开（公告）日：2008-07-03

  The present application relates to a cosmetic composition comprising at least one carbonic acid ester corresponding to formula (I) below: R1—O—CO—O—R2   (I) in which R1 and R2 are identical or different and represent a linear or branched hydrocarbon-based radical, with the proviso that: when R1 and R2 are linear, they each contain from 1 to 6 carbon atoms, with 6≦R1+R2≦7; and when R1 and/or R2 are branched, they each contain from 1 to 8 carbon atoms, with 6≦R1+R2≦9. This composition can be used as a product for caring for and/or making up keratin materials, in particular the skin, the lips and/or the integuments.
• CONJUGATED POLYMERS
  申请人：INNOVATIONLAB GMBH

  公开号：US20170331043A1

  公开（公告）日：2017-11-16

  The invention relates to new conjugated semiconducting polymers containing thermally cleavable side groups. The thermally cleavable side groups are selected from among carbonate groups and carbamate groups, By thermally cleaving side groups, the solubility or the polymers can he reduced in a targeted manner. The polymers are used as semiconductors in organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices, organic photodetectors (OPDs), organic light emitling diodes (OLEDs), and organic field effect transistors (OFETs).
• [EN] COSMETIC COMPOSITION COMPRISING AT LEAST ONE APROTIC HYDROCARBON-BASED VOLATILE SOLVENT<br/>[FR] COMPOSITION COSMÉTIQUE COMPRENANT AU MOINS UN SOLVANT VOLATIL À BASE D'HYDROCARBURE APROTIQUE
  申请人：OREAL

  公开号：WO2008061985A1

  公开（公告）日：2008-05-29

  [EN] The present application relates to a cosmetic composition comprising, in a physiologically acceptable medium, at least one aprotic hydrocarbon-based volatile solvent comprising no more than one branch, the volatility of said solvent being such that the amount evaporated in 30 minutes is between 4.1 mg/cm² and 24 mg/cm². This composition can be used as a product for caring for and/or making up keratin materials, in particular the skin, the lips and/or the integuments.
  [FR] La présente invention concerne une composition cosmétique comprenant, dans un milieu physiologiquement acceptable, au moins un solvant volatil à base d'hydrocarbure aprotique ne comprenant pas plus d'une ramification, la volatilité dudit solvant étant telle que la quantité évaporée après 30 minutes est située entre 4,1 mg/cm² et 24 mg/cm². La présente composition peut être utilisée comme produit pour prendre soin et/ou fabriquer des matériaux à base de kératine, en particulier la peau, les lèvres et/ou les téguments.