tetradecylzinc chloride | 70771-17-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: tetradecylzinc chloride
• CAS: 70771-17-4
• 化学式: C₁₄H₂₉ClZn
• 分子量: 298.227
• InChiKey: ASLGMWNTSZYALU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.34
• 重原子数：
  16.0
• 可旋转键数：
  13.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  tetradecylzinc chloride 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 N-溴代丁二酰亚胺(NBS) 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 生成 2,5-dibromo-3,6-ditetradecylthieno[3,2-b]thiophene
  参考文献：
  名称：

  Influence of Side-Chain Regiochemistry on the Transistor Performance of High-Mobility, All-Donor Polymers

  摘要：

  Three novel polythiophene isomers are reported whereby the only difference in structure relates to the regiochemistry of the solubilizing side chains on the backbone. This is demonstrated to have a significant impact on the optoelectronic properties of the polymers and their propensity to aggregate in solution. These differences are rationalized on the basis of differences in backbone torsion. The polymer with the largest effective conjugation length is demonstrated to exhibit the highest field-effect mobility, with peak values up to 4.6 cm(2) V-1 s(-1).

  DOI：

  10.1021/ja508798s

文献信息

• Synthesis of long chain fatty acid esters of N-acetylmuramyl-L-alanyl-D-isoglutamine in relation to antitumor activity
  作者：Shoichi Kusumoto、Masaru Inage、Tetsuo Shiba、Ichiro Azuma、Yuichi Yamamura

  DOI：10.1016/s0040-4039(01)85765-8

  日期：1978.1