Ni(DIPDTC)₂ | 15694-55-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Ni(DIPDTC)₂
• 英文别名: [Ni(diisopropyldithiocarbamate)₂]；N,N-di(propan-2-yl)carbamodithioate;nickel(2+)
• CAS: 15694-55-0
• 化学式: C₁₄H₂₈N₂NiS₄
• 分子量: 411.344
• InChiKey: PYLMYJVNPREXPE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.87
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Ni(DIPDTC)₂ 以 neat (no solvent, solid phase) 为溶剂， 生成 nickel(II) sulfide
  参考文献：
  名称：

  二硫代氨基甲酸镍（II）配合物的单晶转化为硫化镍晶体

  摘要：

  摘要以双（κ2S，S'-二（异丙基）二硫代氨基甲酸酯）镍（II）单晶为单源前驱体，通过热解法形成NiS。该复合物在约250°C时分解形成α-NiS，仅未检测到β-NiS。使用原位技术对热解过程的分析表明，热解发生在一个步骤中，主要的挥发性副产物为异丙基-异硫氰酸酯和二硫化碳。使用SEM和TEM检查生成的NiS，以显示前体晶体边缘长度和角度关系的保留。

  DOI：

  10.1016/j.ica.2018.12.014
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 sodium N,N'-diisopropyldithiocarbamate 在 sodium acetate 作用下， 以 水 为溶剂， 以81%的产率得到Ni(DIPDTC)₂
  参考文献：
  名称：

  Lindmark, Alan F.; Fay, Robert C., Inorganic Chemistry, 1983, vol. 22, # 14, p. 2000 - 2006

  摘要：

  DOI：

文献信息

• Bis(κ2S,Sʹ-di(isopropyl)dithiocarbamato)nickel(II): Anagostic C–H⋅⋅⋅Ni interactions and physical properties
  作者：Alexander Angeloski、Anthony Thomas Baker、Mohan Bhadbhade、Andrew Michael McDonagh

  DOI：10.1016/j.molstruc.2016.02.028

  日期：2016.6

  Abstract The molecular structure of bis(κ2S,Sʹ-di(isopropyl)dithiocarbamato)nickel(II) has been examined by single crystal X-ray diffraction. The data reveal a C–H⋅⋅⋅Ni anagostic interaction arising from the interaction of two non-equivalent molecules within the crystal. Thermal analysis data show that the complex decomposes at ∼330 °C. The structure of the resultant NiS material was examined using

  摘要 通过单晶X射线衍射研究了双(κ2S,S′-二(异丙基)二硫代氨基甲酸)镍(II)的分子结构。数据揭示了由晶体内两个非等价分子相互作用引起的 C–H⋅⋅⋅Ni 对立相互作用。热分析数据表明配合物在~330°C 分解。使用扫描电子显微镜和能量色散 X 射线光谱检查所得 NiS 材料的结构，揭示了 NiS 纳米线。
• Synthesis and single-crystal structure determination of bis(triphenylphosphine) (diisopropyldithiocarbamato)nickel(II) perchlorate chloroform solvate and [1,2-bis(diphenylphosphino-k.P,P′)ethane] (diisopropyldithiocarbamato)nickel(II) perchlorate chloroform solvate: Steric effect of bulky alkyl substituents on the dithiocarbamate, free and chelating phosphines on the NiS2P2 chromophore
  作者：V. Venkatachalam、K. Ramalingam、Thomas C.W. Mak、Luo Bao-Sheng

  DOI：10.1016/0277-5387(95)00376-2

  日期：1996.4

  The complexes [Ni(dipdtc)(PPh 3 ) 2 ]ClO 4 ∗d CHCl 3 ( 1 ) [Ni(dipdtc)dppe]ClO 4 ∗d CHCl 3 ( 2 ) (dipdtc = diisopropyldithiocarbamate, dppe = 1,2-bis(diphenylphosphino)ethane) have been prepared from the reaction between Ni(dipdtc) 2 ( 3 ) and phosphines (PPh 3 and dppe) in CHCl 3 CH 3 OH. The crystal structures of 1 and 2 have been determined, showing that both complexes have planar NiS 2 P 2 chromophores

  摘要配合物[Ni（dipdtc）（PPh 3）2] ClO 4 * d CHCl 3（1）[Ni（dipdtc）dppe] ClO 4 * d CHCl 3（2）（dipdtc =二异丙基二硫代氨基甲酸酯，dppe = 1,2-由Ni（dipdtc）2（3）与膦（PPh 3和dppe）在CHCl 3 = CH 3 OH中的反应制备了双（二苯基膦基）乙烷。已确定1和2的晶体结构，表明两种配合物均具有平面NiS 2 P 2发色团。二硫代氨基甲酸酯上烷基取代基的增加的体积增加了分子的跨度体积，并由于其起皱而迫使CN距离延长。与配合物1相比，配合物2中的螯合dppe迫使PNiP角减小，SNiS角增大。
• Design and synthesis of heteroleptic Ni(II) dipyrrin complexes for electrochemical proton reduction reactions: Cyclic voltammetric and theoretical studies
  作者：Rajendra Prasad Paitandi、Indranil Mondal、Yogesh Kumar、Nikhil Kumar Singh、Daya Shankar Pandey

  DOI：10.1016/j.ica.2024.122113

  日期：2024.9

  described. Complexes – have been meticulously characterized by spectroscopic studies (ESI-MS, IR, H, C NMR, UV–vis) and their structures unambiguously confirmed by X-ray single crystal analyses. Electrocatalytic properties of the complexes toward hydrogen evolution reaction have been investigated by cyclic voltammetric studies in an organic medium in the presence of acetic acid as a weak proton source

  描述了使用含有氧化还原活性二吡啉和二硫代氨基甲酸酯配体的新型杂配 Ni(II) 配合物，核性对电化学氢产生的影响。配合物——通过光谱研究（ESI-MS、IR、H、C NMR、UV-vis）进行了细致的表征，并且通过 X 射线单晶分析明确证实了它们的结构。在有机介质中，在乙酸作为弱质子源的存在下，通过循环伏安研究研究了配合物对析氢反应的电催化性能。值得注意的是，在乙酸存在下，通过双重还原的 Ni(II) 物质（即 Ni(0)）络合并产生 H。此外，这些配合物表现出显着的电催化活性（TOF：264 () 和 650 s ()。受控电位电解建立的最小法拉第效率为 92 () 和 96 % ()。配合物相对于 表现出更高的周转频率，同时表现出较低的过电势(0.35 V) 与 (0.45 V) 相比，复合物的稳定性和产生的 H 量已通过本体电解研究进行了研究（ECEC；E，电子和 C，化学步骤）并涉
• Heteroleptic Dipyrrinato Complexes Containing 5-Ferrocenyldipyrromethene and Dithiocarbamates as Coligands: Selective Chromogenic and Redox Probes
  作者：Rakesh Kumar Gupta、Rampal Pandey、Roopshikha Singh、Nitin Srivastava、Biswajit Maiti、Satyen Saha、Peizhou Li、Qiang Xu、Daya Shankar Pandey

  DOI：10.1021/ic300900m

  日期：2012.8.20

  Six heteroleptic dipyrrinato complexes [Ni(fcdpm)(dedtc)] (1), [Ni(fcdpm)(dipdtc)] (2), [Ni(fcdpm)(dbdtc)] (3), [Pd(fcdpm)(dedtc)] (4), [Pd(fcdpm)(dipdtc)] (5), and [Pd(fcdpm)(dbdtc)] (6) (fcdpm = 5-ferrocenyldipyrromethene; dedtc = diethyldithiocarbamate; dipdtc = diisopropyldithiocarbamate; dbdtc = dibutyldithiocarbamate) have been synthesized and characterized by elemental analyses and spectral (ESI-MS, IR, H-1, C-13 NMR, UV-vis) and electrochemical studies. Crystal structures of!, 2, 4, and 5 have been authenticated by X-ray single-crystal analyses. Nickel-based complexes 1-3 display selective chromogenic and redox sensing for Hg2+ and Pb2+ ions, while palladium complexes 4-6 display selective chromogenic and redox sensing only for Hg2+. Electronic absorption, ESI-MS, and electrochemical studies indicated that sensing arises from interaction between 1-3 and Hg2+/Pb2+ through sulfur of the coordinated dithiocarbamates, while it arises from the pyrrolic nitrogen of fcdpm and dithiocarbamate sulfur from 4-6 and Hg2+. Different modes of binding between Ni and Pd complexes have further been supported by theoretical studies. The receptor-cation binding constants (K-a) and stoichiometry between probes and Hg2+/Pb2+ have been estimated by the Benesi-Hildebrand method and Job's plot analysis. Detection limits for 1-3 toward Hg2+/Pb2+ and 4-6 for Hg2+ have been found to be reasonably high.
• Manohar; Ramalingam; Thiruneelakandan, Zeitschrift fur Anorganische und Allgemeine Chemie, 2001, vol. 627, # 5, p. 1103 - 1108
  作者：Manohar、Ramalingam、Thiruneelakandan、Bocelli、Righi, Lara

  DOI：——

  日期：——