(1,4,7-trimethyl-1,4,7-triazacyclononane)MoI3 | 94370-81-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: (1,4,7-trimethyl-1,4,7-triazacyclononane)MoI3
• CAS: 94370-81-7
• 化学式: C₉H₂₁I₃MoN₃
• 分子量: 647.939
• InChiKey: MKRUVMYYLRXHCT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (1,4,7-trimethyl-1,4,7-triazacyclononane)MoI3 在 air 作用下， 以 甲醇 、 硝酸 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, properties and crystal structures of [Mo^VL(O)l₂]PF_6′[Mo^IVL(O)l₂], [Mo^VL(O)(OMe)₂]PF_6′[Mo^VILO₂(OMe)]BPh₄and [Mo₂L₂O₃(µ-O)l][BPh₄]₂(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)

  摘要：

  A series of mononuclear oxomolybdenum-(IV), -(V) and -(VI) complexes has been prepared from the precursor complex [Mo(V)L(O)I2]PF6 2 where L = 1,4,7-trimethyl-1,4,7-triazacyclononane. Compound 2 is reduced by NEt3 in MeCN yielding [Mo(IV)L(O)I2] 3. The iodide ligands in 2 may be substituted by alkoxy ligands generating paramagnetic mononuclear complexes [Mo(V)L(O)(OMe)I]PF6 4 and [Mo(V)L(O)(OMe)2]PF6 5. The latter is oxidized by H2O2 to [Mo(VI)LO2(OMe)]BPh4 6. Complex 2 was found to form the dinuclear diamagnetic species [Mo(V)2L2O2(mu-O)I2][PF6]2 7 which generates the asymmetric, diamagnetic mixed-valence complex [I(O)LMo(IV)(mu-O)Mo(VI)LO2]BPh4 8 in the presence of NaOH. Complex 8 undergoes a reversible one-electron-transfer oxidation and paramagnetic [I(O)LMo(V)(mu-O)Mo(VI)LO2][BPh4]2 9 has been isolated. The electrochemical, magnetic, and electronic structural as well as infrared and ESR spectral properties of the new complexes have been investigated. The structures of 2, 3, 5, 6 and 9 have been determined by X-ray crystallography.

  DOI：

  10.1039/dt9930001987
• 作为产物：
  描述：

  fac-Mo(CO)3(1,4,7-trimethyl-1,4,7-triazacyclononane) 在 iodine 作用下， 以 further solvent(s) 为溶剂， 以64%的产率得到(1,4,7-trimethyl-1,4,7-triazacyclononane)MoI3
  参考文献：
  名称：

  Synthesis, properties and crystal structures of [Mo^VL(O)l₂]PF_6′[Mo^IVL(O)l₂], [Mo^VL(O)(OMe)₂]PF_6′[Mo^VILO₂(OMe)]BPh₄and [Mo₂L₂O₃(µ-O)l][BPh₄]₂(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)

  摘要：

  A series of mononuclear oxomolybdenum-(IV), -(V) and -(VI) complexes has been prepared from the precursor complex [Mo(V)L(O)I2]PF6 2 where L = 1,4,7-trimethyl-1,4,7-triazacyclononane. Compound 2 is reduced by NEt3 in MeCN yielding [Mo(IV)L(O)I2] 3. The iodide ligands in 2 may be substituted by alkoxy ligands generating paramagnetic mononuclear complexes [Mo(V)L(O)(OMe)I]PF6 4 and [Mo(V)L(O)(OMe)2]PF6 5. The latter is oxidized by H2O2 to [Mo(VI)LO2(OMe)]BPh4 6. Complex 2 was found to form the dinuclear diamagnetic species [Mo(V)2L2O2(mu-O)I2][PF6]2 7 which generates the asymmetric, diamagnetic mixed-valence complex [I(O)LMo(IV)(mu-O)Mo(VI)LO2]BPh4 8 in the presence of NaOH. Complex 8 undergoes a reversible one-electron-transfer oxidation and paramagnetic [I(O)LMo(V)(mu-O)Mo(VI)LO2][BPh4]2 9 has been isolated. The electrochemical, magnetic, and electronic structural as well as infrared and ESR spectral properties of the new complexes have been investigated. The structures of 2, 3, 5, 6 and 9 have been determined by X-ray crystallography.

  DOI：

  10.1039/dt9930001987

文献信息

• Mohammed, Abdul K.; Isovitsch, Ralph A.; Maverick, Andrew W., Inorganic Chemistry, 1998, vol. 37, # 11, p. 2779 - 2785
  作者：Mohammed, Abdul K.、Isovitsch, Ralph A.、Maverick, Andrew W.

  DOI：——

  日期：——
• Backes-Dahmann, Gabriele; Herrmann, Willy; Wieghardt, Karl, Inorganic Chemistry, 1985, vol. 24, # 4, p. 485 - 491
  作者：Backes-Dahmann, Gabriele、Herrmann, Willy、Wieghardt, Karl、Weiss, Johannes

  DOI：——

  日期：——