tribut-3-enyl-triazinetrione | 82106-82-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: tribut-3-enyl-triazinetrione
• 英文别名: tri(3-butenyl) isocyanurate；1,3,5-tris-(3-butenyl)-isocyanurate；tri-but-3-enyl isocyanurate；1,3,5-Tris(but-3-enyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 82106-82-9
• 化学式: C₁₅H₂₁N₃O₃
• 分子量: 291.35
• InChiKey: GADKTYSTRRYUGD-UHFFFAOYSA-N

物化性质

• 沸点：
  403.8±44.0 °C(Predicted)
• 密度：
  1.094±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  21
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  60.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tribut-3-enyl-triazinetrione 在 碳酸氢钠 、 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 反应 18.0h， 生成 1-But-3-enyl-3,5-bis[2-(oxiran-2-yl)ethyl]-1,3,5-triazinane-2,4,6-trione
  参考文献：
  名称：

  ISOCYANURATE EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING SAME, COMPOSITION INCLUDING SAME, CURED PRODUCT OF THE COMPOSITION, AND USE OF THE COMPOSITION

  摘要：

  公开号：

  EP2774929B1
• 作为产物：
  描述：

  4-溴-1-丁烯 、 sodium cyanurate 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以46%的产率得到tribut-3-enyl-triazinetrione
  参考文献：
  名称：

  Fischer; Zeidler; Budnowski, Arzneimittel-Forschung/Drug Research, 1984, vol. 34, # 5, p. 543 - 547

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING EPOXY COMPOUND CONTAINING HYDROGEN PEROXIDE STABILIZER
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20170275258A1

  公开（公告）日：2017-09-28

  The present invention provides a method for producing an epoxy compound by a reaction of an olefin compound with hydrogen peroxide, wherein the epoxy compound is stably and safely produced using a hydrogen peroxide stabilizer for reducing an oxygen gas generated from hydrogen peroxide. A method for producing an epoxy compound by a reaction of an olefin compound with hydrogen peroxide, wherein the reaction is carried out in the presence of an organophosphorus compound in such a reaction medium that the pH is maintained within a range of more than 7.5 and less than 12.0. The olefin compound may be 1,3,5-tris-(alkenyl)-isocyanurate. The alkenyl group in the olefin compound may be 3-butenyl group, 4-pentenyl group, 5-hexenyl group, 6-heptenyl group, or 7-octenyl group. The epoxy compound may be 1,3,5-tris-(epoxyalkyl)-isocyanurate. The reaction medium may be such a reaction medium that the pH is maintained within a range of 8.0 to 10.5.

  本发明提供了一种通过烯烃化合物与过氧化氢反应制备环氧化合物的方法，其中使用过氧化氢稳定剂来减少从过氧化氢产生的氧气，从而稳定且安全地生产环氧化合物。该方法是在存在有机磷化合物的反应介质中进行反应，该反应介质的pH值保持在7.5以上且小于12.0的范围内。烯烃化合物可以是1,3,5-三（烯基）-异氰酸酯。烯基化合物中的烯基可以是3-丁烯基，4-戊烯基，5-己烯基，6-庚烯基或7-辛烯基。环氧化合物可以是1,3,5-三（环氧烷基）-异氰酸酯。反应介质可以是pH值保持在8.0至10.5的反应介质。
• LONG-CHAIN ALKYLENE-CONTAINING CURABLE EPOXY RESIN COMPOSITION
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP2530098A1

  公开（公告）日：2012-12-05

  There is provided a curable composition that maintains good handleability in the liquid form and that can be photo- or heat-cured to form a cured product having physical properties including both high transparency and high flexural strength. A curable composition comprising: an epoxy compound of Formula (1): [where each of E1, E2, and E3 is independently an organic group of Formula (2) or Formula (3); and each of R1, R2, and R3 is independently an optionally branched C2-6 alkylene group or oxyalkylene group: (where R4 is a hydrogen atom or a methyl group)]; and an acid generator.

  本发明提供了一种可固化组合物，该组合物在液态时可保持良好的可操作性，并可通过光固化或热固化形成具有高透明度和高抗折强度等物理性能的固化产品。可固化组合物包括：式（1）的环氧化合物： [其中 E1、E2 和 E3 各自独立地为式（2）或式（3）的有机基团；R1、R2 和 R3 各自独立地为任选支化的 C2-6 烷基或氧亚烷基： (其中 R4 为氢原子或甲基）]；以及一种酸发生器。
• LIGHT-CURING RESIN COMPOSITION
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP2762517A1

  公开（公告）日：2014-08-06

  There is provided a curable resin composition that exhibits high adhesive properties to materials such as glass, copper, aluminum, PET, and PC, which have been regarded as poor adherends relative to photo-curable compositions, and high adhesive properties also between adherends different from each other. A curable resin composition comprising a polyene compound of Formula (1): (where n1, n2, and n3 are each independently an integer of 2 to 4; and R1 to R9 are each independently a hydrogen atom or a Cmo alkyl group). The composition may further comprise a thiol compound or a photopolymerization initiator. The thiol compound may be a compound having two to six thiol groups in the molecule, or be an aliphatic thiol, or be produced by a reaction of an aliphatic mercapto carboxylic acid and a polyhydric alcohol. The polyhydric alcohol may be an aliphatic polyhydric alcohol or hydroxyalkyl isocyanurate.

  本发明提供了一种可固化树脂组合物，该组合物对玻璃、铜、铝、 PET 和 PC 等材料具有较高的粘合性，这些材料相对于光固化组合物而言一直被认为是粘合性较差的材料，并且在不同的粘合剂之间也具有较高的粘合性。一种可固化树脂组合物，包含式（1）的聚烯化合物： (其中 n1、n2 和 n3 各自独立地为 2 至 4 的整数；R1 至 R9 各自独立地为氢原子或 Cmo 烷基）。组合物可进一步包含硫醇化合物或光聚合引发剂。硫醇化合物可以是分子中含有 2 到 6 个硫醇基团的化合物，或者是脂肪族硫醇，或者是由脂肪族巯基羧酸和多元醇反应生成的。多元醇可以是脂肪族多元醇或羟烷基异氰脲酸酯。
• METHOD FOR PRODUCING EPOXY COMPOUND
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP2913331A1

  公开（公告）日：2015-09-02

  There is provided a method for producing an epoxy compound having an epoxy ring bonded to a triazinetrione ring via a long chain alkylene group, an olefin compound having a specific structure is used to efficiently obtain an epoxy compound of which an olefin moiety is epoxidized in high yield. A method for producing an epoxy compound of Formula (2): comprising reacting a triolefin compound of the following Formula (1): (In the above-mentioned Formulae, R1 to R9 are each independently a hydrogen atom or a methyl group; and n1 to n3 are each independently an integer of 1 to 4) with hydrogen peroxide, a nitrile compound, and an alkaline substance in a solvent. The nitrile compound is an aliphatic nitrile compound or an aromatic nitrile compound. The alkaline substance is phosphate, carbonate, or an alkaline metal hydroxide.

  提供了一种生产环氧化合物的方法，该环氧化合物具有通过长链亚烷基键合到三嗪三酮环上的环氧环，使用具有特定结构的烯烃化合物可有效地获得环氧化合物，其中的烯烃分子以高收率环氧化。一种生产式（2）环氧化合物的方法： 包括使下式（1）的三烯烃化合物反应： (在上述式中，R1 至 R9 各自独立地为氢原子或甲基；n1 至 n3 各自独立地为 1 至 4 的整数）与过氧化氢、腈化合物和碱性物质在溶剂中反应。腈化合物是脂肪族腈化合物或芳香族腈化合物。碱性物质为磷酸盐、碳酸盐或碱金属氢氧化物。
• NONAQUEOUS ELECTROLYTE SOLUTION AND NONAQUEOUS ELECTROLYTE BATTERY
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3780226A1

  公开（公告）日：2021-02-17

  Provided is a nonaqueous electrolyte battery in which not only the generation of a gas during high-temperature storage but also an increase in the battery resistance are inhibited. Also provided is a nonaqueous electrolyte solution containing: a compound represented by the following Formula (A); a cyclic carbonate having an unsaturated carbon-carbon bond; and at least one compound selected from the group consisting of compounds represented by the following Formula (B) or (C). In this nonaqueous electrolyte solution, the content of the cyclic carbonate having an unsaturated carbon-carbon bond with respect to a total amount of the nonaqueous electrolyte solution is in a specific range, and the content of the at least one compound selected from the group consisting of compounds represented by Formula (B) or (C) is in a specific range.         OCN-Q-NCO     (C)

  本发明提供了一种非水电解质电池，它不仅能抑制高温储存期间气体的产生，还能抑制电池电阻的增加。本发明还提供了一种非水电解质溶液，其中含有：由下式（A）代表的化合物；具有不饱和碳碳键的环状碳酸盐；以及至少一种选自由下式（B）或（C）代表的化合物组成的化合物组。在该非水电解质溶液中，具有不饱和碳-碳键的环状碳酸盐的含量占该非水电解质溶液总量的比例在特定范围内，至少一种选自由式（B）或（C）代表的化合物组成的组的化合物的含量在特定范围内。 OCN-Q-NCO (C)