N,N,N′,N′-tetra-n-hexylurea | 13020-52-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: N,N,N′,N′-tetra-n-hexylurea
• 英文别名: THU；N,N,N',N'-tetrahexylurea；Tetrahexyl-harnstoff；1,1,3,3-Tetrahexylurea
• CAS: 13020-52-5
• 化学式: C₂₅H₅₂N₂O
• 分子量: 396.701
• InChiKey: ISEOFGHWDGAQID-UHFFFAOYSA-N

物化性质

• 沸点：
  213 °C(Press: 0.1 Torr)
• 密度：
  0.876±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  28
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.96
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N,N′,N′-tetra-n-hexylurea 在 光气 、 三乙胺 作用下， 以 乙腈 为溶剂， 反应 1.0h， 生成 N-(bis(dihexylamino)methylene)-N-hexylhexan-1-aminium chloride
  参考文献：
  名称：

  Orthoamide，LXIX [1]。合成这些 N,N,N´,N´,N´´-过烷基胍和 N,N,N´,N´,N´´䞲,N´´-persubstituierter Guanidiniumsalze / Orthoamides, LXIX [1]。对合成 N、N、N'、N'、N'-全烷基化胍和 N、N、N'、N'、N''、N''-全取代胍盐的贡献

  摘要：

  N, N, N', N'-四烷基氯甲脒氯化物 6 由 N, N, N', N'-四烷基脲 5 和光气在乙腈中制备。亚胺盐 6 在三乙胺存在下与伯胺和仲胺反应，得到 N、N、N'、N'、N''-五取代和 N、N、N'、N'、N''、N'' - 六取代胍盐 7 和 8，分别用过量的氢氧化钠处理胍盐 7，得到 N、N、N'N'、N''-五取代的胍 9a-9aa。此外，N、N、N'、N'、N''-五取代和 N、N、N'、N'、N''、N''-六取代的胍盐 7l'、7p' 和 8a-c 可以通过加入化学计量量的氢氧化钠从反应混合物中获得。描述了一种用于制备具有由两个长链烷基 (> C14) 组成的二烷基氨基取代基的胍盐的改进方法。一些胍 9 与烯丙基氯和溴、乙基溴、丁基溴、苄基溴和氯、硫酸二甲酯、硫酸二乙酯和甲磺酸甲酯烷基化，得到相应的胍盐 11-15。 通过 N、N、N 的烷基化´, N´, N´´-五取代胍

  DOI：

  10.1515/znb-2010-0712

文献信息

• SINGLE LAYER FILM AND HYDROPHILIC MATERIAL COMPOSED OF SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1955782A1

  公开（公告）日：2008-08-13

  A single layer film containing at least one anionic hydrophilic group selected from a sulfonic acid group, a carboxyl group and a phosphate group, wherein an anion concentration ratio (Sa/Da) of an anion concentration at a surface (Sa) to an anion concentration at a deep part (Da) is 1.1 or more. The single layer film is a copolymer prepared by polymerizing a composition containing a compound (I) represented by the general formula (1) ([X]s[M1]1[M2]m (1)) and a compound (II) having two or more (meth)acryloyl groups in a molecule at a molar ratio of 15:1 to 1: 30 and having a water contact angle of 30° or less. Such a single layer film has high hydrophilicity and surface hardness and is excellent in antifogging property, antifouling property and antistatic property, thus is useful as an antifogging material, an antifouling material, an antistatic material and a multilayer body.

  一种单层薄膜，含有至少一个选自磺酸基、羧基和磷酸基的阴离子亲水基团，其中表层阴离子浓度（Sa）与深层阴离子浓度（Da）之比（Sa/Da）为 1.1 或以上。单层膜是一种共聚物，它是通过聚合含有通式(1)（[X]s[M1]1[M2]m (1)）表示的化合物(I)和分子中含有两个或两个以上(甲基)丙烯酰基的化合物(II)的组合物制备而成，摩尔比为 15:1 至 1:30，水接触角为 30°或更小。这种单层薄膜具有高亲水性和表面硬度，防雾性能、防污性能和抗静电性能优异，因此可用作防雾材料、防污材料、抗静电材料和多层体。
• MONOLAYER FILM AND HYDROPHILIC MATERIAL COMPRISING SAME
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2738188A1

  公开（公告）日：2014-06-04

  The invention provides monolayer films which not only have hydrophilicity and are excellent in such properties as antifogging properties, antifouling properties, antistatic properties and anti-condensation properties but also tend to exhibit excellent transparency even with a large film thickness and excellent scratch resistance, as well as stacks having the monolayer film. The monolayer film is obtained by preparing a mixture including a monomer composition and a solvent, the monomer composition including a specific monomer and a polyvalent monomer having two or more (meth)acryloyl groups and being free of sulfonic group, carboxyl group and phosphoric group in a specific molar ratio, the solvent having a specific solubility parameter σ; applying the mixture onto a substrate and removing at least part of the solvent; and polymerizing the monomer composition to produce a monolayer film having at least one anionic hydrophilic group selected from a sulfonic group, a carboxyl group and a phosphoric group and a specific anion concentration ratio (Sa/Da) of the anion concentration (Sa) at the outer surface to the anion concentration (Da) at the middle point between the inner surface in contact with the substrate and the outer surface.

  本发明提供的单层膜不仅具有亲水性，在防雾性、防污性、抗静电性和抗凝结性等性能方面表现优异，而且即使膜厚较大也往往表现出优异的透明度和优异的抗划伤性，同时还提供具有该单层膜的叠层。单层膜是通过以下方法获得的：制备包括单体组合物和溶剂的混合物，单体组合物包括特定单体和具有两个或两个以上（甲基）丙烯酰基且不含磺酸基、羧基和磷酸基的多价单体，其摩尔比为特定比例，溶剂具有特定的溶解度参数σ；将混合物涂在基底上，然后除去至少部分溶剂；使单体组合物聚合，生成单层膜，该膜具有至少一个选自磺酸基、羧基和磷酸基的阴离子亲水基团，且外表面的阴离子浓度 (Sa) 与与基底接触的内表面和外表面之间的中间点的阴离子浓度 (Da) 具有特定的阴离子浓度比 (Sa/Da)。
• Fluorine-containing cyclic olefin polymer composition, imprint product obtained using the composition, and method for producing the same
  申请人：Mitsui Chemicals, Inc.

  公开号：US10000633B2

  公开（公告）日：2018-06-19

  A fluorine-containing cyclic olefin polymer composition of the present invention includes a fluorine-containing cyclic olefin polymer (A) containing a repeating structural unit represented by the general formula (1) and having a fluorine atom content rate of 40 to 75% by mass; a photocurable compound (B); and a photocuring initiator (C).

  本发明的含氟环状烯烃聚合物组合物包括：含氟环状烯烃聚合物（A），该聚合物含有通式（1）所代表的重复结构单元，氟原子的质量含量为 40% 至 75%；光固化化合物（B）；以及光固化引发剂（C）。
• Method for the continuous production of tetra-substituted ureas
  申请人：Henkelmann Jochen

  公开号：US20050261524A1

  公开（公告）日：2005-11-24

  The invention relates to a process for the preparation of tetrasubstituted ureas by reaction of the corresponding amines with phosgene in the presence of an aqueous inorganic base at a temperature in the range from 0 to 150° C., which comprises: feeding the corresponding amine, the phosgene and the aqueous inorganic base on average continuously to the reaction apparatus, forming a two-phase system in the reaction apparatus through the choice of the tetrasubstituted ureas to be prepared, through the mixing ratios of the substances and substance mixtures to be fed in, through the temperature during the reaction and, where appropriate, through the feed of an organic solvent which is not completely miscible with water, and discharging the reaction mixture on average continuously from the reaction apparatus.

  本发明涉及一种制备四取代脲的工艺，该工艺是在无机水基存在下，在 0 至 150 摄氏度的温度范围内，通过相应的胺与光气反应制备四取代脲、其中包括：将相应的胺、光气和水性无机碱平均连续地加入反应装置中，通过选择要制备的四代脲，通过加入的物质和物质混合物的混合比，通过反应过程中的温度，并酌情通过加入与水不完全混溶的有机溶剂，在反应装置中形成两相体系，并将反应混合物平均连续地从反应装置中排出。
• Production of urethane compounds
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0083096B1

  公开（公告）日：1987-02-25