Tert-butyl-(5-ethenoxy-6-methylhept-6-enoxy)-dimethylsilane | 512278-04-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Tert-butyl-(5-ethenoxy-6-methylhept-6-enoxy)-dimethylsilane
• CAS: 512278-04-5
• 化学式: C₁₆H₃₂O₂Si
• 分子量: 284.514
• InChiKey: ACARGSPXMWZNET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.28
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Tert-butyl-(5-ethenoxy-6-methylhept-6-enoxy)-dimethylsilane 在 mercury(II) diacetate 、 水 、 sodium hexamethyldisilazane 、 mercury(II) trifluoroacetate 、 lithium 、 戴斯-马丁氧化剂 、 溶剂黄146 作用下， 以 苯 为溶剂， 生成
  参考文献：
  名称：

  6-endo,6-endo,6-exo Cascade cyclization starting from vinyl radical; construction of a dodecahydrophenanthrene system

  摘要：

  Treatment of 1-iodo-1,5-diene 3 with Bu3SnH at 80 degrees C afforded the 6-endo cyclized product 6. The reaction was extended further to achieve the transformation of 1-iodo-1,5,9,14-tetraene 10 into dodecahydrophenanthrene 11 under one electron reductive conditions via 6-endo,6-endo,6-exo cascade cyclization. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01234-4
• 作为产物：
  描述：

  5-((叔丁基二甲基甲硅烷基)氧基)戊醛 在 mercury(II) diacetate 、 mercury(II) trifluoroacetate 、 lithium 作用下， 生成 Tert-butyl-(5-ethenoxy-6-methylhept-6-enoxy)-dimethylsilane
  参考文献：
  名称：

  6-endo,6-endo,6-exo Cascade cyclization starting from vinyl radical; construction of a dodecahydrophenanthrene system

  摘要：

  Treatment of 1-iodo-1,5-diene 3 with Bu3SnH at 80 degrees C afforded the 6-endo cyclized product 6. The reaction was extended further to achieve the transformation of 1-iodo-1,5,9,14-tetraene 10 into dodecahydrophenanthrene 11 under one electron reductive conditions via 6-endo,6-endo,6-exo cascade cyclization. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01234-4

文献信息

• 6-endo,6-endo,6-exo Cascade cyclization starting from vinyl radical; construction of a dodecahydrophenanthrene system
  作者：Kiyosei Takasu、Jun-ichi Kuroyanagi、Akira Katsumata、Masataka Ihara

  DOI：10.1016/s0040-4039(99)01234-4

  日期：1999.8

  Treatment of 1-iodo-1,5-diene 3 with Bu3SnH at 80 degrees C afforded the 6-endo cyclized product 6. The reaction was extended further to achieve the transformation of 1-iodo-1,5,9,14-tetraene 10 into dodecahydrophenanthrene 11 under one electron reductive conditions via 6-endo,6-endo,6-exo cascade cyclization. (C) 1999 Elsevier Science Ltd. All rights reserved.