1,3-dicyclohexyl-imidazolidine | 200068-65-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 1,3-dicyclohexyl-imidazolidine
• 英文别名: 1,3-Dicyclohexyl-imidazolidin；1,3-Dicyclohexylimidazolidine
• CAS: 200068-65-1
• 化学式: C₁₅H₂₈N₂
• 分子量: 236.401
• InChiKey: KVWRWYHVNAAYHJ-UHFFFAOYSA-N

物化性质

• 熔点：
  13-15 °C
• 沸点：
  137-138 °C(Press: 0.7 Torr)
• 密度：
  1.023±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-dicyclohexyl-imidazolidine 在 硝酸 作用下， 生成 N,N'-dicyclohexyl-N-nitro-ethylenediamine
  参考文献：
  名称：

  An Intermediate in the Nitrolysis of 1,3-Dicyclohexylimidazolidine

  摘要：

  DOI：

  10.1021/jo50007a008
• 作为产物：
  描述：

  N,N'-二环己基-1,2-二胺 在 聚合甲醛 作用下， 生成 1,3-dicyclohexyl-imidazolidine
  参考文献：
  名称：

  REACTIONS OF MONO- AND DI-AMINES WITH CARBON DISULFIDE. II. METHYLENEDIAMINE AND IMIDAZOLIDINE-CARBON DISULFIDE REACTIONS¹

  摘要：

  DOI：

  10.1021/jo01158a004

文献信息

• CYCLOADDITION OF AZIDES AND ALKYNES
  申请人：Nolan Steven P.

  公开号：US20090069569A1

  公开（公告）日：2009-03-12

  This invention provides a process which comprises contacting, in a reaction zone, at least one organic azide, at least one alkyne, and at least one N-heterocyclic carbene copper compound in which the ligands are either (i) a halide and an N-heterocyclic carbene or (ii) two N-heterocyclic carbenes and a BF 4 − or PF 6 − anion, to form a 1,2,3-triazole in which at least the 1 and 4 positions each has a substituent. The N-heterocyclic carbene either an imidazol-2-ylidene in which the 1 and the 3 positions each has a substituent which has at least one carbon atom, or a 4,5-dihydro-imidazol-2-ylidene in which the 1 and the 3 positions each has a substituent which has at least one carbon atom.

  这项发明提供了一种方法，其中包括在反应区域中接触至少一种有机叠氮化合物、至少一种炔烃以及至少一种N-杂环卡宾铜化合物，其中配体可以是（i）一种卤素和一种N-杂环卡宾，或者（ii）两种N-杂环卡宾和一个BF4−或PF6−阴离子，以形成一种1,2,3-三唑，其中至少1和4位置各具有一个取代基。N-杂环卡宾可以是1,3位置各具有至少一个碳原子的咪唑-2-基卡宾，或者是1,3位置各具有至少一个碳原子的4,5-二氢咪唑-2-基卡宾。
• RUTHENIUM COMPLEX, METHOD FOR PRODUCING SAME, AND USE OF SAME
  申请人：Takasago International Corporation

  公开号：US20170044196A1

  公开（公告）日：2017-02-16

  The present invention provides a novel ruthenium complex that is easy to produce and handle and that can be supplied relatively inexpensively, a method for producing this ruthenium complex, a method for producing alcohols and the like using this ruthenium complex as a catalyst, a method for producing carbonyl compounds using this ruthenium complex as a catalyst, and a method for producing N-alkylamine compounds using this ruthenium complex as a catalyst. The present invention pertains to a ruthenium complex represented by general formula (1) RuX 1 X 2 (PNP) (NHC) m (Solv) n (1) (in general formula (1), X 1 and X 2 each independently represent a monovalent anionic monodentate ligand; PNP represents a tridentate aminodiphosphine ligand, NHC represents an N-heterocyclic carbene derived from a nitrogen-containing heterocyclic ring, and Solv represents a coordinating solvent; and m represents an integer from 1 to 3, n represents an integer from 0 to 2, and 1≦m+n≦3.), a method for producing the same, a catalyst including the same, and methods for producing various organic compounds using this catalyst.

  本发明提供了一种新型的钌配合物，易于生产和处理，成本相对较低，以及使用该钌配合物作为催化剂生产醇类等物质的方法，使用该钌配合物作为催化剂生产羰基化合物的方法，以及使用该钌配合物作为催化剂生产N-烷基胺化合物的方法。本发明涉及一种由通式（1）RuX1X2(PNP) (NHC)m(Solv)n(1)表示的钌配合物（在通式（1）中，X1和X2分别独立表示一价阴离子的单齿配体；PNP表示三齿氨基二膦配体，NHC表示源自含氮杂环环的N-杂环卡宾，Solv表示配位溶剂；m表示1到3之间的整数，n表示0到2之间的整数，且1≦m+n≦3），以及生产该钌配合物的方法，包括该配合物的催化剂，以及使用该催化剂生产各种有机化合物的方法。
• [EN] PROCESS FOR PRODUCING N-(HETERO)ARYLAZOLES<br/>[FR] PROCÉDÉ DE PRODUCTION DE N-(HÉTÉRO)ARYLAZOLES
  申请人：TAKASAGO PERFUMERY CO LTD

  公开号：WO2013032035A1

  公开（公告）日：2013-03-07

  The present invention provides a process for effectively producing an N-(hetero)arylazole with high yield, which is useful as a medical or agrochemical product, an organic photoconductor material, an organic electroluminescent element material, or the like. The present invention relates to a process for producing an N-(hetero)arylazole, which includes reacting a (hetero)aryl (pseudo)halide with an NH-azole in the presence of: a catalyst including a palladium compound and a coordination compound; and a basic magnesium compound.

  本发明提供了一种有效生产高产率的N-(杂)芳唑的方法，该方法可用作医药或农药产品、有机光导体材料、有机电致发光元件材料等。本发明涉及一种生产N-(杂)芳唑的方法，包括在存在催化剂包括钯化合物和配位化合物以及碱性镁化合物的情况下，将(杂)芳(伪)卤化物与NH-唑反应。
• CATALYSTS FOR EFFICIENT Z-SELECTIVE METATHESIS
  申请人：Trustees of Boston College

  公开号：US20140371454A1

  公开（公告）日：2014-12-18

  The present application provides, among other things, compounds and methods for metathesis reactions. In some embodiments, provided compounds promote highly efficient and highly Z-selective metathesis. In some embodiments, provided compounds and methods are particularly useful for producing allyl alcohols. In some embodiments, provided compounds have the structure of formula I. In some embodiments, provided compounds comprise ruthenium, and a ligand bonded to ruthenium through a sulfur atom.

  本申请提供了化合物和用于交换反应的方法，其中所提供的化合物在某些实施方式中促进高效和高度Z-选择性的交换反应。在某些实施方式中，所提供的化合物和方法特别适用于生产烯丙醇。在某些实施方式中，所提供的化合物具有式I的结构。在某些实施方式中，所提供的化合物包含钌，并且与钌通过硫原子结合的配体。
• Process for Production of 2-(Substituted Phenyl)-3,3,3-Trifluoropropene Compound
  申请人：Matoba Kazutaka

  公开号：US20100160683A1

  公开（公告）日：2010-06-24

  There is provided a novel process for production of a 2-(substituted phenyl)-3,3,3-trifluoropropene. Disclosed is a process for production of a 2-(substituted phenyl)-3,3,3-trifluoropropene compound represented by the formula (7) or a salt thereof The process comprises reacting a compound represented by the formula (1) (X is an alkyl group, etc.) with a compound represented by the formula (2) (Y is a halogen atom, etc.) in the presence of a catalyst represented by the formula (3) (M is an ion of a metal belonging to Group 10 on the elementary periodic table which has an oxidation state number of 1 to 8; G is a unidentate or multidentate ligand; L is a phosphine compound represented by the formula (4) which is bound to the center metal M or is a carbene selected from those represented by the formulae (5) and (6), provided that L's may be same as or different from one another when a is 2 to 5; A represents a univalently or multivalently charged anion; b represents an integer of 1 to 3; a represents an integer of 1 to 5·b; c represents 0 or an integer of 1 to 4·b; and n represents an integer of 1 to 6).

  提供了一种生产2-(取代苯基)-3,3,3-三氟丙烯的新型工艺。公开了一种生产由式(7)表示的2-(取代苯基)-3,3,3-三氟丙烯化合物或其盐的工艺。该工艺包括在催化剂的存在下，将由式(1)表示的化合物（其中X为烷基等）与由式(2)表示的化合物（其中Y为卤素原子等）反应。催化剂由式(3)表示（其中M是元素周期表上属于第10族金属的离子，其氧化态数为1至8；G是单齿或多齿配体；L是与中心金属M结合的磷化合物，由式(4)表示，或者是从由式(5)和(6)表示的卡宾中选择的卡宾，但当a为2至5时，L可能相同也可能不同；A表示单价或多价带电阴离子；b表示1至3的整数；a表示1至5·b的整数；c表示0或1至4·b的整数；n表示1至6的整数）。