bis(cyclopentadienyl)zirconium dichloride | 75699-46-6

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: bis(cyclopentadienyl)zirconium dichloride
• 英文别名: bis(η5-cyclopentadienyl)zirconium dichloride；bis(cyclopentadienyl) zirconium dichloride；di(cyclopentadienyl)zirconium dichloride；dichlorobiscyclopentadienyl zirconium；dicyclopentadienylzirconium chloride；Cl2Zr(cyclopentadienyl)2；Zirconocene dichioride；cyclopenta-1,3-diene;zirconium(2+);dichloride
• CAS: 75699-46-6
• 化学式: C₁₀H₁₀Cl₂Zr
• 分子量: 292.319
• InChiKey: OUGHJMMORHUQBY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.19
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(cyclopentadienyl)zirconium dichloride 、 甲基锂 在 氩 、 乙醚 作用下， 以 乙醚 为溶剂， 反应 1.67h， 生成 Zirconium(4+) bis(cyclopentadienide) dimethanide
  参考文献：
  名称：

  Photosensitive composition comprising aryl-substituted polysilane and

  摘要：

  本发明涉及一种光敏组合物，其包括具有以下一般式（1）所表示的重复单位的聚硅烷和具有有机过氧化物的苯并苯酮类化合物，其中Ar代表取代或未取代的芳基基团。 ##STR1##

  公开号：

  US05985513A1
• 作为产物：
  描述：

  dilithium 、 氯化锆(IV) 、 甲苯 在 正戊烷 作用下， 反应 48.0h， 以giving the zirconocene dichioride in a crude yield of 30% (2.72 g)的产率得到bis(cyclopentadienyl)zirconium dichloride
  参考文献：
  名称：

  Process for the preparation of polyolefins

  摘要：

  本发明涉及一种聚烯烃的制备方法，该方法通过在立体刚性的金属茂化合物存在下聚合至少一种烯烃，所述金属茂化合物包含至少两个取代或未取代的环戊二烯基配体，通过单环或多环环系统相互连接，其中至少一个环戊二烯基配体与单环或多环环系统融合。

  公开号：

  US05565534A1
• 作为试剂：
  描述：

  1-己烯 、 三乙基铝 在 bis(cyclopentadienyl)zirconium dichloride 、 盐酸 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 24.0h， 以16%的产率得到1-diethylalumina-2-ethylhexane
  参考文献：
  名称：

  On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes

  摘要：

  The influence of the organoaluminium compound nature, Zr p-ligand environment, solvent type and reagent ratio on the chemoselectivity of reactions of trialkylalanes (AlMe3, AlEt3) with alkenes, catalyzed with L2ZrCl2 [L = Cp, Cp' (Cp'-eta(5)-C5H4CH3), Cp* (Cp*-eta(5)-C-5(CH3)(5)), Ind (indenyl), Flu (fluorenyl)] has been studied. It is shown that in the case of AlMe3, the hydro-and carboalumination products, and alkene dimers are formed. The catalytic reaction of AlEt3 with the olefins yields aluminacyclopentanes altogether with the hydro-and carboalumination products, and the dimers. A probable reaction mechanism has been proposed. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.07.037

文献信息

• Process for the preparation of organometallic compounds
  申请人：Ciba-Geigy Corporation

  公开号：US04992572A1

  公开（公告）日：1991-02-12

  There is disclosed a process for the preparation of compounds of formula I [R Fe R.sup.2 ].sub.q.sup..sym. X.sup.q.crclbar. (I), wherein R is an anion of formula C.sub.5 H.sub.4 R.sup.1 or C.sub.9 H.sub.7, R.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl or halogen, R.sup.2 is a .pi.-arene, X is an anion of valency q and q is 1, 2 or 3, by reacting ferrocene or a ferrocene derivative (C.sub.5 H.sub.4 R.sup.3)Fe(C.sub.5 H.sub.4 R.sup.1) or (C.sub.9 H.sub.7).sub.2 Fe, in which R.sup.3 has one of the meanings of R.sup.1, with at least one mole of a .pi.-arene R.sup.2, followed by the optional replacement of the anion X.sup.q.crclbar. in a manner known per se, the reaction of the ferrocene or ferrocene derivative being carried out in the presence of (a) at least 1.2 mol of a mixture of Al trihalide and Zr(IV) or Hf(IV) tetrahalide, in the presence or absence of a metallic reducing agent, such that at least 0.2 mol of Zr(IV) or Hf(IV) tetrahalide and at least 0.1 mol of Al trihalide are present, or of (b) at least 1.0 mol of a Zr(IV) or Hf(IV) tetrahalide as sole Lewis acid in conjunction with at least 1.0 mol of a metallic reducing agent, the amounts being based in each case on 1 mol of ferrocene or a ferrocene derivative. The compounds of formula I containing non-nucleophilic anions can be used as photoinitiators for cationically polymerizable compounds.

  本发明涉及一种制备式I [RFeR.sup.2].sub.q.sup..sym. X.sup.q.crclbar. (I)化合物的方法，其中R是公式C.sub.5H.sub.4R.sup.1或C.sub.9H.sub.7的阴离子，R.sup.1是氢、C.sub.1-C.sub.6烷基或卤素，R.sup.2是.pi.-芳香烃，X是价态为q的阴离子，q为1、2或3，通过将二茂铁或二茂铁衍生物(C.sub.5H.sub.4R.sup.3)Fe(C.sub.5H.sub.4R.sup.1)或(C.sub.9H.sub.7).sub.2Fe（其中R.sup.3具有R.sup.1的一种含义）与至少一个摩尔的.pi.-芳香烃R.sup.2反应，随后按已知方式选择性地替换X.sup.q.crclbar.阴离子，二茂铁或二茂铁衍生物的反应在(a)至少1.2摩尔的Al三卤化物和Zr（IV）或Hf（IV）四卤化物的混合物存在下进行，存在或不存在金属还原剂，使至少存在0.2摩尔的Zr（IV）或Hf（IV）四卤化物和至少0.1摩尔的Al三卤化物，或(b)至少1.0摩尔的Zr（IV）或Hf（IV）四卤化物作为唯一的路易斯酸，与至少1.0摩尔的金属还原剂结合使用，每种情况下的量都是基于1摩尔的二茂铁或二茂铁衍生物。含有非亲核阴离子的式I化合物可用作阳离子聚合化合物的光引发剂。
• Metallocenes, and their use as catalysts
  申请人：Hoechst Aktiengesellschaft

  公开号：US05710297A1

  公开（公告）日：1998-01-20

  The present invention relates to a stereorigid metallocene compound containing, as ligands, at least two substituted or unsubstituted cyclopentadienyl groups which are bonded to one another via a monocyclic or polycyclic ring system, where at least one cyclopentadienyl group is fused to the monocyclic or polycyclic ring system, and to a process for the preparation of a cycloolefin copolymer. The cycloolefin copolymers obtained in this way have high tear strengths and are suitable for the production of extrusion parts and injection moldings.

  本发明涉及一种立体刚性的金属茂化合物，其含有至少两个取代或未取代的环戊二烯基配体，这些配体通过单环或多环环系统相互连接，其中至少一个环戊二烯基与单环或多环环系统融合，以及一种制备环烯共聚物的方法。通过这种方法获得的环烯共聚物具有高撕裂强度，适用于挤出件和注塑成型的生产。
• Catalyst system based on monoazadiene metal complexes
  申请人：Bayer AG

  公开号：US05965678A1

  公开（公告）日：1999-10-12

  The present invention relates to a catalyst system based on monoazadiene metal complexes of the formula ##STR1## and a co-catalyst suitable for activating the metal complex, and to the use of the catalyst system for the polymerization of unsaturated compounds, especially for the polymerization and copolymerization of olefins and/or dienes. The novel catalyst system is characterised in particular by its ease of access, its lack of sensitivity to external influences and its ease of handling.

  本发明涉及一种基于公式##STR1## 的单氮二烯金属配合物催化系统和适用于激活金属配合物的协同催化剂，以及使用该催化系统进行不饱和化合物的聚合，特别是进行烯烃和/或二烯的聚合和共聚合。该新型催化系统的特点在于易于获取，对外部影响不敏感且易于操作。
• Metallocenes as catalysts in the preparation of cycloolefin copolymers
  申请人：Targor GmbH

  公开号：US05990254A1

  公开（公告）日：1999-11-23

  The present invention relates to a stereorigid metallocene compound containing, as ligands, at least two substituted or unsubstituted cyclopentadienyl groups which are bonded to one another via a monocyclic or polycyclic ring system, where at least one cyclopentadienyl group is fused to the monocyclic or polycyclic ring system, and to a process for the preparation of a cycloolefin copolymer. The cycloolefin copolymers obtained in this way have high tear strengths and are suitable for the production of extrusion parts and injection moldings.

  本发明涉及一种立体刚性的金属烯化合物，其包含至少两个取代或未取代的环戊二烯基配体，这些配体通过单环或多环环系彼此键合，其中至少一个环戊二烯基与单环或多环环系融合，以及制备环烯共聚物的方法。通过这种方法获得的环烯共聚物具有高撕裂强度，并适用于生产挤出件和注塑件。
• Silicone polymer composition, method of forming a pattern and method of
  申请人：Kabushiki Kaisha Toshiba

  公开号：US05962581A1

  公开（公告）日：1999-10-05

  A method of forming a pattern comprising the steps of forming a film of an organosilane compound comprising a polysilane having a repeating unit represented by the following general formula (1) on a substrate, irradiating an actinic radiation onto a predetermined portion of the film of the organosilane compound formed on the substrate, and removing the predetermined portion of the film irradiated by the actinic radiation by dissolving it with an aqueous alkaline developing solution. ##STR1## wherein Ar is a substituted or non-substituted aryl group.

  一种形成图案的方法，包括以下步骤：在基板上形成一层有机硅化合物薄膜，该有机硅化合物包括具有由以下通式（1）表示的重复单元的聚硅烷，在基板上形成的有机硅化合物薄膜的预定部分照射活性辐射，并通过用水性碱性显影溶液溶解照射的有机硅化合物薄膜的预定部分来去除它。 其中Ar是取代或非取代的芳基基团。