4-[4-(4-乙酰氧基苯甲酰氧基)苯甲酰氧基]苯甲酸 | 787595-86-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 中文名称: 4-[4-(4-乙酰氧基苯甲酰氧基)苯甲酰氧基]苯甲酸
• 英文名称: 4-[4-(4-acetoxybenzoyloxy)benzoyloxy]benzoic acid
• 英文别名: Acetyl-di-(4-oxy-benzoyl)-4-oxy-benzoesaeure；4-[4-(4-Acetoxy-benzoyloxy)-benzoyloxy]-benzoesaeure；Acetyl-di-(p-oxy-benzoyl)-(p-oxy-benzoesaeure)；4-[4-(4-Acetyloxybenzoyl)oxybenzoyl]oxybenzoic acid；4-[4-(4-acetyloxybenzoyl)oxybenzoyl]oxybenzoic acid
• CAS: 787595-86-2
• 化学式: C₂₃H₁₆O₈
• 分子量: 420.375
• InChiKey: QNIIBBZCXTZMPW-UHFFFAOYSA-N

物化性质

• 熔点：
  236 °C
• 沸点：
  634.9±50.0 °C(Predicted)
• 密度：
  1.371±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  31
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  116
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  4-[4-(4-乙酰氧基苯甲酰氧基)苯甲酰氧基]苯甲酸 在 吡啶 、 ammonium hydroxide 、 丙酮 作用下， 生成 4-[4-(4-hydroxy-benzoyloxy)-benzoyloxy]-benzoic acid
  参考文献：
  名称：

  Fischer,E.; Kadisade, Chemische Berichte, 1919, vol. 52, p. 74

  摘要：

  DOI：
• 作为产物：
  描述：

  4-Ethoxycarbonyloxybenzoyl chloride 在 吡啶 、 ammonium hydroxide 、 sodium hydroxide 、 乙醚 、 丙酮 作用下， 生成 4-[4-(4-乙酰氧基苯甲酰氧基)苯甲酰氧基]苯甲酸
  参考文献：
  名称：

  Fischer,E.; Freudenberg, Justus Liebigs Annalen der Chemie, 1910, vol. 372, p. 36

  摘要：

  DOI：

文献信息

• Polymer Whiskers Composed of <i>p</i>-Oxybenzoyl and <i>p</i>-Mercaptobenzoyl Having Graded Compositions
  作者：Kazufumi Kobashi、Kunio Kimura、Yuhiko Yamashita

  DOI：10.1021/ma035962f

  日期：2004.10.1

  Preparation of polymer whiskers composed of p-oxybenzoyl (O) units and p-mercaptobenzoyl (S) units having graded composition was examined by the polymerization of S-acetyl-4-mercaptobenzoic acid (AMBA) and 4-(4-acetoxybenzoyloxy)benzoic acid (OO) or 4-[4-(4-acetoxybenzoyloxy)benzoyloxy]benzoic acid (OOO). Polymerizations were carried out in liquid paraffin at 300 degreesC for 6 h. The polymerization concentration was 1.0% and the molar ratio of O units in feed was 50%. Polymerization of AMBA and OO yielded copolymer whiskers by means of the crystallization of oligomers, which were 15 mum in average length and 0.4 mum in average width. The length and the width increased with polymer yield but the length increased preferentially rather than the width. The number of whiskers was constant during polymerization. The content of O units in the whiskers (chi(O)) prepared for 8 min was 62 mol % and then decreased to 49 mol % after 6 h. This fact revealed that the center part of the whisker was rich in O units, and the outer and tip parts were rich in S units. This whisker possessed a graded composition from O units to S units along the directions of the length and width. The oligomers rich in O unit sequences were preferentially precipitated in the early stage of polymerization, and afterward the oligomers poor in O units were precipitated to form the whiskers leading to a graded composition. Polymerization of AMBA and OOO yielded copolymer whiskers with a larger gradient composition than that of whiskers prepared from AMBA and OO.
• Klepl, Journal fur praktische Chemie (Leipzig 1954), 1883, vol. <2> 28, p. 217
  作者：Klepl

  DOI：——

  日期：——
• Fischer,E.; Kadisade, Chemische Berichte, 1919, vol. 52, p. 74
  作者：Fischer,E.、Kadisade

  DOI：——

  日期：——
• Fischer,E.; Freudenberg, Justus Liebigs Annalen der Chemie, 1910, vol. 372, p. 36
  作者：Fischer,E.、Freudenberg

  DOI：——

  日期：——