2,2,2-三硝基乙基-2-羟乙基醚 | 123657-30-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 原羧酸衍生物
• 中文名称: 2,2,2-三硝基乙基-2-羟乙基醚
• 英文名称: 2,2,2-trinitroethyl 2-hydroxyethyl ether
• 英文别名: 2-(2,2,2-trinitroethoxy)ethanol
• CAS: 123657-30-7
• 化学式: C₄H₇N₃O₈
• 分子量: 225.115
• InChiKey: LUPOWWMUPYADCF-UHFFFAOYSA-N

物化性质

• 沸点：
  318.2±42.0 °C(Predicted)
• 密度：
  1.645±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  167
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,2,2-三硝基乙基-2-羟乙基醚 在 chromium(VI) oxide 、 硫酸 作用下， 以 丙酮 为溶剂， 反应 18.0h， 以65%的产率得到(2,2,2-trinitroethoxy)acetic acid (TNEAA)
  参考文献：
  名称：

  (2,2,2-Trinitroethoxy)acetic acid and its derivatives

  摘要：

  Methods are developed for synthesizing (2,2,2-trinitroethoxy)acetic acid (TNEAA) by oxidation of the 2,2,2-trinitroethyl ethers of allylic alcohol or ethylene glycol; among the carboxyl group derivatives obtained were esters from the simplest alcohols and polynitro alcohols, the acid chloride, the amide, and the nitrile.

  DOI：

  10.1007/bf00961041
• 作为产物：
  描述：

  Acetic acid 2-(2,2,2-trinitro-ethoxy)-ethyl ester 在 甲醇 、 silver(I) chloride 作用下， 反应 1.0h， 生成 2,2,2-三硝基乙基-2-羟乙基醚
  参考文献：
  名称：

  Trinitroethyl ethers of substituted alcohols

  摘要：

  The influence of the trinitromethane salt cations and the substituents in the alkyl moiety of chloromethyl ethers of alcohols on the yields of trinitroethyl ethers of the substituted alcohols formed from them was established. On this basis a representative series of previously unavailable trinitroethanol ethers was synthesized.

  DOI：

  10.1007/bf00961040

文献信息

• Method for preparing 2,2,2-trinitroethyl 2-nitroxyethyl ether
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：USH0000644H1

  公开（公告）日：1989-06-06

  A process for preparing 2,2,2-trinitroethyl 2-nitroxyethyl ether by the fowing reaction sequence: ##STR1## 2,2,2-Trinitroethyl 2-nitroxyethyl ether is useful as an energetic plasticizer in propellants and explosives.

  一种制备2,2,2-三硝基乙基2-硝基乙醚的过程，通过以下反应序列进行：##STR1## 2,2,2-三硝基乙基2-硝基乙醚在推进剂和炸药中作为高能塑化剂有用。
• Sitzmann, Michael E.; Adolph, Horst G., Synthetic Communications, 1990, vol. 20, # 21, p. 3303 - 3311
  作者：Sitzmann, Michael E.、Adolph, Horst G.

  DOI：——

  日期：——
• SITZMANN, MICHAEL E.;ADOLPH, HORST G., SYNTH. COMMUN., 20,(1990) N1, C. 3303-3311
  作者：SITZMANN, MICHAEL E.、ADOLPH, HORST G.

  DOI：——

  日期：——
• Trinitroethyl ethers of substituted alcohols
  作者：O. A. Luk'yanov、G. V. Pokhvisneva

  DOI：10.1007/bf00961040

  日期：1991.11

  The influence of the trinitromethane salt cations and the substituents in the alkyl moiety of chloromethyl ethers of alcohols on the yields of trinitroethyl ethers of the substituted alcohols formed from them was established. On this basis a representative series of previously unavailable trinitroethanol ethers was synthesized.
• (2,2,2-Trinitroethoxy)acetic acid and its derivatives
  作者：O. A. Luk'yanov、G. V. Pokhvisneva

  DOI：10.1007/bf00961041

  日期：1991.11

  Methods are developed for synthesizing (2,2,2-trinitroethoxy)acetic acid (TNEAA) by oxidation of the 2,2,2-trinitroethyl ethers of allylic alcohol or ethylene glycol; among the carboxyl group derivatives obtained were esters from the simplest alcohols and polynitro alcohols, the acid chloride, the amide, and the nitrile.