N-甲基-1-(三乙氧基硅烷基)甲胺 | 151734-80-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: N-甲基-1-(三乙氧基硅烷基)甲胺
• 英文名称: (N-methylamino)methyltriethoxysilane
• 英文别名: N-methylaminomethyltriethoxysilane；N-Methyl-1-(triethoxysilyl)methanamine；N-methyl-1-triethoxysilylmethanamine
• CAS: 151734-80-4
• 化学式: C₈H₂₁NO₃Si
• 分子量: 207.345
• InChiKey: TVEHWKTXIHQJQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.79
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  39.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-甲基-1-(三乙氧基硅烷基)甲胺 在 三乙胺 作用下， 以 正戊烷 为溶剂， 反应 4.0h， 生成 3-[Methyl-(2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undec-1-ylmethyl)-amino]-propionic acid methyl ester
  参考文献：
  名称：

  N-methyI-N-(triethoxysilylmethyl) andN-methyl-N-(silatran-1-ylmethyl) substituted glycine and alanine

  摘要：

  Organosilicon derivatives of glycine, alpha- and beta-alanine, and alpha-methylalanine were prepared by the reaction of methyl esters of alpha- and beta-halocarboxylic acids with N-methyl-aminomethyltriethoxysilane in the presence of triethylamine. The compounds synthesized were converted into the corresponding N-silatran-1-ylmethyl derivatives. Trimethyl-silyliodoacetate reacts with N-methylaminomethyltrietoxysilane to give 2,2-diethoxy-4-methyl-1-oxa-4-aza-2-silacyclohexane-6-one. Its reaction with triethanolamine leads to N-methyl-N-(silatran-1-ylmethyl)glycine.

  DOI：

  10.1007/bf00702147

文献信息

• (N-methyl-N-alkoxymethylaminomethyl)dialkoxysilanes and bis[N-methyl-N-(dialkoxysilylmethyl)amino]methanes
  作者：N. F. Lazareva、V. P. Baryshok、M. G. Voronkov

  DOI：10.1007/bf00702156

  日期：1995.2

  Abstract(N-methyl-N-alkoxymethylaminomethyl)-dialkoxysilanes and bis[N-methyl-N-(dialkoxymethyl)amino]methanes were first obtained by the interaction of (N-methylaminomethyl) dialkoxy-R-silanes with chloromethyl alkyl ethers in yields of 40–67% and 10–25 %, respectively.

  摘要 (N​​-甲基-N-烷氧基甲基氨基甲基)-二烷氧基硅烷和双[N-甲基-N-(二烷氧基甲基)氨基]甲烷是首先通过(N-甲基氨基甲基)二烷氧基-R-硅烷与氯甲基烷基醚的相互作用获得的。分别为 40-67% 和 10-25%。
• N-(2-Thenyl)derivatives of aminoalkyltriethoxysilanes,-silatranes and 2,2-dimethyl-1,3-dioxa-6-aza-silacyclooctane
  作者：M. G. Voronkov、N. F. Lazareva、G. G. Efremova、V. P. Baryshok

  DOI：10.1007/bf00702157

  日期：1995.2

  The reactions of aminoalkylethoxysilanes and 2,2-dimethyl-1,3-dioxa-6-aza-2-silacyclooctane with 2-(chlormethyl)thiophene and its 5-chloroderivative lead to the corresponding N-(2-thenyl) derivatives. The N-methyl-N-(2-thenyl)aminomethyltriethoxysilane and 5-chlorothyenyl derivative formed are converted by triethanolamine into silatranes.
• Lasarewa N. F., Baryshok W. P., Woronkow M. G., Isw. AN. Ser. khim, (1995) N 2, S 382-383
  作者：Lasarewa N. F., Baryshok W. P., Woronkow M. G.

  DOI：——

  日期：——
• Woronkow M. G., Lasarewa N. F., Efremowa G. G., Baryshok W. P., Isw. AN. Ser. khim, (1995) N 2, S 384-386
  作者：Woronkow M. G., Lasarewa N. F., Efremowa G. G., Baryshok W. P.

  DOI：——

  日期：——
• ——
  作者：M. G. Voronkov、E. A. Zel'bst、A. A. Kashaev、Yu. V. Katkevich、V. A. Bruskov、N. F. Lazareva、A. I. Albanov、V. A. Pestunovich

  DOI：10.1023/a:1020735206488

  日期：——