(E)-2-(trimethylsilyl)-1-(trimethylstannyl)ethylene | 65801-56-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: (E)-2-(trimethylsilyl)-1-(trimethylstannyl)ethylene
• 英文别名: (E)-1-(trimethysilyl)-2-(trimethylstannyl)ethylene；{2-(trimethylsilyl)-1(E)-ethenyl}trimethylstannane；(E)-1-trimethylstannyl-2-(trimethylsilyl)ethylene；(2-(trimethylsilyl)vinyl)trimethyltin；trans-1-trimethylsilyl-2-trimethylstannylaethylen；trimethyl(2-trimethylstannylethenyl)silane
• CAS: 65801-56-1；110510-36-6
• 化学式: C₈H₂₀SiSn
• 分子量: 263.042
• InChiKey: PJDCAXMJPGJRMP-UHFFFAOYSA-N

物化性质

• 沸点：
  175.7±42.0 °C(Predicted)
• 溶解度：
  溶胶醚、DMF、碳氢化合物、芳香族溶剂。

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-2-(trimethylsilyl)-1-(trimethylstannyl)ethylene 、 (6-甲基环己烯-1-基)三氟甲磺酸酯 在 四(三苯基膦)钯 lithium chloride 作用下， 以 四氢呋喃 为溶剂， 反应 6.0h， 以100%的产率得到(E)-1-(trimethylsilyl)-2-(6-methylcyclohex-1-en-1-yl)ethylene
  参考文献：
  名称：

  钯催化的乙烯基三氟甲磺酸酯与有机锡烷的偶联。pleraplysillin-1 的简短合成

  摘要：

  合成这些 de la pleraplysilline-1 a partir du bromomethyl-3 furanne et de la dimethyl-5,5 cyclohexene-2one

  DOI：

  10.1021/ja00328a063

文献信息

• Palladium-catalyzed carbonylative coupling of vinyl triflates with organostannanes. A total synthesis of (.+-.)-.DELTA.9(12)-capnellene
  作者：G. T. Crisp、William J. Scott、John K. Stille

  DOI：10.1021/ja00336a033

  日期：1984.11

  Synthese du capnellene-9(12) a partir du triflate de trimethyl-2,5,5 cyclopentene-1ol et du stannane de methyl trimethylsilylvinyl

  合成这些 du capnellene-9(12) a partir du triflate de trimethyl-2,5,5 cyclopentene-1ol et du stannane demethyl trimethylsilylvinyl
• Palladium-catalyzed coupling of vinyl triflates with organostannanes. A short synthesis of pleraplysillin-1
  作者：William J. Scott、G. T. Crisp、J. K. Stille

  DOI：10.1021/ja00328a063

  日期：1984.8

  Synthese de la pleraplysilline-1 a partir du bromomethyl-3 furanne et de la dimethyl-5,5 cyclohexene-2one

  合成这些 de la pleraplysilline-1 a partir du bromomethyl-3 furanne et de la dimethyl-5,5 cyclohexene-2one
• Stereospecific cross-coupling of vinyl halides with vinyl tin reagents catalyzed by palladium
  作者：J. K. Stille、B. L. Groh

  DOI：10.1021/ja00237a029

  日期：1987.2
• Functionalization of metalated cyclopentadienyl ligands via palladium-catalyzed cross-coupling reactions
  作者：E. C. Brehm、J. K. Stille、A. I. Meyers

  DOI：10.1021/om00038a066

  日期：1992.2

  The palladium-catalyzed coupling reaction between tricarbonyl(iodo-eta(5)-cyclopentadienyl)methyltungsten and various alkynyl-, aryl-, and vinylstannanes yields the corresponding coupled derivatives. The three classes of tin coupling partners were represented by (2-phenyl-1-ethynyl)trimethylstannane, 1-propynyltrimethylstannane, and 1-hexynyltri-n-butylstannane; phenyltri-n-butylstannane, and (4-methylphenyl)trimethylstannane; and (Z)-methyl 3-(tributylstannyl)acrylate, trimethylvinylstannane, and [2-(trimethylsilyl)-1(E)-ethenyl]trimethylstannane. This chemistry demonstrates a new, general route for the formation of a variety of functionally substituted eta(5)-cyclopentadienyl transition-metal compounds, whereby the cyclopentadienyl ring can be derivatized by several classes of organostannane reagents without affecting the other ligands on the transition metal.
• Studies directed toward the total synthesis of trixikingolide. Analysis of the capacity for transannular carbon-carbon bond formation in various bicyclic and tricyclic intermediates
  作者：Daniel L. Cheney、Leo A. Paquette

  DOI：10.1021/jo00275a018

  日期：1989.7