dimethyl triselenide | 22009-80-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: dimethyl triselenide
• 英文别名: (methyltriselanyl)methane
• CAS: 22009-80-9
• 化学式: C₂H₆Se₃
• 分子量: 266.95
• InChiKey: JLYHRGWTAZOXPR-UHFFFAOYSA-N

物化性质

• 沸点：
  239.7±23.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.03
• 重原子数：
  5
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 dimethyl triselenide 在 氢氧化钾 、 一水合肼 作用下， 反应 4.0h， 以27%的产率得到2,4,6-triselenaheptane
  参考文献：
  名称：

  Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system

  摘要：

  Methods of synthesis of compounds MeY(CH2Y)(n) Me (Y=S, Se, Te; n = 1-3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y2-) and dimethyl dichalcogenides (MeY-) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.

  DOI：

  10.1134/s1070363208090156
• 作为产物：
  描述：

  碘甲烷 在 氢氧化钾 、 selenium 、 一水合肼 作用下， 以 水 为溶剂， 生成 dimethyl triselenide
  参考文献：
  名称：

  Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system

  摘要：

  Methods of synthesis of compounds MeY(CH2Y)(n) Me (Y=S, Se, Te; n = 1-3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y2-) and dimethyl dichalcogenides (MeY-) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.

  DOI：

  10.1134/s1070363208090156

文献信息

• Synthesis of diselenides and selenides from elemental selenium
  作者：Alain Krief、Michel Derock

  DOI：10.1016/s0040-4039(02)00277-0

  日期：2002.4

  Sodium hydride is able to reduce elemental selenium to sodium diselenide (Na2Se2), but not to sodium selenide (Na2Se). Dialkyl diselenides and even dialkyl selenides, including unsymmetrical dialkyl selenides, can be nevertheless synthesized using the proper Se/NaH ratio (1/1 or 1/2).

  氢化钠能够将元素硒还原为二硒化钠（Na 2 Se 2），但不能还原为硒化钠（Na 2 Se）。尽管如此，仍可以使用适当的Se / NaH比（1/1或1/2）合成二烷基二硒化物，甚至二烷基硒化物，包括不对称的二烷基硒化物。
• Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system
  作者：E. P. Levanova、V. Yu. Vshivtsev、E. N. Sukhomazova、V. A. Grabel’nykh、N. V. Russavskaya、E. R. Zhanchipova、L. V. Klyba、A. I. Albanov、N. A. Korchevin

  DOI：10.1134/s1070363208090156

  日期：2008.9

  Methods of synthesis of compounds MeY(CH2Y)(n) Me (Y=S, Se, Te; n = 1-3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y2-) and dimethyl dichalcogenides (MeY-) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.