2-propenyl-2'-hydroxyethyl carbonate | 5331-55-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: 2-propenyl-2'-hydroxyethyl carbonate
• 英文别名: 2-Hydroxyethyl prop-2-en-1-yl carbonate；2-hydroxyethyl prop-2-enyl carbonate
• CAS: 5331-55-5
• 化学式: C₆H₁₀O₄
• 分子量: 146.143
• InChiKey: RHZWMHZZJLEPBC-UHFFFAOYSA-N

物化性质

• 沸点：
  202.3±33.0 °C(Predicted)
• 密度：
  1.123±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  碳酸二稀丙酯 、 乙二醇 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三苯基膦 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 以54%的产率得到2-propenyl-2'-hydroxyethyl carbonate
  参考文献：
  名称：

  Pd催化碳酸烯丙酯与多元醇的反应：甘油在甘油酯交换反应中的作用

  摘要：

  已经开发出分子间的Pd / PPh 3催化碳酸二烯丙酯与甘油的酯交换反应以生成碳酸甘油酯。对THF中反应动力学的分析表明，一阶依赖于Pd和碳酸二烯丙酯，Pd在周转限制事件中带有两个膦，并且增加甘油浓度会抑制反应，可能是通过介质极性的改变来实现的。13 C同位素标记研究表明，Pd催化的酯交换反应需要至少一个碳酸烯丙酯部分，并且碳酸烯丙酯与CO 2迅速平衡溶液中，即使仅以低浓度存在也是如此。即与这些结果相一致的机制涉及氧化加成的碳酸烯丙酯与Pd的随后可逆脱羧，与中间η 1 -和η 3 -烯丙基钯介导的醇盐与甘油的直接和间接的酯交换反应。使用该模型，可以成功地模拟在N 2或CO 2气氛下进行的反应动力学，包括在反应早期在醚化和酯交换之间进行选择性切换。与高级多元醇苏糖醇和赤藓糖醇的反应也是有效的，生成具有高选择性的末端（1,2）单碳酸酯。

  DOI：

  10.1002/chem.201103418

文献信息

• OPTICAL MATERIAL COMPRISING A RED-SHIFTED BENZOTRIAZOLE UV ABSORBER
  申请人：ESSILOR INTERNATIONAL

  公开号：US20190107647A1

  公开（公告）日：2019-04-11

  The present invention relates to an eyeglass lens comprising a substrate made of an optical material comprising a polymer matrix and at least one 2-(2-hydroxy-5-R 1 -phenyl)benzotriazole, in which R 1 is a resonant group, the optical transmittance through a 2 mm thick layer of said optical material being lower than 1% for each light wavelength ranging from 280 to 405 nm. This eyeglass lens protects from phototoxic blue light and UV light.

  本发明涉及一种眼镜镜片，其包括由光学材料制成的基板，该光学材料包括聚合物基质和至少一种2-（2-羟基-5-R1-苯基）苯并三唑，其中R1是共振基团，该光学材料的2毫米厚度层的光学透过率对于从280到405纳米的每个光波长都低于1％。该眼镜镜片可以保护眼睛免受光毒性蓝光和紫外线的伤害。
• Composition for curable paints
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0238327A2

  公开（公告）日：1987-09-23

  A composition for curable paints, comprising (A) l00 parts by weight of resin for curable paints, and (B) 0.5 to l0 parts by weight of chlorinated and graft-modified polypropylene which is produced by chlorinating polypropylene graft-modified with a grafting component selected from the group consisting of alpha,beta-unsaturated dicarboxylic acids, anhydrides thereof and esters thereof, and which has a chlorine content of 5 to 50% by weight, said graft-modified poly­propylene having a degree of saponification of 5 to l50 mg/g and an intrinsic viscosity [η] of 0.l to 5 dl/g. A curable paint comprising the composition and a diluent.

  一种用于固化涂料的组合物，包括 (A) 100 份（按重量计）用于固化涂料的树脂，和 (B) 0.5至l0份（重量）氯化和接枝改性聚丙烯，该聚丙烯是通过氯化聚丙烯，并用选自α，β-不饱和二羧酸、其酸酐和其酯组成的接枝组分进行接枝改性而制得，其氯含量为5至50%（重量），所述接枝改性聚丙烯的皂化度为5至l50毫克/克，固有粘度[η]为0.l 至 5 dl/g。一种可固化涂料，由该组合物和稀释剂组成。
• PROCESSES FOR THE PREPARATION OF MONODISPERSE POLYMERS, PROCESSES FOR THE CONTINUOUS POLYMERIZATION OF CYCLIC MONOMERS, AND POLYMERS PREPARED THEREBY
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP0943641A1

  公开（公告）日：1999-09-22

  The present invention relates to a method for preparing lactone polymers, carbonate polymers, lactone-carbonate block copolymers and lactone-carbonate random copolymers via a ring-opening addition reaction of a lactone monomer, a cyclic carbonate monomer or a mixture thereof using an initiator and in the presence of a specific titanium-type Lewis acid catalyst. The resulting polymers have a molecular weight distribution (Mw/Mn) approximately equal to 1 or a extremely high purity of single-structure components. The polymer molecules range in an oligomer region to a molecular weight of approximately 200,000. The present invention also relates to a method for preparing lactone polymers, carbonate polymers and lactone-carbonate copolymers having a narrow molecular weight distribution and which can be obtained via a continuous polymerisation of a lactone monomer and/or a cyclic carbonate monomer using an initiator in an extruder in the presence of a specific titanium-type Lewis acid catalyst or an aluminium-type Lewis acid catalyst. The present invention also relates to these resulting polymers.

  本发明涉及一种制备内酯聚合物、碳酸酯聚合物、内酯-碳酸酯嵌段共聚物和内酯-碳酸酯无规共聚物的方法，该方法通过内酯单体、环状碳酸酯单体或其混合物在特定钛型路易斯酸催化剂存在下，使用引发剂进行开环加成反应。所得聚合物的分子量分布（Mw/Mn）约等于 1，或具有极高的单一结构成分纯度。聚合物分子在低聚物区域的分子量范围约为 200 000。本发明还涉及一种制备分子量分布较窄的内酯聚合物、碳酸盐聚合物和内酯-碳酸盐共聚物的方法，这些聚合物可在挤压机中使用引发剂，在特定的钛型路易斯酸催化剂或铝型路易斯酸催化剂存在下，通过内酯单体和/或环状碳酸盐单体的连续聚合反应获得。本发明还涉及这些由此产生的聚合物。
• Photochromic article
  申请人：TRANSITIONS OPTICAL, INC.

  公开号：EP2317349A1

  公开（公告）日：2011-05-04

  Describes an optical article, e.g., an ophthalmic photochromic article, such as a lens, in which the article includes: (1) a transparent substrate, such as a thermoset or thermoplastic plastic substrate, (2) a multiply laminate adjacent to at least one surface of the substrate, the laminate comprising (i) a transparent, thermoplastic polyurethane film, the thermoplastic, polyurethane film providing a desirable light filtering property, e.g., photochromism, and being juxtaposed to the surface of the substrate, the polyurethane being formed from a material comprising polyether-based polyurethane or polycarbonate-based polyurethane, and (ii) a transparent protective film of polymeric material, e.g., polycarbonate film, adjacent to the thermoplastic polyurethane film. Describes also the aforedescribed optical article having an abrasion-resistant coating affixed to the protective film, e.g., an organo-silane abrasion-resistant coating; and an optical article having an antireflective coating adhered to the abrasion-resistant coating.

  描述了一种光学制品，例如眼科光致变色制品，如镜片，其中该制品包括：(1) 透明基底，例如热固性或热塑性塑料基底，(2) 与基底至少一个表面相邻的多层压片，该压片包括 (i) 透明的热塑性聚氨酯薄膜，该热塑性聚氨酯薄膜具有理想的滤光特性，例如光致变色，并与基底表面并置、聚氨酯由聚醚基聚氨酯或聚碳酸酯基聚氨酯组成的材料形成，以及(ii) 与热塑性聚氨酯薄膜相邻的高分子材料透明保护膜，例如聚碳酸酯薄膜。还描述了前述光学制品，该光学制品具有附着在保护膜上的耐磨涂层，例如有机硅耐磨涂层；以及具有附着在耐磨涂层上的抗反射涂层的光学制品。
• BLUE LIGHT CUTTING OPTICAL MATERIAL COMPRISING A BENZOTRIAZOLE UV ABSORBER
  申请人：ESSILOR INTERNATIONAL (Compagnie Générale d'Optique)

  公开号：EP3203271A1

  公开（公告）日：2017-08-09

  Optical material comprising a polymer matrix and at least one benzotriazole compound having at least one ester group, wherein said at least one benzotriazole is a chlorobenzotriazole compound that does not comprise any polymerizable group selected from allylic, acrylic and methacrylic moieties, or the optical transmittance through a 2 mm thick layer of said optical material is lower than 1 % for each light wavelength ranging from 280 to 400 nm, and higher than 65 % for light having a wavelength of 430 nm. This optical material can be used to protect from phototoxic blue light and UV light.

  由聚合物基体和至少一种具有至少一个酯基的苯并三唑化合物组成的光学材料，其中所述至少一种苯并三唑为氯苯并三唑化合物，不包含任何选自烯丙基、丙烯酸基和甲基丙烯酸基的可聚合基团，或通过所述光学材料 2 毫米厚的层的光透射率在 280 至 400 纳米的每个光波长范围内均低于 1%，在波长为 430 纳米的光中高于 65%。这种光学材料可用于防止光毒性蓝光和紫外线。