1,1,2,2-tetrakis(bis(trimethylsilyl)methyl)dibismuthine | 443281-44-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,1,2,2-tetrakis(bis(trimethylsilyl)methyl)dibismuthine
• 英文别名: Tetrakis[bis(trimethylsilyl)methyl]dibismuthine
• CAS: 443281-44-5
• 化学式: C₂₈H₇₆Bi₂Si₈
• 分子量: 1055.56
• InChiKey: VXRBMYGHQRTFFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.02
• 重原子数：
  38
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1,2,2-tetrakis(bis(trimethylsilyl)methyl)dibismuthine 以 not given 为溶剂， 生成 Tris[bis(trimethylsilyl)methyl]bismuthane 、 、
  参考文献：
  名称：

  Synthesis and Characterization of R₂SbH, R₂BiH, and R₂Bi−BiR₂ [R = (Me₃Si)₂CH]

  摘要：

  R2SbH (1) and R2BiH (2) [R = (Me3Si)(2)CH] are formed by reactions of the corresponding chlorides with LiAlH4. 1 is stable up to 100 degreesC. Decomposition of 2 at room temperature leads to R2Bi-BiR2 (3) and H-2. The crystal structure of 3 consists of molecules in a near trans conformation. H-1 NMR studies of 3 in C6D6 show that the diastereotopic Me3Si groups become equivalent with increasing concentration and temperature.

  DOI：

  10.1021/om020202z
• 作为产物：
  描述：

  bis[bis(trimethylsilyl)methyl]bismuth chloride 、 lithium aluminium tetrahydride 以 乙醚 为溶剂， 以73.24%的产率得到1,1,2,2-tetrakis(bis(trimethylsilyl)methyl)dibismuthine
  参考文献：
  名称：

  Synthesis and Characterization of R₂SbH, R₂BiH, and R₂Bi−BiR₂ [R = (Me₃Si)₂CH]

  摘要：

  R2SbH (1) and R2BiH (2) [R = (Me3Si)(2)CH] are formed by reactions of the corresponding chlorides with LiAlH4. 1 is stable up to 100 degreesC. Decomposition of 2 at room temperature leads to R2Bi-BiR2 (3) and H-2. The crystal structure of 3 consists of molecules in a near trans conformation. H-1 NMR studies of 3 in C6D6 show that the diastereotopic Me3Si groups become equivalent with increasing concentration and temperature.

  DOI：

  10.1021/om020202z

文献信息

• Synthesis and Characterization of R₂SbH, R₂BiH, and R₂Bi−BiR₂ [R = (Me₃Si)₂CH]
  作者：Gábor Balázs、Hans Joachim Breunig、Enno Lork

  DOI：10.1021/om020202z

  日期：2002.6.1

  R2SbH (1) and R2BiH (2) [R = (Me3Si)(2)CH] are formed by reactions of the corresponding chlorides with LiAlH4. 1 is stable up to 100 degreesC. Decomposition of 2 at room temperature leads to R2Bi-BiR2 (3) and H-2. The crystal structure of 3 consists of molecules in a near trans conformation. H-1 NMR studies of 3 in C6D6 show that the diastereotopic Me3Si groups become equivalent with increasing concentration and temperature.