Tris[bis(trimethylsilyl)methyl]bismuthane | 87371-38-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Tris[bis(trimethylsilyl)methyl]bismuthane
• CAS: 87371-38-8
• 化学式: C₂₁H₅₇BiSi₆
• 分子量: 687.177
• InChiKey: YGSSPYABZIZNOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.86
• 重原子数：
  28
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  bis[bis(bis(trimethylsilyl)methyl)bismuth]sulfide 以 not given 为溶剂， 生成 bismuth(III) sulfide 、 Tris[bis(trimethylsilyl)methyl]bismuthane
  参考文献：
  名称：

  Syntheses and structures of (R2Bi)2E (E=S, Te) and cyclo-(RSbSe)2[W(CO)5]2 [R=CH(SiMe3)2]

  摘要：

  (R2Bi)(2)E [E = S (1), Te (2); R = CH(SiMe3)(2)] are formed by reaction of R2BiCl with Na2S or Na2Te. The reaction of cyclo (RSbSe)(n) [n = 2, 3; R = CH(SiMe3)(2)] with W(CO)(5)THF (THF = tetrahydrofuran) in THF results in trapping of the dimer in cyclo (RSbSe)(2)[W(CO)(5)](2) (3). The crystal structures of 1, 2, and 3 are reported. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01973-3

文献信息

• Synthesis and Characterization of R₂SbH, R₂BiH, and R₂Bi−BiR₂ [R = (Me₃Si)₂CH]
  作者：Gábor Balázs、Hans Joachim Breunig、Enno Lork

  DOI：10.1021/om020202z

  日期：2002.6.1

  R2SbH (1) and R2BiH (2) [R = (Me3Si)(2)CH] are formed by reactions of the corresponding chlorides with LiAlH4. 1 is stable up to 100 degreesC. Decomposition of 2 at room temperature leads to R2Bi-BiR2 (3) and H-2. The crystal structure of 3 consists of molecules in a near trans conformation. H-1 NMR studies of 3 in C6D6 show that the diastereotopic Me3Si groups become equivalent with increasing concentration and temperature.
• Murray, Brendan; Hvoslef, Jan; Hope, Håkon, Inorganic Chemistry, 1983, vol. 22, # 23, p. 3421 - 3424
  作者：Murray, Brendan、Hvoslef, Jan、Hope, Håkon、Power, Philip P.

  DOI：——

  日期：——