phosphorous acid dibutyl ester-heptyl ester | 131108-21-9

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 英文名称: phosphorous acid dibutyl ester-heptyl ester
• 英文别名: Phosphorigsaeure-dibutylester-heptylester；Dibutyl heptyl phosphite；dibutyl heptyl phosphite
• CAS: 131108-21-9
• 化学式: C₁₅H₃₃O₃P
• 分子量: 292.399
• InChiKey: ILGUMOBOJCOKNF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  19
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  phosphorous acid dibutyl ester-heptyl ester 在 diluted aqueous oic acid 作用下， 生成 phosphonic acid butyl ester-heptyl ester
  参考文献：
  名称：

  Arbusow; Imaew, Doklady Akademii Nauk SSSR, 1957, vol. 112, p. 856,858

  摘要：

  DOI：
• 作为产物：
  描述：

  三丁基,三丁酯 、 正庚醇 在 alkaliheptylate 作用下， 生成 phosphorous acid dibutyl ester-heptyl ester
  参考文献：
  名称：

  Arbusow; Imaew, Doklady Akademii Nauk SSSR, 1957, vol. 112, p. 856,858

  摘要：

  DOI：

文献信息

• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP3144064A2

  公开（公告）日：2017-03-22

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons.

  一种由钯和有机磷化合物组成的载体加氢催化剂组成的组合物，该载体加氢催化剂能选择性地将高度不饱和烃加氢为不饱和烃。
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP2403642A2

  公开（公告）日：2012-01-11
• METHODS OF USING A SELECTIVE HYDROGENATION CATALYST
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP2403642B1

  公开（公告）日：2017-08-02
• Hydrogenation Using Highly Selective Catalyst
  申请人：Chevron Phillips Chemical Company LP

  公开号：US20160355449A1

  公开（公告）日：2016-12-08

  A process comprising hydrogenating a highly unsaturated hydrocarbon in the presence of a first hydrogenation catalyst and a second hydrogenation catalyst to one or more compounds including an unsaturated hydrocarbon such that a total conversion of the highly unsaturated hydrocarbon is about 99 mol % or greater. In the process, the first hydrogenation catalyst, the second hydrogenation catalyst, or both, have a hydrogenation selectivity to the unsaturated hydrocarbon of about 90% or greater.