三(十一烷基)亚磷酸酯 | 94133-78-5

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 中文名称: 三(十一烷基)亚磷酸酯
• 中文别名: 1-甲基-3-(2,6,6-三甲基-1-环己烯-1-基)烯丙基苯基乙酸酯
• 英文名称: Trisundecyl phosphite
• 英文别名: triundecyl phosphite
• CAS: 94133-78-5
• 化学式: C₃₃H₆₉O₃P
• 分子量: 544.9
• InChiKey: UKPASDNOVTUNJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.2
• 重原子数：
  37
• 可旋转键数：
  33
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Lubricant oil composition comprising a fluorine-containing aromatic compound and an alkyl- or alkyl derivative- substituted aromatic compound, and a refrigerant composition containing the same
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0638629A2

  公开（公告）日：1995-02-15

  Disclosed is a lubricant oil composition comprising : (A) a fluorine-containing aromatic compound, and (B) an alkyl- or alkyl derivative-substituted aromatic compound having a kinetic viscosity of from 0.1 to 500 cSt as measured at 40 °C, wherein : the compound (A) is represented by the formula : wherein X represents an oxygen or a sulfur atom ; n is an integer of from 1 to 4 ; R represents an n-valent, unsubstituted or substituted aromatic group having from 6 to 60 carbon atoms ; and Rf represents an unsubstituted or partially substituted fluorocarbon group having from 1 to 25 carbon atoms; and the compound (B) comprises at least one substituted aromatic nucleus, wherein a substituent is an unsubstituted or substituted alkyl group having from 1 to 30 carbon atoms, or a derivative thereof. The lubricant oil composition having a kinetic viscosity of from 2 to 500 cSt as measured at 40 °C. The lubricant oil composition exhibits not only excellent miscibility with hydrofluorocarbon refrigerants and hydrofluoroether refrigerants over a wide temperature range, but also satisfy all requirements of properties for use thereof as a lubricant in refrigeration equipment, that is, low temperature fluidity, low moisture absorption properties, high electrical insulation, prolonged durability, and excellent lubricating properties.

  公开了一种润滑油组合物，其中包括： (A) 含氟芳香族化合物，和 (B) 烷基或烷基衍生物取代的芳香族化合物，其在 40 °C 时的动力学粘度为 0.1 至 500 cSt，其中： 化合物(A)由式： 其中 X 代表氧原子或硫原子；n 是 1 至 4 的整数；R 代表具有 6 至 60 个碳原子的 n 价、未取代或取代的芳香族基团；Rf 代表具有 1 至 25 个碳原子的未取代或部分取代的碳氟化合物基团；以及 化合物 (B) 包括至少一个取代的芳香族核，其中一个取代基是具有 1 至 30 个碳原子的未取代或取代的烷基或其衍生物。润滑油组合物在 40 °C 时的动力学粘度为 2 至 500 cSt。该润滑油组合物不仅在较宽的温度范围内与氢氟碳制冷剂和氢氟醚制冷剂具有极佳的相溶性，而且还满足将其用作制冷设备润滑剂的所有性能要求，即低温流动性、低吸湿性、高电绝缘性、持久耐用性和优异的润滑性。
• Fluorine-containing aromatic compound
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0913454A1

  公开（公告）日：1999-05-06

  Disclosed is a fluorine-containing aromatic compound represented by the formula: wherein: each of R1 and R2 independently represents a hydrogen atom or a C1-C19 alkyl group, wherein the total number of carbon atoms in R1 and R2 is from 4 to 19; and each Rf is an unsubstituted or partially substituted C1-C25 fluorocarbon group in which the ratio of fluorine atom or atoms to carbon atom or atoms is from 0.6 to 3. The compound of the present invention has various excellent properties, such as very high miscibility with hydrocarbons and low bioaccumulation (or low bioconcentration), so that is can be advantageously used not only as lubricant oils for refrigeration equipment using HFC refrigerants or an additive in a refrigerant system using in combination an HFC refrigerant and a hydrocarbon lubricant, but also as lubricants for general purpose, or additives or modifiers for various types of oily substances and polymeric materials.

  公开了一种由式表示的含氟芳香族化合物： 其中：R1 和 R2 各自独立地代表氢原子或 C1-C19 烷基，其中 R1 和 R2 中的碳原子总数为 4 至 19；每个 Rf 为未取代或部分取代的 C1-C25 碳氟化合物基团，其中氟原子与碳原子的比例为 0.6 至 3。本发明的化合物具有各种优良特性，例如与碳氢化合物的高度混溶性和低生物蓄积性（或低生物浓缩性），因此不仅可用作使用氢氟碳化合物制冷剂的制冷设备的润滑油，或用作结合使用氢氟碳化合物制冷剂和碳氢化合物润滑剂的制冷系统的添加剂，还可用作一般用途的润滑剂，或用作各种油性物质和聚合材料的添加剂或改性剂。
• Oil for cutting and grinding by ultra low volume oil feed system and for sliding surface and method for cutting and grinding by ultra low volume feed system using the oil
  申请人：——

  公开号：US20040116308A1

  公开（公告）日：2004-06-17

  An oil for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester, and is used as a lubricating oil for cutting and grinding suitable for a cutting and grinding method by minimal quantity lubrication system, and also used as a lubricating oil for sliding surface.

  根据本发明，一种用于通过极少量润滑系统进行切割和研磨以及用于滑动表面的润滑油由酯类组成，可用作适用于通过极少量润滑系统进行切割和研磨方法的切割和研磨润滑油，也可用作滑动表面的润滑油。
• Oil composition for cutting and grinding by minimal quantity lubrication system
  申请人：——

  公开号：US20040116309A1

  公开（公告）日：2004-06-17

  An oil composition for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester and a sulfur compound and/or a phosphorus compound.

  根据本发明，一种用于通过极少量润滑系统进行切割和磨削以及用于滑动表面的油组合物包括一种酯和一种硫化合物和/或磷化合物。
• WORKING FLUID COMPOSITION FOR A REFRIGERATING MACHINE
  申请人：JX Nippon Oil & Energy Corporation

  公开号：EP2749629B1

  公开（公告）日：2017-04-26