亚磷酸三壬酯 | 2549-63-5

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 中文名称: 亚磷酸三壬酯
• 英文名称: phosphorous acid trinonyl ester
• 英文别名: phosphoric acid trinonyl ester；Phosphorigsaeure-trinonylester；Trinonylphosphit；trinonyl phosphite；Tri-(n-nonyl)-phosphit
• CAS: 2549-63-5
• 化学式: C₂₇H₅₇O₃P
• 分子量: 460.722
• InChiKey: QUTZUATVZPXUJR-UHFFFAOYSA-N

物化性质

• 沸点：
  186.5-188 °C(Press: 0.018 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  31
• 可旋转键数：
  27
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2920901900

反应信息

• 作为反应物：
  描述：

  亚磷酸三壬酯 、 1-溴壬烷 生成 nonyl-phosphonic acid dinonyl ester
  参考文献：
  名称：

  Arbusow; Winogradowa, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1952, p. 882,890; engl.Ausg.S.787,793

  摘要：

  DOI：
• 作为产物：
  描述：

  1-壬醇 在 三(2-氯乙基)亚磷酸酯 作用下， 生成 亚磷酸三壬酯
  参考文献：
  名称：

  Ovchinnikova,N.K. et al., Journal of Organic Chemistry USSR (English Translation), 1975, vol. 11, # 9, p. 1849 - 1851

  摘要：

  DOI：

文献信息

• MANUFACTURING METHOD FOR POLYCARBONATE
  申请人：——

  公开号：US20020037838A1

  公开（公告）日：2002-03-28

  A method for manufacturing polycarbonate by melt-polycondensing bisphenol and carbonic acid diester uses as catalyst an alkali metal compound and/or alkaline earth metal compound (a). The catalyst is added to the bisphenol prior to the melt polycondensation, in an effective amount, i.e., the amount of alkali metal compound and/or alkaline earth metal compound (a) that acts effectively as a catalyst, is contained in said bisphenol, and is controlled to have the same catalytic activity as 1×10 −8 to 1×10 −6 mole of bisphenol disodium salt per mole of pure bisphenol A. The method conducts the reaction efficiently from the initial stage in a stable manner to obtain polycarbonate with good color, good heat stability and color stability during molding and the like.

  一种通过熔融缩聚双酚和碳酸二酯制造聚碳酸酯的方法，使用碱金属化合物和/或碱土金属化合物（a）作为催化剂。催化剂在熔融缩聚之前被添加到双酚中，添加的量是有效的，即碱金属化合物和/或碱土金属化合物（a）的量作为催化剂是包含在双酚中的，并且被控制为具有与1×10^-8至1×10^-6摩尔双酚二钠盐相同的催化活性。该方法从初始阶段开始有效地进行反应，稳定地获得具有良好颜色、良好热稳定性和成型过程中颜色稳定性的聚碳酸酯。
• POLYCARBONATE RESIN COMPOSITION, MOLDED ARTICLE, POLYCARBONATE RESIN, AND END-CAPPING AGENT FOR POLYCARBONATE RESIN
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20200115496A1

  公开（公告）日：2020-04-16

  A polycarbonate resin composition, a molded article, a polycarbonate resin, and an end-capping agent for polycarbonate resins are provided. The polycarbonate resin composition contains: a polycarbonate resin having a terminal structure represented by Formula (A) and having a viscosity average molecular weight from 1×10 4 to 5×10 4 , and a stabilizer. In Formula (A), R 1 is selected from the group consisting of a hydrogen atom, halogen atoms, linear alkyl groups having from 1 to 9 carbons, branched alkyl groups having from 3 to 9 carbons, linear alkenyl groups having from 2 to 9 carbons, branched alkenyl groups having from 3 to 9 carbons, and aryl groups having from 6 to 12 carbons; and R 2 to R 7 are each independently selected from the group consisting of a hydrogen atom, alkyl groups having from 1 to 9 carbons, and alkoxy groups having from 1 to 9 carbons.

  提供聚碳酸酯树脂组合物、成型品、聚碳酸酯树脂和聚碳酸酯树脂封端剂。聚碳酸酯树脂组合物包含：具有由式（A）表示的末端结构和粘度平均分子量为1×104到5×104的聚碳酸酯树脂，以及稳定剂。在式（A）中，R1选择自氢原子、卤素原子、具有1到9个碳原子的直链烷基、具有3到9个碳原子的支链烷基、具有2到9个碳原子的直链烯基、具有3到9个碳原子的支链烯基和具有6到12个碳原子的芳基组成的群；而R2到R7分别独立地选择自氢原子、具有1到9个碳原子的烷基和具有1到9个碳原子的烷氧基组成的群。
• COMPOUND CONTAINING PYRIDINE RING AND METHOD FOR PRODUCING HALOGENATED PICOLINE DERIVATIVE AND TETRAZOLYLOXIME DERIVATIVE
  申请人：Miyazaki Hidekazu

  公开号：US20130012713A1

  公开（公告）日：2013-01-10

  Disclosed is a compound containing a pyridine ring that can be synthesized in an industrially advantageous manner, and is useful as an intermediate for producing tetrazolyloxime derivatives that exhibit fungicidal activity (wherein R 0 represents a C 1-6 alkoxy group, C 1-6 alkoxy-C 1-6 alkoxy group or the like, R 1 represents a C 1-2 alkoxycarbonyl group, acetyl group or the like, Z represents a halogen atom, cyano group or the like, X represents a halogen atom, and n represents an integer of 0 to 3), and industrially advantageous production methods for producing 2-substituted amino-6-halomethylpyridine derivatives and tetrazolyloxime derivatives.

  本发明公开了一种含有吡啶环的化合物，可以以工业上有利的方式合成，并且可用作生产具有杀真菌活性的四唑氧肟衍生物的中间体（其中R0代表C1-6烷氧基基团，C1-6烷氧基-C1-6烷氧基基团或类似物，R1代表C1-2烷氧羰基基团，乙酰基基团或类似物，Z代表卤素原子，氰基团或类似物，X代表卤素原子，n代表0至3的整数），以及用于生产2-取代氨基-6-卤甲基吡啶衍生物和四唑氧肟衍生物的工业上有利的生产方法。
• PHOSPHONO PARAFFINS
  申请人：THE BOEING COMPANY

  公开号：US20180195019A1

  公开（公告）日：2018-07-12

  Aspects described herein generally relate to methods of making a phosphono paraffin comprising forming a reaction mixture by mixing a haloparaffin, a phosphite, and sodium iodide. Methods comprise heating the reaction mixture to form the phosphono paraffin. Aspects described herein further relate to a phosphono paraffin represented by formula (I): wherein each instance of R 1 is independently —H wherein each instance of R 2 and R 3 is independently linear or branched C 1-20 alkyl, C 1-20 cycloalkyl, or aryl; the number of instances where R 1 is of formula (I) is between about 2 and about 8; and n is an integer between 4 and 22.

  本文描述的方面通常涉及制备磷酸酯烷的方法，包括通过混合卤代烷，磷酸酯和碘化钠形成反应混合物。方法包括加热反应混合物以形成磷酸酯烷。本文所述的方面还涉及由公式（I）表示的磷酸酯烷： 其中，R1的每个实例独立地为-H，R2和R3的每个实例独立地为线性或支链的C1-20烷基，C1-20环烷基或芳基；R1在公式（I）中的实例数在大约2到大约8之间；n是介于4到22之间的整数。
• ADHESIVE COMPOSITION
  申请人：NIPPON SODA CO., LTD.

  公开号：US20210078931A1

  公开（公告）日：2021-03-18

  A novel adhesive composition that exhibits excellent adhesiveness even to materials having poor adhesiveness, such as polyolefin materials. The adhesive composition includes a polymer having a partial structure represented by formula [I] (where R 1 to R 3 each independently represent an unsubstituted or substituted aryl group; R 1 and R 2 , R 2 and R 3 , or R 3 and R 1 are optionally bonded by a single bond; A represents an unsubstituted or substituted arylene group; G represents a carbon atom, a silicon atom, or a germanium atom; and * represents a bonding position).

  一种新型粘合剂组合物，即使对于具有较差粘附性的材料，如聚烯烃材料，也表现出优异的粘附性。该粘合剂组合物包括具有由公式[I]表示的部分结构的聚合物（其中R1至R3分别独立地表示未取代或取代芳基；R1和R2、R2和R3或R3和R1可选择地通过单键连接；A表示未取代或取代芳基烃基；G表示碳原子、硅原子或锗原子；*表示键合位置）。