2,4,6-三(甲基硫代)-1,3,5-三嗪 | 5759-58-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 2,4,6-三(甲基硫代)-1,3,5-三嗪
• 英文名称: 2,4,6-tris(methylthio)-1,3,5-triazine
• 英文别名: s-Triazine, 2,4,6-tris(methylthio)-；2,4,6-tris(methylsulfanyl)-1,3,5-triazine
• CAS: 5759-58-0
• 化学式: C₆H₉N₃S₃
• mdl: MFCD01678800
• 分子量: 219.356
• InChiKey: KMWQATAKCGOGFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  115
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 危险等级：
  IRRITANT
• 危险品标志：
  Xi

反应信息

• 作为反应物：
  描述：

  2,4,6-三(甲基硫代)-1,3,5-三嗪 在 ammonium hydroxide 作用下， 生成 甲硫醇
  参考文献：
  名称：

  Obermeyer, Chemische Berichte, 1887, vol. 20, p. 2922

  摘要：

  DOI：
• 作为产物：
  描述：

  硫氰酸甲酯 在 三氟甲磺酸酐 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以88%的产率得到2,4,6-三(甲基硫代)-1,3,5-三嗪
  参考文献：
  名称：

  A Practical and Easy Synthesis of 2,4,6-Trisubstituted-s-triazines

  摘要：

  研究发现，在温和的条件下，三氟酸酐能有效地使二烷基氰酰胺发生环三聚反应。同样的反应也可用于芳基腈和硫氰酸盐。

  DOI：

  10.1055/s-2004-815927

文献信息

• CURABLE COMPOSITION, CURED PRODUCT, COLOR FILTER, METHOD FOR PRODUCING COLOR FILTER, SOLID-STATE IMAGING ELEMENT, AND IMAGE DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20200385582A1

  公开（公告）日：2020-12-10

  Provided are a curable composition including a compound represented by Formula 1 and having a maximum absorption wavelength in a range of 600 nm or more and less than 700 nm, or a polymer having a structure represented by Formula 2 and having a maximum absorption wavelength in a range of 600 nm or more and less than 700 nm; a polymerizable compound; and a chromatic colorant different from the compound represented by Formula 1 and the polymer represented by Formula 2, as well as a cured product of the curable composition; a color filter including the cured product; a method for producing a color filter; a solid-state imaging element; and an image display device.

  提供一种可治愈的组合物，包括由式1表示的化合物，其最大吸收波长在600纳米或更大且小于700纳米范围内，或者具有由式2表示的结构的聚合物，其最大吸收波长在600纳米或更大且小于700纳米范围内；一种可聚合的化合物；和一种与式1表示的化合物和式2表示的聚合物不同的色素染料，以及所述可治愈组合物的固化产物；包括所述固化产物的彩色滤光片；生产彩色滤光片的方法；固态成像元件；和图像显示装置。
• Inverse Electron Demand Diels-Alder Reactions of 2,4,6-(ethoxycarbonyl)-l,3,5-triazine and 2,4,6-(methylthio)-1,3,5-triazine: Pyrimidine Introduction
  作者：Dale L. Boger、Qun Dang

  DOI：10.1016/s0040-4020(01)85973-1

  日期：1988.1

  investigation of the scope of the participation of 2,4,6-(ethoxycarbonyl)-1, 3,5-triazine (1a) and 2.4.6-(methylthio)-1,3,5-triazine (1b) in inverse electron demand Diels-Alder reactions suitable for the preparation of functionalized 5,6-disubstituted pyrimidines is detailed. The use of the resulting [4 + 2] cycloadducts as immediate precursors to the parent 4,5-disubstltuted pyrimldines is described

  全面调查2,4,6- （乙氧羰基）-1，3,5-三嗪（1a）和2.4.6- （甲硫基）-1,3,5-三嗪（1b）的参与范围逆电子需求Diels-Alder反应适合于制备官能化的5,6-二取代的嘧啶。描述了将所得的[4 + 2]环加合物用作母体4,5-二取代的嘧啶的直接前体的用途。
• One-pot synthesis of new heterocycles: 2,4-disubstituted 6,7-dihydro-5H-benzo[6,7]cyclohepta[1,2-d]pyrimidines
  作者：A HERRERA、R MARTINEZALVAREZ、R CHIOUA、M CHIOUA

  DOI：10.1016/s0040-4039(03)00160-6

  日期：2003.3.3

  The reaction of 1-benzosuberone with nitriles in the presence of triflic anhydride affords in good yields 2,4-diaryl substituted 6,7-dihydro-5H-benzo[6,7]cyclohepta[1,2-d]pyrimidines, a new class of heterocycle.

  在三氟甲磺酸酐的存在下，1-苯并亚砜与腈的反应收率很高，得到2,4-二芳基取代的6,7-二氢-5 H-苯并[6,7]环庚[1,2- d ]嘧啶，新一类的杂环。
• PROCESS FOR ALKYLATING TRIAZINE DERIVATIVE
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0760369A1

  公开（公告）日：1997-03-05

  The object of the present invention is to provide a method for producing substituted-1,3,5-triazine derivatives at high yield, in which at least one of carbon atoms in the ring thereof is substituted by a secondary amine group having at leat one of alkyl groups. The method of the present invention is a method for alkylation of 1,3,5-triazine derivatives, characterized by reacting 1,3,5-triazine derivatives (melamines, melamine derivatives, various kinds of guanaminde derivatives, etc.) which has at least one or more amino groups or mono-substituted amino groups on carbon atom of the ring thereof, with aldehydes or ketones alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table and a hydrogen-containing gas to alkylate said at least one of amino groups or mono-substituted amino groups. These derivatives are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dyestuffs, paints and the like and are widely used resin materials and as flame-retardant materials.

  本发明的目的是提供一种高产率生产取代的-1,3,5-三嗪衍生物的方法，在这种衍生物中，其环上至少有一个碳原子被至少有一个烷基的仲胺基取代。 本发明的方法是 1,3,5-三嗪衍生物的烷基化方法，其特征是将 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种胍衍生物等）与至少具有一个或多个烷基的 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种胍衍生物等）反应。其特征是：在元素周期表中第 VII 族和/或 VIII 族金属和含氢气体催化剂的存在下，将环的碳原子上至少有一个或多个氨基或单取代氨基的 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种鸟苷酸衍生物等）与醛或酮醇反应，使上述至少一个氨基或单取代氨基烷基化。 这些衍生物被广泛用作精细化工产品的中间体，如农药、药物、染料、油漆等，也被广泛用作树脂材料和阻燃材料。
• EPOXY/ACID ANHYDRIDE COMPOSITION
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0834523A1

  公开（公告）日：1998-04-08

  (Object) It is to provide an epoxy/acid anhydride composition comprising an epoxy compound and an acid anhydride serving as a curing agent wherein a substituted triazine of a specific structure is employed as a curing accelerator to thereby impart a long pot life, a high storage stability and good working characteristics to the composition and cause no defect such as bubbling or cracking in the cured resin. (Constitution of the invention) An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [] (wherein X is an amino group, C1-18 monoalkylamino group, di C1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R1 and R2 independently each represent C1-12 alkyl group, C1-12 hydroxyalkyl group, C4-8 cycloalkyl group, C5-9 cycloalkylmethyl group or C5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  目的 提供一种环氧/酸酐组合物，该组合物由环氧化合物和用作固化剂的酸酐组成，其中使用了特定结构的取代三嗪作为固化促进剂，从而使该组合物具有较长的固化寿命、较高的储存稳定性和良好的工作特性，并且不会导致固化树脂出现气泡或开裂等缺陷。 (本发明的结构） 一种环氧树脂/酸酐组合物，其特征在于含有式[]的取代三嗪作为固化促进剂。 (其中 X 是氨基、C1-18 单烷基氨基、二 C1-18 烷基氨基、吗啉基、哌啶基、甲基或苯基；R1 和 R2 各自独立地代表环氧化合物和酸酐固化剂的环氧/酸酐组合物中的 C1-12 烷基、C1-12 羟基烷基、C4-8 环烷基、C5-9 环烷基甲基或 C5-9 甲基环烷基），以及通过热固化该环氧/酸酐组合物制备的环氧/酸酐树脂组合物。

表征谱图