1-methyldibenzo<1,4>dioxin | 123701-18-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并二恶英
• 英文名称: 1-methyldibenzo<1,4>dioxin
• 英文别名: 1-Methyldibenzo-p-dioxin
• CAS: 123701-18-8
• 化学式: C₁₃H₁₀O₂
• 分子量: 198.221
• InChiKey: SMPCVHNJTONGCD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-methyldibenzo<1,4>dioxin 、 叔丁基锂 、 二氧化碳 生成 9-methyldibenzo<1,4>dioxin-1-carboxylic acid
  参考文献：
  名称：

  PALMER, BRIAN D.;BOYD, MARUTA;DENNY, WILLIAM A., J. ORG. CHEM., 55,(1990) N, C. 438-441

  摘要：

  DOI：
• 作为产物：
  描述：

  二苯并对二噁英 、 碘甲烷 在 正丁基锂 、 四甲基乙二胺 作用下， 生成 1-methyldibenzo<1,4>dioxin
  参考文献：
  名称：

  Aromatic lithiation directed by the carboxylic acid group. Synthesis of 9-substituted dibenzodioxin-1-carboxylic acids and 6-substituted phenoxathiin-4-carboxylic acids

  摘要：

  DOI：

  10.1021/jo00289a012

文献信息

• ORGANOMETALLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20190019964A1

  公开（公告）日：2019-01-17

  An organic light-emitting device includes: a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the emission layer includes an organometallic compound of Formula 1. The organometallic compound of Formula 1 may be a phosphorescent dopant:

  一种有机发光器件包括：第一电极；第二电极；以及位于第一电极和第二电极之间的有机层，该有机层包括一个发射层，其中该发射层包括化合物Formula 1的有机金属化合物。Formula 1的有机金属化合物可能是一种磷光掺杂剂。
• CONDENSED-CYCLIC COMPOUND AND ORGANIC LIGHT EMITTING DEVICE COMPRISING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170062720A1

  公开（公告）日：2017-03-02

  The present disclosure provides a condensed-cyclic compound represented by Formula 1, in which one selected from R 1 to R 8 is a monoamine represented by Formula 2: The condensed-cyclic compound represented by Formula 1 may act as a hole transport material having a suitable energy level and band-gap. Further, the condensed-cyclic compound represented by Formula 1 has a fused core, and accordingly may have a high glass transition temperature (Tg), high melting point, and improved resistance to high temperatures. Therefore an organic light-emitting device including the condensed-cyclic compound represented by Formula 1 may retain high durability during storing and/or driving.

  本公开提供一种由化学式1表示的稠环化合物，其中R1至R8中选择一个为由化学式2表示的单胺：化学式1表示的稠环化合物可以作为具有适当能级和带隙的空穴传输材料。此外，化学式1表示的稠环化合物具有一个融合的核心，因此可能具有较高的玻璃转变温度（Tg）、高熔点和改善的耐高温性能。因此，包括化学式1表示的稠环化合物的有机发光器件在存储和/或驱动过程中可能保持高耐久性。
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：EP3133661A1

  公开（公告）日：2017-02-22

  An organic light-emitting device comprises: a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode , the organic layer comprising an emission layer and a hole transport region, wherein the hole transport region is between the first electrode and the emission layer, and the hole transport region comprises a first compound represented by Formula 1 and a second compound represented by Formula 2:

  一种有机发光器件包括：第一电极；第二电极；以及位于第一电极和第二电极之间的有机层，有机层包括发射层和空穴传输区域，其中空穴传输区域位于第一电极和发射层之间，空穴传输区域包括由式 1 表示的第一化合物和由式 2 表示的第二化合物：
• Condensed-cyclic compound and organic light emitting device comprising the same
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10361373B2

  公开（公告）日：2019-07-23

  The present disclosure provides a condensed-cyclic compound represented by Formula 1, in which one selected from R1 to R8 is a monoamine represented by Formula 2: The condensed-cyclic compound represented by Formula 1 may act as a hole transport material having a suitable energy level and band-gap. Further, the condensed-cyclic compound represented by Formula 1 has a fused core, and accordingly may have a high glass transition temperature (Tg), high melting point, and improved resistance to high temperatures. Therefore an organic light-emitting device including the condensed-cyclic compound represented by Formula 1 may retain high durability during storing and/or driving.

  本公开提供了一种由式 1 表示的缩合环状化合物，其中选自 R1 至 R8 的一种是由式 2 表示的单胺： 式 1 所代表的缩合环状化合物可作为空穴传输材料，具有合适的能级和带隙。此外，式 1 所代表的缩合环状化合物具有熔融核，因此可以具有高玻璃化转变温度（Tg）、高熔点和更好的耐高温性。因此，包括式 1 所代表的缩合环状化合物的有机发光器件在存储和/或驱动过程中可保持较高的耐用性。
• Organic light-emitting device
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10797246B2

  公开（公告）日：2020-10-06

  An organic light-emitting device includes: a first electrode; a second electrode; and an organic layer including an emission layer and a hole transport region between the first electrode and the second electrode, wherein the hole transport region is between the first electrode and the emission layer, and the hole transport region includes a first compound represented by Formula 1 and a second compound represented by Formula 2:

  一种有机发光器件包括：第一电极；第二电极；以及包括发射层和位于第一电极与第二电极之间的空穴传输区域的有机层，其中空穴传输区域位于第一电极与发射层之间，空穴传输区域包括由式 1 表示的第一化合物和由式 2 表示的第二化合物：