1-(chlorodimethylsilyl)-3-[N,N-bis(trimethylsilyl)amino]propane | 124774-86-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-(chlorodimethylsilyl)-3-[N,N-bis(trimethylsilyl)amino]propane
• 英文别名: Bistrimethylsilylaminopropyldimethylchlorosilane；3-[chloro(dimethyl)silyl]-N,N-bis(trimethylsilyl)propan-1-amine
• CAS: 124774-86-3
• 化学式: C₁₁H₃₀ClNSi₃
• 分子量: 296.075
• InChiKey: AFOVZRKWLMSDSL-UHFFFAOYSA-N

物化性质

• 沸点：
  284.3±42.0 °C(Predicted)
• 密度：
  0.881±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.79
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  乙烯基氯化镁 、 1-(chlorodimethylsilyl)-3-[N,N-bis(trimethylsilyl)amino]propane 以 四氢呋喃 为溶剂， 反应 6.0h， 生成 N,N-bistrimethylsilylaminopropyldimethylvinylsilane
  参考文献：
  名称：

  AMINO-CONTAINING VINYLSILANE COMPOUNDS AND MAKING METHOD

  摘要：

  具有特定氨基的乙烯硅烷化合物，通常为二乙胺丙基二甲基乙烯硅烷、N-甲基哌嗪基丙基二甲基乙烯硅烷和双三甲基硅氨基丙基二甲基乙烯硅烷，作为聚合物的改性剂具有新颖和有用的特性。

  公开号：

  US20100317852A1
• 作为产物：
  描述：

  双(三甲基硅烷基)氨基钾 在 Pt₂[CH₂=CHSi(CH₃)2OSi(CH₃)2CH=CH₂]3 六甲基二硅氮烷 作用下， 生成 1-(chlorodimethylsilyl)-3-[N,N-bis(trimethylsilyl)amino]propane
  参考文献：
  名称：

  Anionic Synthesis of Primary Amine Functionalized Polystyrenes via Hydrosilation of Allylamines with Silyl Hydride Functionalized Polystyrenes

  摘要：

  A general anionic omega-chain-end functionalization methodology is described and illustrated by the synthesis of omega-primary amine functionalized polystyrenes. First, the quantitative omega-silyl hydride functionalization of well-defined poly(styryl)lithium (M-n = 2200 and 14 100 g/mol) was effected with dimethylchlorosilane in hydrocarbon solution at room temperature. In the second step, involving amination by hydrosilation, the silyl hydride functionalized polystyrene was added quantitatively to 3-[N,N- bis(trimethylsilylamino]-l-propene, a protected amine, using Karstedt's Pt(0) hydrosilation catalyst in benzene. One of the principal advantages of this method is the fact that it is not necessary to use protecting groups for many functional groups, as illustrated by the quantitative primary amine functionalization of omega-silyl hydride functionalized poly(styryl)lithium with allylamine using the Karstedt's hydrosilation catalyst. The silyl hydride and amine functionalized polystyrenes were characterized by SEC, FTIR, H-1 and C-13 NMR, MALDI-TOF mass spectrometry, and end-group titration.

  DOI：

  10.1021/ma0513261

文献信息

• Amino-containing vinylsilane compounds and making method
  申请人：Tonomura Yoichi

  公开号：US08436166B2

  公开（公告）日：2013-05-07

  Vinylsilane compounds having a specific amino group, typically diethylaminopropyldimethylvinylsilane, N-methylpiperazinylpropyldimethylvinylsilane, and bistrimethylsilylaminopropyldimethylvinylsilane are novel and useful as a modifier for polymers.

  含有特定氨基的乙烯基硅烷化合物，通常为二乙氨丙基二甲基乙烯基硅烷、N-甲基哌嗪基丙基二甲基乙烯基硅烷和双三甲基硅氨基丙基二甲基乙烯基硅烷，是一种新颖且有用的聚合物改性剂。
• Bis(trimethylsilyl)aminopropyl substituted chlorosilanes
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP1481980B1

  公开（公告）日：2008-08-13
• Anionic Synthesis of Primary Amine Functionalized Polystyrenes via Hydrosilation of Allylamines with Silyl Hydride Functionalized Polystyrenes
  作者：Roderic P. Quirk、Hoon Kim、Michael J. Polce、Chrys Wesdemiotis

  DOI：10.1021/ma0513261

  日期：2005.9.1

  A general anionic omega-chain-end functionalization methodology is described and illustrated by the synthesis of omega-primary amine functionalized polystyrenes. First, the quantitative omega-silyl hydride functionalization of well-defined poly(styryl)lithium (M-n = 2200 and 14 100 g/mol) was effected with dimethylchlorosilane in hydrocarbon solution at room temperature. In the second step, involving amination by hydrosilation, the silyl hydride functionalized polystyrene was added quantitatively to 3-[N,N- bis(trimethylsilylamino]-l-propene, a protected amine, using Karstedt's Pt(0) hydrosilation catalyst in benzene. One of the principal advantages of this method is the fact that it is not necessary to use protecting groups for many functional groups, as illustrated by the quantitative primary amine functionalization of omega-silyl hydride functionalized poly(styryl)lithium with allylamine using the Karstedt's hydrosilation catalyst. The silyl hydride and amine functionalized polystyrenes were characterized by SEC, FTIR, H-1 and C-13 NMR, MALDI-TOF mass spectrometry, and end-group titration.
• AMINO-CONTAINING VINYLSILANE COMPOUNDS AND MAKING METHOD
  申请人：Tonomura Yoichi

  公开号：US20100317852A1

  公开（公告）日：2010-12-16

  Vinylsilane compounds having a specific amino group, typically diethylaminopropyldimethylvinylsilane, N-methylpiperazinylpropyldimethylvinylsilane, and bistrimethylsilylaminopropyldimethylvinylsilane are novel and useful as a modifier for polymers.

  具有特定氨基的乙烯硅烷化合物，通常为二乙胺丙基二甲基乙烯硅烷、N-甲基哌嗪基丙基二甲基乙烯硅烷和双三甲基硅氨基丙基二甲基乙烯硅烷，作为聚合物的改性剂具有新颖和有用的特性。