Isobutyltri-n-butylstannan | 97019-94-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: Isobutyltri-n-butylstannan
• 英文别名: (n-Bu)3Sn(i-Bu)；Stannane, tributyl(2-methylpropyl)-；tributyl(2-methylpropyl)stannane
• CAS: 97019-94-8
• 化学式: C₁₆H₃₆Sn
• 分子量: 347.172
• InChiKey: NZYSSHPDPTWGJP-UHFFFAOYSA-N

物化性质

• 沸点：
  120 °C(Press: 0.003 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  6.49
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三异丁基铝 、 三丁基氧化锡 以 四氢呋喃 为溶剂， 以83.5%的产率得到Isobutyltri-n-butylstannan
  参考文献：
  名称：

  Fountain brush

  摘要：

  公开号：

  US02095433A1

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.5.4.8, page 63 - 65
  作者：

  DOI：——

  日期：——
• Nomura, Ryoki; Fujii, Satoru; Matsuda, Haruo, Inorganic Chemistry, 1990, vol. 29, # 22, p. 4586 - 4588
  作者：Nomura, Ryoki、Fujii, Satoru、Matsuda, Haruo

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.5.1, page 272 - 276
  作者：

  DOI：——

  日期：——
• Schneider, B.; Neumann, W. P., Liebigs Annalen der Chemie, 1967, vol. 707, p. 7 - 14
  作者：Schneider, B.、Neumann, W. P.

  DOI：——

  日期：——
• Reactivity of intramolecularly coordinated aluminum compounds to R3EOH (E = Sn, Si). Remarkable migration of N,C,N and O,C,O pincer ligands
  作者：Libor Dostál、Roman Jambor、Aleš Růžička、Robert Jirásko、Ivana Císařová、Jaroslav Holeček

  DOI：10.1016/j.jorganchem.2005.08.043

  日期：2006.1

  The reaction of organoaluminum compounds containing O,C,O or N,C,N chelating (so called pincer) ligands [2,6-(YCH2)(2)C6H3]-(AlBu2)-Bu-i (Y = MeO 1, (BuO)-Bu-t 2, Me2N 3) with R3SnOH (R = Ph or Me) gives tetraorganotin complexes [2,6-(YCH2)(2)C6H3]SnR3 (Y = MeO, R = Ph 4, Y = MeO, R = Me 5; Y = (BuO)-Bu-t, R = Ph 6, Y = (BuO)-Bu-t, R = Me 7; Y = Me2N, R = Ph 8, Y = Me2N, R = Me 9) as the result of migration of O,C,O or N,C,N pincer ligands from aluminum to tin atom. Reaction of 1 and 2 with ((Bu3Sn)-Bu-n)(2)O proceeded in similar fashion resulting in 10 and 11 ([2,6-(YCH2)(2)C6H3](SnBu3)-Bu-n, Y = MeO 10; Y = (BuO)-Bu-t 11) in mixture with (Bu3SnBu)-Bu-n-Bu-i. The reaction I and 3 with 2 equiv. of Ph3SiOH followed another reaction path and ([2,6-(YCH2)(2)C6H3]Al(OSiPh3)(2), Y = MeO 12, Me2N 13) were observed as the products of alkane elimination. The organotin derivatives 4-11 were characterized by the help of elemental analysis, ESI-MS technique, H-1, C-13, Sn-119 NMR spectroscopy and in the case 6 and 8 by single crystal X-ray diffraction (XRD). Compounds 12 and 13 were identified using elemental analysis, H-1, C-13, Si-29 NMR and IR spectroscopy. (c) 2005 Elsevier B.V. All rights reserved.