4-benzoyloxyphenyl-(6'-O-benzoyl)-O-β-D-glucopyranoside

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 单宁
• 英文名称: 4-benzoyloxyphenyl-(6'-O-benzoyl)-O-β-D-glucopyranoside
• 英文别名: [(2R,3S,4S,5R,6S)-6-(4-benzoyloxyphenoxy)-3,4,5-trihydroxyoxan-2-yl]methyl benzoate
• 化学式: C₂₆H₂₄O₉
• 分子量: 480.471
• InChiKey: RQOQCQVYRVKJIL-MYIDKPJBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  35
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  132
• 氢给体数：
  3
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  苯甲酸 、 熊果苷 在 吡啶 、 双(2-氧代-3-恶唑烷基)次磷酰氯 作用下， 反应 3.0h， 以0.420 g的产率得到4-hydroxyphenyl-(6'-O-benzoyl)-O-β-D-glucopyranoside
  参考文献：
  名称：

  Polyphenolic Glycosides from African Proteaceae

  摘要：

  The phytochemical investigation of members of the genus Protea afforded a series of polyphenolic compounds (1-5) that were identified by 1D and 2D NMR experiments. Of these, 2-5 are new compounds. Chemical syntheses of 1-3 were performed in order to confirm the structures and to prepare additional material for biological evaluation.

  DOI：

  10.1021/np9902237

文献信息

• Polyphenolic Glycosides from African Proteaceae
  作者：L. Verotta、F. Orsini、F. Pelizzoni、G. Torri、C. B. Rogers

  DOI：10.1021/np9902237

  日期：1999.11.1

  The phytochemical investigation of members of the genus Protea afforded a series of polyphenolic compounds (1-5) that were identified by 1D and 2D NMR experiments. Of these, 2-5 are new compounds. Chemical syntheses of 1-3 were performed in order to confirm the structures and to prepare additional material for biological evaluation.