1-chloro-1,1,3,3-tetramethyl-3-vinyl-1,3-disiloxane | 142042-23-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-chloro-1,1,3,3-tetramethyl-3-vinyl-1,3-disiloxane
• 英文别名: vinyltetramethylchlorodisiloxane；Chloro-[ethenyl(dimethyl)silyl]oxy-dimethylsilane
• CAS: 142042-23-7
• 化学式: C₆H₁₅ClOSi₂
• 分子量: 194.809
• InChiKey: OAODKCMJSAKCRB-UHFFFAOYSA-N

物化性质

• 沸点：
  140.2±13.0 °C(Predicted)
• 密度：
  0.919±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.87
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-chloro-1,1,3,3-tetramethyl-3-vinyl-1,3-disiloxane 、 苯硼酸 在 三乙胺 作用下， 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of difunctional borasiloxanes and their behavior in metathesis reactions

  摘要：

  New divinyl- and diallyl-borasiloxanes have been synthesized in good yield from corresponding boronic acids. They have been characterized by H-1-, C-13-, Si-29- and B-11-NMR, as well as by MS. Their behavior in metathesis reactions initiated by two different catalysts ([RhCl(COD)](2) for vinylsiloxanes and [Mo] Schrock's catalyst for allylsiloxanes) has been studied. This has led to new cycloborasiloxanes that have been characterized. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00498-7
• 作为产物：
  描述：

  dimethyl vinyl silanol 、 二氯二甲基硅烷 在 三乙胺 作用下， 以 乙醚 为溶剂， 反应 4.0h， 以51%的产率得到1-chloro-1,1,3,3-tetramethyl-3-vinyl-1,3-disiloxane
  参考文献：
  名称：

  Synthesis of difunctional borasiloxanes and their behavior in metathesis reactions

  摘要：

  New divinyl- and diallyl-borasiloxanes have been synthesized in good yield from corresponding boronic acids. They have been characterized by H-1-, C-13-, Si-29- and B-11-NMR, as well as by MS. Their behavior in metathesis reactions initiated by two different catalysts ([RhCl(COD)](2) for vinylsiloxanes and [Mo] Schrock's catalyst for allylsiloxanes) has been studied. This has led to new cycloborasiloxanes that have been characterized. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00498-7

文献信息

• Reactions of Trichlorogermane and Trimethylgermane Etherates with 1,3-Divinyl-1,1,3,3-tetramethyldisiloxane
  作者：V. G. Lakhtin、A. I. Blagushina、N. V. Ushakov、I. B. Sokolʼskaya、I. A. Semyashkina、D. A. Efimenko、I. A. Gritskova、N. G. Komalenkova、P. A. Storozhenko

  DOI：10.1134/s1070363220060067

  日期：2020.6

  AbstractThe effect of the reactant ratio in the reaction of tetramethyldisiloxane with germanium tetrachloride and diethyl ether on the structure and reactivity of the resulting trichlorogermane–diethyl ether complexes was studied, and the products were reacted with 1,1,3,3-tetramethyl-1,3-divinyldisiloxane. The hydrogermylation of 1,1,3,3-tetramethyl-1,3-divinyldisiloxane with trimethylgermane in

  摘要研究了四甲基二硅氧烷与四氯化锗和二乙醚反应中反应物比例对所得三氯锗烷-二乙醚配合物的结构和反应活性的影响，并将产物与1,1,3,3-四甲基-1 ，3-二乙烯基二硅氧烷。在Karstedt催化剂的存在下，1,1,3,3-四甲基-1,3-二乙烯基二硅氧烷与三甲基锗烷的氢加氢甲基化反应仅在底物的一个和两个双键上提供了相应的抗马氏复合物。
• Synthesis of difunctional borasiloxanes and their behavior in metathesis reactions
  作者：Anne-Françoise Mingotaud、Valérie Héroguez、Alain Soum

  DOI：10.1016/s0022-328x(98)00498-7

  日期：1998.6

  New divinyl- and diallyl-borasiloxanes have been synthesized in good yield from corresponding boronic acids. They have been characterized by H-1-, C-13-, Si-29- and B-11-NMR, as well as by MS. Their behavior in metathesis reactions initiated by two different catalysts ([RhCl(COD)](2) for vinylsiloxanes and [Mo] Schrock's catalyst for allylsiloxanes) has been studied. This has led to new cycloborasiloxanes that have been characterized. (C) 1998 Elsevier Science S.A. All rights reserved.