四(二乙基氨基)硅烷 | 17048-10-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 四(二乙基氨基)硅烷
• 英文名称: tetrakis(diethylamino)silane
• 英文别名: tetra(diethylamino) silane；tetra(diethylamino)silane；Si(NEt2)4；tetrakis-diethylamino-silane；Tetrakis-diaethylamino-silan；Octaethylsilanetetramine；N-ethyl-N-[tris(diethylamino)silyl]ethanamine
• CAS: 17048-10-1
• 化学式: C₁₆H₄₀N₄Si
• 分子量: 316.606
• InChiKey: GURMJCMOXLWZHZ-UHFFFAOYSA-N

物化性质

• 熔点：
  3-4 °C
• 沸点：
  156-158 °C(Press: 14 Torr)
• 密度：
  0.9026 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.44
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  四(二乙基氨基)硅烷 、 2-氨基-5-硝基苯酚 在 N-甲基吡咯烷酮 作用下， 以 甲苯 为溶剂， 反应 16.0h， 以80%的产率得到
  参考文献：
  名称：

  An Alternative Route Based on Acid−Base Hydrolytic Chemistry to NLO Active Organic−Inorganic Hybrid Materials for Second-Order Nonlinear Optics

  摘要：

  An alternative approach, based on simple acid-base hydrolytic chemistry, to prepare organic-inorganic composites is reported. In these hybrid materials, NLO-active chromophores such as Disperse Red 19, a pyridinium salt based dye, and 1-amino-4-nitrobenzene are covalently locked into silica networks. The resulting hybrids are soluble and offer ease of processibility in the preparation of good-optical-quality thin films. Network materials that are akin to the traditional sol-gel approach are also prepared from,the monofunctional NLO chromophore DR1 and, as expected, are found to be insoluble. Physical properties of the NLO chromophore-incorporated hybrids can be tailored by changing the molar amounts of chromophores and water, and the type of chromophore. High thermal stability and glass-transition temperatures of these hybrids offer effective electric-field poling at high temperatures and long-term temporal stabilities of the second-harmonic-generation signals at room temperature and at 80 degrees C. The chi((2)) values for the networks were found to be in the range of (1.2-37) x 10(-8) esu.

  DOI：

  10.1021/ja983274j
• 作为产物：
  描述：

  二乙胺 生成 四(二乙基氨基)硅烷
  参考文献：
  名称：

  Kannengiesser,G.; Damm,F., Bulletin de la Societe Chimique de France, 1967, p. 2492 - 2495

  摘要：

  DOI：

文献信息

• Organometallic compound, its synthesis method, and solution raw material and metal-containing thin film containing the same
  申请人：MITSUBISHI MATERIALS CORPORATION

  公开号：US20040210071A1

  公开（公告）日：2004-10-21

  The organometallic compound of the present invention is a compound that has bonds between metal atoms and nitrogen atoms or bonds between semimetal atoms and nitrogen atoms, and the content of chlorine in the compound is 200 ppm or less and the content of water is 30 ppm or less. In addition, the general formula of this compound is represented by the following formula (1): M [( R 1 ) 2 N ] (n−s) ( R 2 ) s (1) wherein, M represents a metal atom or semimetal atom, with the metal atom being Hf, Zr, Ta, Ti, Ce, Al, V, La, Nb or Ni, and the semimetal atom being Si, R 1 represents a methyl group or ethyl group, R 2 represents an ethyl group, n represents the valence of M, and s represents an integer of 0 to n−1.

  本发明的有机金属化合物是一种具有金属原子与氮原子之间的键或半金属原子与氮原子之间的键的化合物，该化合物中氯的含量为200 ppm或更低，水的含量为30 ppm或更低。此化合物的一般式由以下式（1）表示：M[(R1)2N](n−s)(R2)s(1)其中，M代表金属原子或半金属原子，金属原子为Hf、Zr、Ta、Ti、Ce、Al、V、La、Nb或Ni，半金属原子为Si，R1代表甲基基团或乙基基团，R2代表乙基基团，n代表M的化合价，s代表0到n-1之间的整数。
• Breederveld; Waterman, Research (London), 1953, vol. 6, p. Spl.50
  作者：Breederveld、Waterman

  DOI：——

  日期：——
• Synthèse et activité radioprotectrice de nouveaux trithiagermatranes, trithiasilatranes, oxyde et sulfure germaniés à substituant chlorhydrate de cystéamine et N(2-thioéthyl)-1,3-diaminopropane
  作者：G Rima、J Satgé、M Fatome、JD Laval、H Sentenac-Roumanou、C Lion、M Lazraq

  DOI：10.1016/0223-5234(91)90061-q

  日期：1991.4

  New organotrithiagermatranes, trithiasilatranes, bicyclodithiazagermolidines and 6-aza-1,3-dithia 2-germaperhydrocine with cysteamine and N-(2-thioethyl)-1,3-diaminopropane chlorhydrate ligands and germylated oxide and sulfide with N-(2-thioethyl)-1,3-diaminopropane chlorhydrate ligands were synthesized. Their toxicities and radioprotective activities were determined.
• TAMANO, MICHIKO;KOKETSU, JUGO, J. CHEM. SOC. JAP., CHEM. AND IND. CHEM., 1986, N 6, 796-800
  作者：TAMANO, MICHIKO、KOKETSU, JUGO

  DOI：——

  日期：——
• An Alternative Route Based on Acid−Base Hydrolytic Chemistry to NLO Active Organic−Inorganic Hybrid Materials for Second-Order Nonlinear Optics
  作者：Hongwei Jiang、Ashok K. Kakkar

  DOI：10.1021/ja983274j

  日期：1999.4.1

  An alternative approach, based on simple acid-base hydrolytic chemistry, to prepare organic-inorganic composites is reported. In these hybrid materials, NLO-active chromophores such as Disperse Red 19, a pyridinium salt based dye, and 1-amino-4-nitrobenzene are covalently locked into silica networks. The resulting hybrids are soluble and offer ease of processibility in the preparation of good-optical-quality thin films. Network materials that are akin to the traditional sol-gel approach are also prepared from,the monofunctional NLO chromophore DR1 and, as expected, are found to be insoluble. Physical properties of the NLO chromophore-incorporated hybrids can be tailored by changing the molar amounts of chromophores and water, and the type of chromophore. High thermal stability and glass-transition temperatures of these hybrids offer effective electric-field poling at high temperatures and long-term temporal stabilities of the second-harmonic-generation signals at room temperature and at 80 degrees C. The chi((2)) values for the networks were found to be in the range of (1.2-37) x 10(-8) esu.