3-甲基-1-丁醇磷酸酯 | 919-62-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 3-甲基-1-丁醇磷酸酯
• 中文别名: [4-(3,3,4,4,5,5,6,6,6-九氟己基)苯基]甲醇
• 英文名称: triisoamyl phosphate
• 英文别名: Tri-isoamyl-phosphat；Phosphoric acid, triisoamyl ester；tris(3-methylbutyl) phosphate
• CAS: 919-62-0
• 化学式: C₁₅H₃₃O₄P
• 分子量: 308.398
• InChiKey: YQLIHRFKJJQBAF-UHFFFAOYSA-N

物化性质

• 沸点：
  297.7±8.0 °C(Predicted)
• 密度：
  0.962±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-甲基-1-丁醇磷酸酯 、 草酸 以 十二烷 为溶剂， 生成
  参考文献：
  名称：

  Extraction of oxalic acid from solutions of electrolyte mixture

  摘要：

  Extraction of oxalic acid with tributyl phosphate and triisoamyl phosphate Solutions of its mixtures with nitric, phosphoric, sulfuric, and hydrochloric acid and with ammonium nitrate and chloride was studied. In the extractability series, oxalic acid occupies the position between nitric and phosphoric acids, with sulfuric and hydrochloric acids acting as strong salting-out agents. Nitric acid salts drastically decrease the distribution ratios of oxalic acid.

  DOI：

  10.1134/s1070427208090012
• 作为产物：
  描述：

  异戊醇 在 磷酸 作用下， 以98.3%的产率得到3-甲基-1-丁醇磷酸酯
  参考文献：
  名称：

  生产磷酸三异戊酯的方法及所用装置

  摘要：

  本发明公开了一种用于制备磷酸三异戊酯的反应精馏装置以及利用该反应精馏装置生产磷酸三异戊酯的方法，方法包括以下步骤：在反应精馏塔的中部设置超强固体酸催化剂，超强固体酸催化剂兼作填料；在塔釜内预先存储异戊醇；以异戊醇和磷酸作为原料，磷酸预热后从反应精馏塔的填料段顶部进料；异戊醇通过塔釜加热后以气体形式从反应精馏塔填料段底部进料；磷酸三异戊酯粗品从反应精馏塔底部的侧线出料口流出。

  公开号：

  CN113121593B

文献信息

• Method for Producing Quaternary Ammonium Compounds
  申请人：Szarvas Laszlo

  公开号：US20070254822A1

  公开（公告）日：2007-11-01

  The present invention relates to a process for preparing quaternary ammonium compounds, which comprises reacting compounds comprising an sp 3 -hybridized nitrogen atom with a dialkyl sulfate or trialkyl phosphate and subjecting the resulting ammonium compound to an anion exchange.

  本发明涉及一种制备季铵盐化合物的方法，包括将含有sp3杂化氮原子的化合物与二烷基硫酸盐或三烷基磷酸酯反应，并将所得的铵盐化合物进行阴离子交换。
• Solvent-Free Microwave Synthesis of Trialkylphosphates
  作者：Laaldja Meddour-Boukhobza、Abdelhamid Elias、Mohamed Didi

  DOI：10.13005/ojc/300131

  日期：2014.3.30

  Trialkylphosphates are synthesized from alcohols by reaction with reactive phosphorus oxychloride under microwave irradiations and classical heating. Effects of these irradiations on the nature of the products and on the yield are studied.  The compounds were characterized by their spectroscopic data and elemental analysis. The obtained results show that the products of these reactions are essentially trialkylphosphates and alkylphosphoric acids.  They always show as the nature of the formed products and the yields in trialkylphosphates are comparable to those obtained in the classical conditions of heating. The speed of the reaction was increased by a factor from 40 to 120.

  在微波辐照和传统加热条件下，通过与活性氧氯化磷反应，从醇类合成三烷基磷酸盐。研究了这些辐照对产物性质和产量的影响。 通过光谱数据和元素分析对化合物进行了表征。研究结果表明，这些反应的产物主要是三烷基磷酸盐和烷基磷酸。 它们始终显示出所形成产物的性质，三烷基磷酸盐的产率与传统加热条件下获得的产率相当。反应速度从 40 倍提高到 120 倍。
• CONVERSION OF PRENYL DERIVATIVES TO ISOPRENE
  申请人：MCAULIFFE Joseph C.

  公开号：US20100113846A1

  公开（公告）日：2010-05-06

  The present invention provides methods for producing derivatives from cultured cells. In addition, the present invention provides methods for conversion of prenyl deerivatives, obtained from biological or petrochemical sources, to isoprene by employing chemical or biological catalysts. The present invention also provides compositions that include the cultured cells or isoprene or prenyl derivatives produced there from.

  本发明提供了一种从培养细胞中生产衍生物的方法。此外，本发明提供了一种将从生物或石油化学来源获得的萜基衍生物转化为异戊二烯的方法，通过使用化学或生物催化剂。本发明还提供了包括培养细胞、异戊二烯或其衍生物的组合物。
• Servo valve erosion inhibited aircraft hydraulic fluids
  申请人：——

  公开号：US20020179883A1

  公开（公告）日：2002-12-05

  The incorporation of a minor amount of a salt of pentafluorobenzene sulfonic acid to phosphate ester based functional fluids enhances the anti-erosion properties of the fluid.

  向磷酸酯基功能液体中加入少量五氟苯磺酸盐可以增强该液体的抗侵蚀性能。
• Functional fluid compositions containing epoxide acid scavengers
  申请人：——

  公开号：US20020033478A1

  公开（公告）日：2002-03-21

  A phosphate ester-based functional fluid composition that generates reduced levels of carboxylic acid during use by incorporating at least one acid scavenger selected from the epoxides of the invention. The phosphate ester-based functional fluids are particularly useful as hydraulic fluids.

  一种以磷酸酯为基础的功能性流体组合物，通过将本发明的环氧化物中的至少一种酸清除剂纳入使用中生成降低水平的羧酸。磷酸酯基功能流体在液压油方面特别有用。