N,N-bis-(2-hydroxy-ethyl)-2-(9-oxo-9H-thioxanthen-2-yloxy)-acetamide | 1129771-56-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 英文名称: N,N-bis-(2-hydroxy-ethyl)-2-(9-oxo-9H-thioxanthen-2-yloxy)-acetamide
• 英文别名: N,N-bis(2-hydroxyethyl)-2-(9-oxothioxanthen-2-yl)oxyacetamide
• CAS: 1129771-56-7
• 化学式: C₁₉H₁₉NO₅S
• 分子量: 373.43
• InChiKey: LNHYGSFZOGQLNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  112
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N-bis-(2-hydroxy-ethyl)-2-(9-oxo-9H-thioxanthen-2-yloxy)-acetamide 在 吡啶 、 1,3-二硝基苯 、 三乙胺 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 5.42h， 以62%的产率得到2-[[2-(9-oxothioxanthen-2-yl)oxyacetyl]-(2-prop-2-enoyloxyethyl)amino]ethyl prop-2-enoate
  参考文献：
  名称：

  Radiation curable compositions for food applications

  摘要：

  公开号：

  EP2033949B1
• 作为产物：
  描述：

  (9-oxo-9H-thioxanthen-2-yloxy)-acetic acid methyl ester 、 二乙醇胺 在 potassium hydroxide 作用下， 反应 1.5h， 生成 N,N-bis-(2-hydroxy-ethyl)-2-(9-oxo-9H-thioxanthen-2-yloxy)-acetamide
  参考文献：
  名称：

  Polymerizable photoinitiators and radiation curable compositions

  摘要：

  公开号：

  EP2199273B1

文献信息

• [EN] SYNTHESIS OF ACETAL COMPOUNDS USING ZWITTERIONIC CATALYSTS<br/>[FR] SYNTHÈSE DE COMPOSÉS ACÉTAL À L'AIDE DE CATALYSEURS ZWITTERIONIQUES
  申请人：AGFA GRAPHICS NV

  公开号：WO2015062935A1

  公开（公告）日：2015-05-07

  A process for the preparation of optionally asymmetric acetal compounds, comprising reacting a compound containing a hydroxyl group with a vinylether compound in the presence of a zwitterionic catalyst including at least one basic nitrogen containing structural fragment and at least one sulfonic acid group in its structure, with the proviso that the basic nitrogen on sulfonic acid molar ratio is 1 over 1.

  一种制备可选择性不对称缩醛化合物的方法，包括在带有至少一个碱性氮结构基团和至少一个磺酸基团的偶极催化剂存在下，将含有羟基的化合物与乙烯基醚化合物反应，但碱性氮和磺酸的摩尔比为1比1。
• SYNTHESIS OF ACETAL COMPOUNDS
  申请人：AGFA GRAPHICS NV

  公开号：US20160237185A1

  公开（公告）日：2016-08-18

  A process for the preparation of optionally asymmetric acetal compounds includes reacting a compound containing a hydroxyl group with a vinylether compound in the presence of a zwitterionic catalyst including at least one basic nitrogen containing structural fragment and at least one sulfonic acid group in its structure, with the proviso that a molar ratio of the basic nitrogen to sulfonic acid is 1:1

  一种制备可选非对称缩醛化合物的方法，包括在带有至少一个碱性氮结构片段和至少一个磺酸基团的中性离子催化剂存在下，将含有羟基的化合物与乙烯醚化合物反应，但碱性氮与磺酸的摩尔比为1:1。
• RADIATION CURABLE COMPOSITIONS FOR FOOD APPLICATIONS
  申请人：Loccufier Johan

  公开号：US20100304149A1

  公开（公告）日：2010-12-02

  A liquid radiation curable composition for inkjet printing includes a photoinitiating system consisting of one or more diffusion hindered photoinitiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric or polymeric initiators, and polymerizable initiators, and one or more polymerizable co-initiators, wherein at least one of the polymerizable co-initiators is a polymerizable aromatic tertiary amine. Inkjet inks, an inkjet printing process, and packaging materials may include the liquid radiation curable composition.

  一种用于喷墨打印的液体辐射固化组合物，包括一个光引发系统，该系统由选自非聚合二元或多功能引发剂、寡聚物或聚合物引发剂和可聚合引发剂的一种或多种扩散受阻光引发剂组成，以及一种或多种可聚合共同引发剂，其中至少一种可聚合共同引发剂是可聚合芳香族三级胺。喷墨墨水、喷墨打印过程和包装材料可能包括该液体辐射固化组合物。
• Synthesis of acetal compounds using zwitterionic catalysts
  申请人：AGFA NV

  公开号：EP2868650B1

  公开（公告）日：2018-08-08
• POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110224324A1

  公开（公告）日：2011-09-15

  A polymerizable photoinitiator is represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w=1 to (p−z) and z=0 to (p−w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation.