2-[2-[1-[2-[[2-(9-Oxothioxanthen-2-yl)oxyacetyl]-[2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl]amino]ethoxy]ethoxy]ethoxy]ethyl prop-2-enoate | 1231708-15-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 英文名称: 2-[2-[1-[2-[[2-(9-Oxothioxanthen-2-yl)oxyacetyl]-[2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl]amino]ethoxy]ethoxy]ethoxy]ethyl prop-2-enoate
• CAS: 1231708-15-8
• 化学式: C₃₇H₄₇NO₁₃S
• 分子量: 745.845
• InChiKey: KGBHEHKLVDSTDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  52
• 可旋转键数：
  29
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  180
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  丙烯酸乙烯基乙氧基乙酯 、 N,N-bis-(2-hydroxy-ethyl)-2-(9-oxo-9H-thioxanthen-2-yloxy)-acetamide 在 3-吡啶磺酸 、 2,6-二叔丁基-4-甲基苯酚 作用下， 反应 22.0h， 生成 2-[2-[1-[2-[[2-(9-Oxothioxanthen-2-yl)oxyacetyl]-[2-[1-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl]amino]ethoxy]ethoxy]ethoxy]ethyl prop-2-enoate
  参考文献：
  名称：

  Synthesis of acetal compounds using zwitterionic catalysts

  摘要：

  公开号：

  EP2868650B1

文献信息

• [EN] POLYMERIZABLE THIOXANTHONES<br/>[FR] THIOXANTHONES POLYMÉRISABLES
  申请人：AGFA GRAPHICS NV

  公开号：WO2014009194A1

  公开（公告）日：2014-01-16

  A polymerizable thioxanthone according to Formula (I) wherein, A represents a thioxanthone moiety; R1 and R2 are independently selected from the group consisting of a hydrogen, an alkyl group, an aikenyl group, an alkynyl group, an aryl group and a heteroaryl group; n represent 1 or 2; and R3 represents a moiety comprising at least one free radical polymerizable group selected from the group consisting of an acrylate, a methacrylate, an acryiamide, a methacrylamide, a styrene group, a maleate, a fumarate, an itaconate, a vinyl ether, a viny! ester, an allyl ether and an ally! ester.

  化合物式（I）中的可聚合噻吩酮，其中，A代表噻吩酮基团；R1和R2独立地选自氢、烷基、烯基、炔基、芳基和杂芳基的群；n表示1或2；R3代表至少包含一种自由基聚合基团的基团，所述自由基聚合基团选自丙烯酸酯、甲基丙烯酸酯、丙烯酰胺、甲基丙烯酰胺、苯乙烯基团、马来酸酯、富马酸酯、己二酸酯、乙烯醚、乙烯酯、烯丙基醚和烯丙基酯的群。
• [EN] SYNTHESIS OF ACETAL COMPOUNDS USING ZWITTERIONIC CATALYSTS<br/>[FR] SYNTHÈSE DE COMPOSÉS ACÉTAL À L'AIDE DE CATALYSEURS ZWITTERIONIQUES
  申请人：AGFA GRAPHICS NV

  公开号：WO2015062935A1

  公开（公告）日：2015-05-07

  A process for the preparation of optionally asymmetric acetal compounds, comprising reacting a compound containing a hydroxyl group with a vinylether compound in the presence of a zwitterionic catalyst including at least one basic nitrogen containing structural fragment and at least one sulfonic acid group in its structure, with the proviso that the basic nitrogen on sulfonic acid molar ratio is 1 over 1.

  一种制备可选择性不对称缩醛化合物的方法，包括在带有至少一个碱性氮结构基团和至少一个磺酸基团的偶极催化剂存在下，将含有羟基的化合物与乙烯基醚化合物反应，但碱性氮和磺酸的摩尔比为1比1。
• SYNTHESIS OF ACETAL COMPOUNDS
  申请人：AGFA GRAPHICS NV

  公开号：US20160237185A1

  公开（公告）日：2016-08-18

  A process for the preparation of optionally asymmetric acetal compounds includes reacting a compound containing a hydroxyl group with a vinylether compound in the presence of a zwitterionic catalyst including at least one basic nitrogen containing structural fragment and at least one sulfonic acid group in its structure, with the proviso that a molar ratio of the basic nitrogen to sulfonic acid is 1:1

  一种制备可选非对称缩醛化合物的方法，包括在带有至少一个碱性氮结构片段和至少一个磺酸基团的中性离子催化剂存在下，将含有羟基的化合物与乙烯醚化合物反应，但碱性氮与磺酸的摩尔比为1:1。
• Polymerizable photoinitiators and radiation curable compositions
  申请人：AGFA Graphics NV

  公开号：EP2199273A1

  公开（公告）日：2010-06-23

  A polymerizable photoinitiator represented by Formula (I): and wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w = 1 to (p-z) and z = 0 to (p-w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation. Radiation curable compositions including the polymerizable photoinitiator and methods of preparing the polymerizable photoinitiator are also disclosed.

  由式 (I) 表示的可聚合光引发剂： 其中 R1、R2 和 R3 独立地选自氢、任选取代的烷基和任选取代的芳基组成的组，或 R1 和 R3 代表形成五至八分子环所需的原子； p、w、y 和 z 均为整数，其中 y 代表 1 至 6 的值；p 代表 w 和 z 的和；p 代表 1 至 6 的值；w = 1 至 (p-z) 和 z = 0 至 (p-w)；L 代表由 1 至 14 个碳原子组成的任选取代的 (p+y)- 价连接基团； A 代表可辐射聚合的基团，选自由下列基团：丙烯酸酯基团、甲基丙烯酸 酯基团、苯乙烯基团、丙烯酰胺基团、甲基丙烯酸酰胺基团、马来酸 酯基团、富马酸酯基团、伊塔康酸酯基团、乙烯基醚基团、烯丙基醚基 团、烯丙基酯基团和乙烯基酯基团；以及 X 代表光引发基，包括至少一个在暴露于光辐射时能引发自由基聚合反应的基团。还公开了包括可聚合光引发剂的辐射固化组合物和制备可聚合光引发剂的方法。
• Radiation curable compositions for food packaging
  申请人：AGFA GRAPHICS NV

  公开号：US10316204B2

  公开（公告）日：2019-06-11

  A radiation curable inkjet ink set includes at least a cyan radiation curable inkjet ink, a magenta radiation curable inkjet ink, a yellow radiation curable inkjet ink, and a black radiation curable inkjet ink, each having a viscosity of no more than 50 mPa·s at 25° C. and a shear rate of 90 s−1 and containing: a) at least one non-polymerizable, non-polymeric bisacylphosphine oxide present in a concentration of no more than 4.0 wt % based on the total weight of the radiation curable composition; b) at least one monomer including at least one vinyl ether group and at least one polymerizable group selected from the group consisting of an acrylate group and a methacrylate group; and c) at least one polymerizable or polymeric thioxanthone, with the proviso that if the at least one polymerizable or polymeric thioxanthone contains no tertiary amine group that the radiation curable composition further includes at least one tertiary amine co-initiator selected from the group consisting of ethylhexyl-4-dimethylaminobenzoate, a polymerizable co-initiator containing a tertiary amine and a polymeric co-initiator containing a tertiary amine.

  一种辐射固化喷墨墨水组至少包括青色辐射固化喷墨墨水、品红色辐射固化喷墨墨水、黄色辐射固化喷墨墨水和黑色辐射固化喷墨墨水，每种墨水在 25° C 时的粘度不超过 50 mPa-s，剪切速率为 90 s-1，并含有： a) 至少一种不可聚合的非聚合双酰基氧化膦，其浓度不超过辐射固化组合物总重量的 4.b) 至少一种单体，包括至少一个乙烯基醚基团和至少一个可聚合基团，该基团选自由丙烯酸酯基团和甲基丙烯酸酯基团组成的组；c) 至少一种可聚合或聚合硫杂蒽酮，但如果至少一种可聚合或聚合硫杂蒽酮不含叔胺基团，则辐射固化组合物还包括至少一种叔胺助引发剂，该助引发剂选自 4-二甲氨基苯甲酸乙基己酯、含叔胺的可聚合助引发剂和含叔胺的聚合助引发剂组成的组。