Al[N(SiMe3)2]3 | 25605-37-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Al[N(SiMe3)2]3
• 英文别名: tris[bis(trimethylsilyl)amino]aluminum；[Al{N(SiMe₃)₂}₃]；Al[N(SiMe₃)₂]₃；Al(N(SiMe3)2)3；Aluminium-hexakis-(trimethylsilyl)-triamid；Aluminium-hexakis-trimethylsilyl-triamid
• CAS: 25605-37-2
• 化学式: C₁₈H₅₄AlN₃Si₆
• 分子量: 508.141
• InChiKey: KZRQNAMACMILIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.65
• 重原子数：
  10.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  14.1
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Al[N(SiMe3)2]3 、 2,2,2',2'-tetramethyl-5,5'-(ethane-1,2-diyldiimino)bis(hex-4-en-3-one) 以 正庚烷 为溶剂， 以92%的产率得到bis-5,5'-(1,3-ethanediyldiimino)-2,2-dimethyl-4-hexene-3-onato aluminum bis(trimethylsilyl)amino
  参考文献：
  名称：

  带有无环四齿席夫碱的两个五配位烷基铝和双（三甲基甲硅烷基）氨基配合物的合成和结构表征

  摘要：

  摘要两个无环席夫碱配体bis-5,5'-（1,3-丙二基二亚氨基）-2,2-二甲基-4-己烯-3-一和bis-5,5'-（1,3-乙二基二亚氨基） ）-2，2-二甲基-4-己烯-3-酮分别用于络合均均三乙基铝和三[双（三（甲基硅烷基）氨基]铝。酸碱反应以优异的收率进行，在原质Schiff碱原位去质子化过程中消除了乙烷或双（三甲基甲硅烷基）胺。由正戊烷结晶的无色铝络合物，通过包括单晶X射线衍射在内的标准方法进行表征。外消旋丙交酯的聚合反应，再加上醇，得到的聚乳酸具有较窄的多分散性，但分子量较低。

  DOI：

  10.1016/j.poly.2007.03.008
• 作为产物：
  描述：

  三氯化铝 、 lithium hexamethyldisilazane 以 苯 为溶剂， 以40.8%的产率得到Al[N(SiMe3)2]3
  参考文献：
  名称：

  Paciorek; Nakahara; Masuda, Inorganic Chemistry, 1990, vol. 29, # 21, p. 4252 - 4255

  摘要：

  DOI：

文献信息

• MOLECULAR PRECURSOR COMPOUNDS FOR ZINC-GROUP 13 MIXED OXIDE MATERIALS
  申请人：Precursor Energetics, Inc.

  公开号：US20150218190A1

  公开（公告）日：2015-08-06

  Molecular precursor compounds, processes and compositions for making Zn-Group 13 mixed oxide materials including IZO, GZO, AZO and BZO, by providing inks comprising a molecular precursor compound having the formula M A a Zn(OROR) 3a+2 , and printing or depositing the inks on a substrate. The printed or deposited ink films can be treated to convert the molecular precursor compounds to a material.

  分子前体化合物、制备Zn-Group 13混合氧化物材料（包括IZO、GZO、AZO和BZO）的过程和组合物，方法是提供包含具有公式M的分子前体化合物的油墨，在基底上印刷或沉积这些油墨。印刷或沉积的油墨膜可以经处理转化为材料。
• Synthesis and Characterization of Group 13 and 15 Selenolates and Tellurolates and the x-ray Crystal Structures of Ga[TeSi(SiMe3)3]3, In[SeC(SiMe3)3]3, {In[SeSi(SiMe3)3]3}2(.mu.-DMPE), and P[SeSi(SiMe3)3]3
  作者：Stephen P. Wuller、Allen L. Seligson、Gregory P. Mitchell、John Arnold

  DOI：10.1021/ic00123a021

  日期：1995.9

  A broad range of chalcogenolate complexes of group 13 and 15 elements have been isolated and studied. Metathesis of AlEt(2)Cl with (THF)LiSeSi(SiMe(3))(3) gave (THF)AlEt(2)[SeSi(SiMe(3))(3)] in good yield. Chalcogenolysis of Al[N(SiMe(3))(2)](3) With 3 equiv of HESi(SiMe(3))(3) (E = Se, Te) afforded Al[ESi(SiMe(3))(3)](3) (E = Se, Te). Treatment of GaCl3 with 3 equiv of (THF)(2)LiTeSi(SiMe(3))3 produced the homoleptic species Ga[TeSi(SiMe(3))(3)](3); likewise, addition of 3 equiv of (DME)LiSeC(SiMe(3))(3) to InCl3 yielded In[SeC(SiMe(3))(3)](3). Reaction of InCl3 with 3 equiv of (THF)(2)-LiSeSi(SiMe(3))(3) produced (THF)In[SeSi(SiMe(3))(3)](3) in low yield. Homoleptic chalcogenolates, In[ESi(SiMe(3))(3)](3) (E = Se, Te) were prepared by chalcogenolysis of InCp(3) (Cp = eta(5)-C5H5). Addition of THF, pyridine, or TMEDA (N,N,N',N'-tetramethylethylenediamine) to In[SeSi(SiMe(3))(3)](3) gave 1:1 adducts, (L)In[SeSi(SiMe(3))(3)](3) (L = THF, pyridine, TMEDA). Addition of DMPE (1,2-bis(dimethylphosphino)ethane) to In[SeSi(SiMe(3))(3)](3), produced a 1:1 complex In[SeSi(SiMe(3))(3)](3)(DMPE) that was characterized in solution by NMR spectroscopy; attempts to isolate the complex yielded instead the crystalline 2:1 adduct In [SeSi(SiMe(3))(3)](3)}(2)(u-DMPE), whose X-ray structure was determined. Indium(I) complexes InESi(SiMe(3))3 (E = Se, Te) were isolated from either the metathesis of InCl with (THF)(2)LiESi(SiMe(3))3 or chalcogenolysis with InCp. Likewise, chalcogenolysis with TlCp produced TlESi(SiMe(3))3 (E = Se, Te). Reaction of PCl3 with (THF)(2)LiSeSi(SiMe(3))(3) produced P[SeSi(SiMe(3))(3)](3) in good yield. The arsenic derivative As[SeSi(SiMe(3))(3)](3) was isolated from the reaction of As(NMe(2))3 and 3 equiv of selenol. Similarly, the antimony and bismuth complexes M[ESi(SiMe(3))(3)](3) (M = Sbt E = Se, Te; M = Bi, E = Se, Te) were prepared in good yields by chalcogenolysis with Sb(NMe(2))3 or Bi[N(SiMe(3))(2)](3). Crystallographic data are as follows. Ga[TeSi(SiMe(3))(3)](3): monoclinic, P2(1)/c, Z = 4, a = 24.235(4) Angstrom, b = 13.808(3) Angstrom, c = 18.689(4) Angstrom, beta = 106.424(16)degrees, R = 0.0926, R(W) = 0.0731. In[SeC(SiMe(3))(3)](3): triclinic, P $($) over bar$$ l, Z = 2, a = 13.772(4) Angstrom, b = 13.778(4) Angstrom, c = 16.026(4) Angstrom, alpha = 74.25(2)degrees, beta = 75.27(2)degrees, gamma = 62.12(2)degrees, R = 0.0424, R(W) = 0.0476. In[SeSi(SiMe(3))(3)](3)}(2)(u-DMPE): triclinic, Pl $($) over bar$$, Z = 2, a = 13.655(3) Angstrom, b = 13.8323(20) Angstrom, c = 18.442(3) Angstrom, alpha = 97.874(13)degrees, beta = 104.066(16)degrees, gamma = 113.708(15)degrees, R = 0.0323, R(W) = 0.0332. P[SeSi(SiMe(3))(3)](3): monoclinic, P2(l)/c, Z = 6, a = 22.706(4) Angstrom, b = 13.959(5) Angstrom, c = 17.619(3) Angstrom, beta = 93.851(14)degrees, R = 0.0554, R(W) = 0.0463.
• Synthesis, Structure, and Spectroscopic Characterization of Unassociated Mono-, Di- and Triamido Derivatives of Aluminum and Gallium
  作者：Penelope J. Brothers、Rudolf J. Wehmschulte、Marilyn M. Olmstead、Karin Ruhlandt-Senge、Sean R. Parkin、Philip P. Power

  DOI：10.1021/om00019a040

  日期：1994.7

  As part of a study of the possible existence of pi-interactions in Al-N or Ga-N bonds, the synthesis and spectroscopic and structural characterization of several unassociated amido derivatives of aluminum and gallium are described. The compounds Mes*GaClN(H)Ph}.0.25 (hexane), 1, Mes*2GaN(H)Ph, 2, MesAlN(SiMe3)2}2, 3, Mes*Ga(NHPh)2, 4, and ClGaN(SiMe3)2}2,5 (Mes = 2,4,6-Me3C6H2, Mes* = 2,4,6-t-Bu3C6H2) were synthesized by simple salt elimination procedures and characterized by H-1 and C-13 NMR and X-ray crystallography. In addition, the X-ray crystal structures of the previously reported triamido compounds AlN(iPr)213,6, and GaN(SiMe3)2}3,7, are described. The Al-N and Ga-N distances in 1-7 fall within the narrow limits 1.790(4)-1.809(2) and 1.829(9)-1.874(4) angstrom, respectively, which are within the previously known range for bonds between three-coordinate nitrogen and three-coordinate aluminum or gallium. Dynamic behavior in the H-1 and C-13 NMR spectra of 2 and 3 was also observed, with a barrier near 11 kcal mol-1 being estimated in both molecules. The structural and dynamic NMR data suggest that any pi-interactions in the M-N bonds are rather weak and are of the order of 10 kcal mol-1. Crystal data at 130 K with Mo Kalpha (4, 6, 7, lambda = 0.710 73 angstrom) or Cu Kalpha (1-3, 5, lambda = 1.541 78 angstrom) radiation: (1) C25.5H38.5ClGaN, a = 9.421(2) angstrom, b = 14.413(2) angstrom, c = 18.967(3) angstrom, alpha = 87.88(2)degrees, beta = 79.22(2)degrees, gamma = 80.66(2)degrees, triclinic, space group P1BAR, Z = 4, R = 0.083 for 3867 (I > 3sigma(I)) reflections; (2) C42H64GaN, a = 9.945(2) angstrom, b = 11.245(2) angstrom, c = 17.825(2) angstrom, alpha = 87.28(2)degrees, beta = 85.73(2)degrees, gamma = 79.25(2)degrees, space group P1BAR, Z = 2, R = 0.054 for 4155 (I > 2osigma(I)) reflections; (3) C21H47AlN2Si4, a = 13.403(3) angstrom, b = 16.651(2) angstrom, c = 26.061(5) angstrom, beta = 91.46(2)degrees, monoclinic, space group C2/c, Z = 8, R = 0.035 for 2992 (I > 2sigma(I)) reflections; (4) C30H30GaN2, a = 20.346(4) angstrom, b = 11.696(3) angstrom, c = 13.565(3) A, beta = 123.17(2)degrees, monoclinic, space group C2/c, Z = 4, R = 0.066 for 1707 (I > 3sigma(I)) reflections; (5) C12H36ClGaN2Si4, a = 11.657(3) angstrom, b = 12.677(2) angstrom, c = 15.831(3) angstrom, orthorhombic, space group P2(1)2(1)2(1), Z = 4, R = 0.040 for 2577 (I > 3sigma(I)) reflections; (6) C18H42AlN3, a = 7.803(6) angstrom, b = 16.590(12) angstrom, c = 17.397(14) angstrom, alpha = 102.68(5), beta = 90.67(5)degrees, gamma = 96.67(5)degrees, triclinic, space group P1BAR, Z = 4, R = 0.071 for 4311 (I > 2simga(I)) data; (7) C18H54GaN3Si6, a = 16.008(3) angstrom, c = 8.444(2) angstrom, trigonal, space group P31cBAR, Z = 2, R = 0.059 for 718 (I > 3sigma(I)) reflections.
• Paciorek; Nakahara; Masuda, Inorganic Chemistry, 1990, vol. 29, # 21, p. 4252 - 4255
  作者：Paciorek、Nakahara、Masuda

  DOI：——

  日期：——
• Synthesis and structural characterization of two five coordinate aluminum alkyl and bis(trimethylsilyl)amino complexes bearing acyclic tetradentate Schiff bases
  作者：C.R. Wade、B.J. Lamprecht、V.W. Day、J.A. Belot

  DOI：10.1016/j.poly.2007.03.008

  日期：2007.8

  acyclic Schiff-base ligands, bis-5,5′-(1,3-propanediyldiimino)-2,2-dimethyl-4-hexene-3-one and bis-5,5′-(1,3-ethanediyldiimino)-2,2-dimethyl-4-hexene-3-one, were used to complex homoleptic triethylaluminum and tris[bis(trimethylsilyl)amino]aluminum, respectively. The acid–base reactions proceeded in excellent yields with elimination of ethane or bis(trimethylsilyl)amine during in situ deprotonation of

  摘要两个无环席夫碱配体bis-5,5'-（1,3-丙二基二亚氨基）-2,2-二甲基-4-己烯-3-一和bis-5,5'-（1,3-乙二基二亚氨基） ）-2，2-二甲基-4-己烯-3-酮分别用于络合均均三乙基铝和三[双（三（甲基硅烷基）氨基]铝。酸碱反应以优异的收率进行，在原质Schiff碱原位去质子化过程中消除了乙烷或双（三甲基甲硅烷基）胺。由正戊烷结晶的无色铝络合物，通过包括单晶X射线衍射在内的标准方法进行表征。外消旋丙交酯的聚合反应，再加上醇，得到的聚乳酸具有较窄的多分散性，但分子量较低。