phenyl 2-(benzoyloxy)benzoate | 88815-27-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: phenyl 2-(benzoyloxy)benzoate
• 英文别名: 2-benzoyloxy-benzoic acid phenyl ester；2-Benzoyloxy-benzoesaeure-phenylester；Benzoyl-salicylsaeure-phenylester；Benzoylsalol；Phenyl 2-benzoyloxybenzoate
• CAS: 88815-27-4
• 化学式: C₂₀H₁₄O₄
• 分子量: 318.329
• InChiKey: LIDDQKAMUXHIQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  phenyl 2-(benzoyloxy)benzoate 、 邻甲苯胺 生成 2-benzoyloxy-benzoic acid o-toluidide
  参考文献：
  名称：

  ‘Prodigious Riches’: The Wealth of Jamaica Before the American Revolution

  摘要：

  This article determines new estimates for the wealth of Jamaica in 1774. These revisions push up previous calculations by between one-half and two-thirds and demonstrate that Jamaica was the wealthiest colony in British America, both in terms of total wealth and in regard to the wealth of individual colonists. These revised estimates also reinforce the extent to which wealth in the Americas was established on the backs of black slaves. The re-evaluation of Jamaican wealth demonstrates how valuable the West Indies were within the empire and suggests that the customary regional classifications of British American colonies need to be rethought.

  DOI：

  10.1111/1468-0289.00201
• 作为产物：
  描述：

  水杨酸苯酯 、 苯甲醇 在 叔丁基过氧化氢 、 copper diacetate 作用下， 以 水 、 二甲基亚砜 为溶剂， 反应 20.0h， 以46%的产率得到phenyl 2-(benzoyloxy)benzoate
  参考文献：
  名称：

  Cu(II)-catalyzed oxidative esterification of 2-carbonyl substituted phenols from the alcohol oxidation level

  摘要：

  A copper-catalyzed oxidative esterification of 2-carbonyl substituted phenols from the alcohol oxidation level is described. This protocol represents direct access to a range of 2-carbonylated aryl benzoate derivatives, which are important building blocks in the synthesis of natural and pharmacological compounds. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.08.079

文献信息

• Purgotti; Monti, Gazzetta Chimica Italiana, 1904, vol. 34 I, p. 271
  作者：Purgotti、Monti

  DOI：——

  日期：——
• DERIVATIVES OF AROMATIC BENZOATES AS INHIBITORS OF ESTERASE-PRODUCING MICRO-ORGANISMS
  申请人：ROBERTET S.A.

  公开号：EP0606197A1

  公开（公告）日：1994-07-20
• USE OF AROMATIC BENZOATES AS PERSONAL DEODORANTS
  申请人：ROBERTET S.A.

  公开号：EP0606197B1

  公开（公告）日：1996-01-31
• JPS5624481A
  申请人：——

  公开号：JPS5624481A

  公开（公告）日：1981-03-09
• Process For Preparation Of Optical Compensatory Sheet
  申请人：Nishikawa Naoyuki

  公开号：US20080171143A1

  公开（公告）日：2008-07-17

  A process for preparation of an optical compensatory sheet is disclosed. The process comprises the steps in order of: coating a support with a photosensitive compound; exposing the photosensitive compound to beams of linearly polarized light emitted from a semiconductor laser to form an orientation layer; coating the orientation layer with a liquid crystal composition containing polymerizable liquid crystal molecules; aligning the liquid crystal molecules to form an optically anisotropic layer; and then polymerizing the liquid crystal molecules to fix alignment.