Reaction of anionic and cationic silicon clusters with tungsten hexafluoride studied by fourier transform ion cyclotron resonance mass spectrometry
作者:W.D. Reents、M.L. Mandich、V.E. Bondybey
DOI:10.1016/0009-2614(86)80507-3
日期:1986.10
Anionic and cationic silicon clusters react exothermically with WF6 to give a variety of tungsten and silicon fluorides. All the silicon anionic clusters transfer their charge to WF6. The electron affinities of Si2–6 are estimated to be less than the electron affinity of WF6 (350 kJmole (3.6 eV)).
阴离子和阳离子硅团簇与WF 6放热反应,得到各种钨和氟化硅。所有的硅阴离子簇将其电荷转移至WF 6。据估计,Si 2-6的电子亲和力小于WF 6的电子亲和力(350 kJmole(3.6 eV))。