bis(1-piperidinylthiocarbonyl)sulfide | 725-32-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: bis(1-piperidinylthiocarbonyl)sulfide
• 英文别名: dipentamethylenethiuram monosulphide；dipentamethylene thiuram monosulfide；Dicyclopentamethylenthiurammonosulfid；N,N,N',N'-Bis(pentamethylen)thiurainsulfid；bis-(piperidine-1-carbothioic acid )-thioanhydride；piperidine-1-dithiocarboxylic acid, anhydrosulfide；Bis-(piperidin-1-thiocarbonsaeure)-thioanhydrid；bis(N,N-pentamethylene thiocarbamoyl) sulphide；Thio-bis-N,N-(thiocarbonylpiperidin)；Piperidine-1-dithiocarboxylic acid, anhydrosulphide；piperidine-1-carbothioyl piperidine-1-carbodithioate
• CAS: 725-32-6
• 化学式: C₁₂H₂₀N₂S₃
• 分子量: 288.502
• InChiKey: PFOWLPUJPOQMAL-UHFFFAOYSA-N

物化性质

• 熔点：
  110 °C
• 沸点：
  397.7±25.0 °C(Predicted)
• 密度：
  1.278±0.06 g/cm3(Predicted)
• 溶解度：
  DMSO: 50mg/mL

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  96
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bis(1-piperidinylthiocarbonyl)sulfide 、 p-tolylsulfonyl isothiocyanate 生成 bis-(piperidine-1-thiocarbonyl)-(toluene-4-sulfonyl)-amine
  参考文献：
  名称：

  DE859150

  摘要：

  公开号：
• 作为产物：
  描述：

  二环戊亚甲基二硫化四烷基秋兰姆 在 potassium cyanide 作用下， 以 水 为溶剂， 反应 5.0h， 生成 bis(1-piperidinylthiocarbonyl)sulfide
  参考文献：
  名称：

  D'Amico, John J.; Bollinger, Frederic G.; Tung, Ching C., Journal of Heterocyclic Chemistry, 1987, vol. 24, p. 945 - 948

  摘要：

  DOI：

文献信息

• FUNCTIONAL REINFORCING FILLERS MODIFIED WITH ALKENYLALKOXYSILANE AND PREPARING METHOD OF THE SAME
  申请人：KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20140102332A1

  公开（公告）日：2014-04-17

  Disclosed are a functional reinforcing filler including inorganic particles surface-modified with an alkenylsilanol obtained by hydrolyzing an alkenylalkoxysilane compound, and a method for preparing the same. Since the disclosed functional reinforcing filler has a functional group having a double bond, it has good reactivity for styrene-butadiene rubber and sulfur. Thus, when used as a functional reinforcing filler in the manufacture of rubber, it allows improvement of physical properties through adjustment of the addition amount of sulfur without additional use of the coupling agent. In addition, because of superior hydrolysis reactivity, the problem of alcohol can be solved and a rubber mixture with long scorch time can be prepared. In particular, when the functional reinforcing filler of the present invention is used in the manufacture of tires, improvement in modulus, tensile strength, rotational resistance and wet traction performance can be expected.

  本发明公开了一种功能性增强填料，其中包括经过烯基硅醇表面修饰的无机颗粒，该烯基硅醇是通过水解烯基烷氧基硅烷化合物得到的，并且公开了其制备方法。由于所公开的功能性增强填料具有具有双键的功能性基团，因此对于苯乙烯-丁二烯橡胶和硫具有良好的反应性。因此，在橡胶制造中使用作为功能性增强填料时，可以通过调整硫的添加量来改善物理性能，而无需额外使用偶联剂。此外，由于其优异的水解反应性，可以解决醇的问题，并制备具有长烧伤时间的橡胶混合物。特别是，当本发明的功能性增强填料用于轮胎制造时，可以预期提高模量、拉伸强度、旋转阻力和湿地牵引性能。
• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• Process for the production of graft copolymers of polyphenylene oxides
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0017751A1

  公开（公告）日：1980-10-29

  A process for producing a graft copolymer characterized by melt-blending 100 parts by weight of a resin mixture comprising 90 to 10% by weight of a polyphenylene oxide having a structurel unit of (wherein R1, R2, R3 and R4 each represents hydrogen, a halogen atom, a hydrocarbon or substituted hydrocarbon radical) and 10 to 90% by weight of a styrene polymer and/ or a copolymer of a styrene and other monomers in the presence of 0.01 to 5 parts by weight of a sulfurcontaining grafting agent selected from the group consisting of sulfur, sulfur halogenides, sulfides, thiols and thiophenols.

  一种生产接枝共聚物的工艺，其特征是将 100 重量份的树脂混合物熔融混合，该混合物包括 90 至 10%（重量份）的聚苯醚，其结构单元为 (其中 R1、R2、R3 和 R4 各自代表氢、卤素原子、烃或取代的烃基)和 10 至 90% (重量)苯乙烯聚合物和/或苯乙烯与其他单体的共聚物，在 0.01 至 5 份 (重量)从硫、硫卤化物、硫化物、硫醇和噻吩醇组成的组中选出的含硫接枝剂存在下进行。
• Vulcanized olefin-based rubber composition
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0103695A1

  公开（公告）日：1984-03-28

  A vulcanized olefin-based rubber composition is disclosed which is produced by vulcanizing an olefin-based rubber composition with a sulfur-containing substance alone or with a sulfur-containing substance and a vulcanization accelerator in combination. The olefin-based rubber composition is composed of (A) olefin-based rubber composed mainly of ethylene and propylene and (B) aluminium or an aluminium alloy in the form of powder, fiber, or flake, or being composed of (A) olefin-based rubber composed mainly of ethylene and propylene, (B) aluminium or an aluminium alloy in the form of powder, fiber, orflake, and (C) electrically-conductive carbon black, and said sulfur-containing substance being selected from the group consisting of a sulfur-based vulcanizing agent and a sulfur-releasing agent. The composition of this invention is superior in the shielding of electromagnetic waves.

  本发明公开了一种硫化烯烃基橡胶组合物，它是通过将烯烃基橡胶组合物单独与含硫物质或与含硫物质和硫化促进剂混合硫化而制成的。烯烃基橡胶组合物由(A)主要由乙烯和丙烯组成的烯烃基橡胶和(B)粉末、纤维或薄片形式的铝或铝合金组成，或由(A)主要由乙烯和丙烯组成的烯烃基橡胶组成、(B) 粉末、纤维或薄片形式的铝或铝合金，以及 (C) 导电炭黑，所述含硫物质选自硫基硫化剂和脱硫剂组成的组。 本发明的组合物在屏蔽电磁波方面性能优越。
• Scintillation converter for neutron radiography
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0150863A2

  公开（公告）日：1985-08-07

  A scintillation converter for neutron radiography is described, comprising a composition formed of components (A) 100 parts by weight of an olefin rubber made mainly of ethylene and propylene, (B) from 100 to 400 parts by weight of at least one inorganic compound selected from the group consisting of inorganic boron compounds and inorganic lithium compounds, and (C) from 100 to 600 parts by weight of a zinc sulfide-base fluorescent material. This scintillation converter is not only superior in radiation-sensitive performance, but also has high elasticity and superior abrasion resistance.

  描述了一种用于中子射线照相术的闪烁转换器，它由以下成分组成：(A) 100 份（按重量计）主要由乙烯和丙烯制成的烯烃橡胶，(B) 100 至 400 份（按重量计）至少一种无机化合物，这些无机化合物选自无机硼化合物和无机锂化合物组成的组，以及 (C) 100 至 600 份（按重量计）硫化锌基荧光材料。这种闪烁转换器不仅辐射敏感性能优越，而且具有高弹性和出色的耐磨性。