5,5-Bis(2-methylpropyl)-1,3-dioxan-2-one

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: 5,5-Bis(2-methylpropyl)-1,3-dioxan-2-one
• 英文别名: 5,5-bis(2-methylpropyl)-1,3-dioxan-2-one
• 化学式: C₁₂H₂₂O₃
• 分子量: 214.3
• InChiKey: KNYAUJPUABIQJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• AROMATIC POLYCARBONATE RESIN COMPOSITION
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2921516A1

  公开（公告）日：2015-09-23

  The present invention provides an aromatic polycarbonate resin composition having a high molecular weight and less amount of a heterologous structure, retaining good qualities, and excellent in thermal stability, and an improved preparation process thereof.

  本发明提供了一种芳香族聚碳酸酯树脂组合物，其分子量高，异源结构含量少，质量好，热稳定性优异，并改进了其制备工艺。
• PRODUCTION METHOD FOR AROMATIC POLYCARBONATE RESIN HAVING INCREASED MOLECULAR WEIGHT
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2921515A1

  公开（公告）日：2015-09-23

  The invention provides a process for producing a highly polymerized aromatic polycarbonate resin including a molecular weight-increasing step of reacting an aromatic polycarbonate prepolymer with an aliphatic diol compound represented by Formula (g2) in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin. In the formula, Ra and Rb each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group, a cycloalkyl group, an aryl group or an alkoxy group, or Ra and Rb may be bonded to each other to form a ring; R1 to R4 each independently represent a hydrogen atom, a halogen atom or an alkyl group; and n represents an integer of 0 to 30.

  本发明提供了一种生产高度聚合的芳香族聚碳酸酯树脂的工艺，包括一个增加分子量的步骤，即在酯交换催化剂存在下，芳香族聚碳酸酯预聚物与由式（g2）表示的脂肪族二元醇化合物反应，得到高度聚合的芳香族聚碳酸酯树脂。式中，Ra 和 Rb 各自独立地代表氢原子、卤素原子、直链或支链烷基、环烷基、芳基或烷氧基，或 Ra 和 Rb 可相互键合形成环；R1 至 R4 各自独立地代表氢原子、卤素原子或烷基；n 代表 0 至 30 的整数。
• MANUFACTURING METHOD FOR HIGH MOLECULAR WEIGHT AROMATIC POLYCARBONATE RESIN
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3438152A1

  公开（公告）日：2019-02-06

  Provided is a manufacturing method for a high molecular weight aromatic polycarbonate resin that has superior fluidity and for which a good color and a sufficiently high molecular weight can be achieved. A manufacturing method for a high molecular weight aromatic polycarbonate resin, said manufacturing method including: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is kept in a molten state, and is mixed with an aromatic polycarbonate prepolymer within ten hours after obtaining the catalyst composition, to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin. In formula (1), R1-R4 each independently represent a hydrogen atom, a halogen atom, or a C1-5 straight-chain or branched-chain alkyl group. Q represents a single bond or a divalent radical that may contain a substituent group and is formed from at least one component selected from the group consisting of an aliphatic hydrocarbon group, an aromatic hydrocarbon group, an oxygen atom, a sulfur atom, a sulfone group, a sulfoxide group, a carbonyl group, a dialkylsilyl group, and a diarylsilyl group.

  本发明提供了一种高分子量芳香族聚碳酸酯树脂的制造方法，该树脂具有优异的流动性，并能获得良好的颜色和足够高的分子量。一种高分子量芳香族聚碳酸酯树脂的制造方法，所述制造方法包括：将通式（1）表示的二醇类化合物与催化剂混合以获得催化剂组合物的步骤；将获得的催化剂组合物保持在熔融状态，并在获得催化剂组合物后十小时内与芳香族聚碳酸酯预聚物混合以获得预聚物混合物的步骤；以及将获得的预聚物混合物在减压条件下进行热处理以获得高分子量芳香族聚碳酸酯树脂的高分子量实现步骤。在式 (1) 中，R1-R4 各自独立地代表氢原子、卤素原子或 C1-5 直链或支链烷基。Q 代表单键或可包含取代基的二价基，该二价基至少由一种组分形成，这些组分选自脂族烃基、芳香族烃基、氧原子、硫原子、砜基、亚砜基、羰基、二烷基硅烷基和二元硅烷基组成的组。
• High molecular weight aromatic polycarbonate resin manufacturing method
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10894860B2

  公开（公告）日：2021-01-19

  A high molecular weight aromatic polycarbonate resin manufacturing method that can achieve good quality and sufficiently high molecular weight includes: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is transferred to a prepolymer mixing tank via a transfer pipe; a step in which the transferred catalyst composition and an aromatic polycarbonate prepolymer are mixed in the prepolymer mixing tank, under a pressure that is greater than or equal to the vapor pressure of the dialcohol compound at the temperature of the prepolymer mixing tank and is less than or equal to 5 MPa, to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin.

  一种可获得良好质量和足够高分子量的高分子量芳香族聚碳酸酯树脂的制造方法包括将通式(1)表示的二羟基化合物和催化剂混合以获得催化剂组合物的步骤； 通过输送管将获得的催化剂组合物输送到预聚物混合罐的步骤；在预聚物混合罐中，在大于或等于二元醇化合物在预聚物混合罐温度下的蒸气压且小于或等于 5 兆帕的压力下，将转移的催化剂组合物和芳香族聚碳酸酯预聚物混合，以获得预聚物混合物的步骤；以及 在减压条件下，对获得的预聚物混合物进行热处理，以获得高分子量芳香族聚碳酸酯树脂的高分子量实现步骤。
• Manufacturing method for high molecular weight aromatic polycarbonate resin
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10927216B2

  公开（公告）日：2021-02-23

  Provided is a high molecular weight aromatic polycarbonate resin manufacturing method that suppresses the occurrence of heterogeneous structures and can achieve a sufficiently high molecular weight. A high molecular weight aromatic polycarbonate resin manufacturing method including: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is transferred to a prepolymer mixing tank via a transfer pipe, with a transfer period of 10 hours or less; a step in which the transferred catalyst composition and an aromatic polycarbonate prepolymer are mixed in the prepolymer mixing tank to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin.

  本发明提供了一种高分子量芳香族聚碳酸酯树脂制造方法，该方法可抑制异质结构的出现，并可获得足够高的分子量。一种高分子量芳香族聚碳酸酯树脂制造方法，包括将通式（1）表示的二羟基化合物和催化剂混合以获得催化剂组合物的步骤； 通过输送管将获得的催化剂组合物输送到预聚物混合罐的步骤，输送时间不超过 10 小时；将转移的催化剂组合物和芳香族聚碳酸酯预聚物在预聚物混合罐中混合以获得预聚物混合物的步骤；以及将获得的预聚物混合物在减压条件下进行热处理以获得高分子量芳香族聚碳酸酯树脂的高分子量实现步骤。