1-Methyl-2-thio-benzindolin | 58514-62-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-Methyl-2-thio-benzindolin
• 英文别名: 1-Methylbenzindolin-2-thion；1-Methylbenz[cd]indole-2(1H)-thione；1-methyl-1H-benz[cd]indole-2-thione；1-Methyl-1H-benz[cd]indol-2-thion；1-methylbenzo[cd]indole-2(1H)-thione；1-methylbenzo[cd]indole-2-thione
• CAS: 58514-62-8
• 化学式: C₁₂H₉NS
• 分子量: 199.276
• InChiKey: YVWPVXGKDXTJJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  35.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-Methyl-2-thio-benzindolin 在 mercury(II) diacetate 盐酸 、 sodium hydroxide 、 正丁胺 作用下， 以 1,4-二氧六环 、 5-羟基-2-戊酮 、 水 为溶剂， 生成 2-(n-Butylimino)-1-methyl-1,2-dihydrobenz[cd]indole hydrochloride
  参考文献：
  名称：

  1-Substituted-2-(substituted-imino)-1H-1,2-dihydrobenz[cd]indoles

  摘要：

  Novel 1-取代-2-(取代亚胺基)-1H-1,2-二氢苯[cd]吲哚可用作抑制血小板聚集的抑制剂。

  公开号：

  US04261896A1
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 phosphorous (V) sulfide 、 xylene 作用下， 生成 1-Methyl-2-thio-benzindolin
  参考文献：
  名称：

  Dokunichin; Gaewa, Zhurnal Obshchei Khimii, 1958, vol. 28, p. 2670;engl.Ausg.S.2698

  摘要：

  DOI：

文献信息

• OPTICAL FILTER
  申请人：Mae Yukiko

  公开号：US20110152538A1

  公开（公告）日：2011-06-23

  An optical filter containing at least one naphtholactam derivative represented by general formula (I), wherein X is oxygen or sulfur; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and Y are each hydrogen, halogen, nitro, cyano, aldehyde, carboxyl, hydroxyl, —NRR′, organosilyl, optionally substituted C1-C30 alkyl, optionally substituted C6-C30 aryl, or optionally substituted C7-C30 arylalkyl; and R and R′ are each hydrogen, optionally substituted C1-C30 alkyl, or optionally substituted C6-C30 aryl.

  一个包含至少一种由通式（I）表示的萘内酰胺衍生物的光学滤光片，其中X是氧或硫；R1、R2、R3、R4、R5、R6和Y分别是氢、卤素、硝基、氰基、醛基、羧基、羟基、—NRR′、有机硅基、可选地取代的C1-C30烷基、可选地取代的C6-C30芳基或可选地取代的C7-C30芳基烷基；R和R′分别是氢、可选地取代的C1-C30烷基或可选地取代的C6-C30芳基。
• POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, POLARIZED LIGHT-EMITTING COATING MATERIAL, NOVEL NAPHTHOLACTAM DERIVATIVE NOVEL COUMARIN DERIVATIVE, NOVEL NILE RED DERIVATIVE, AND NOVEL ANTHRACENE DERIVATIVE
  申请人：Kubota Yusuke

  公开号：US20130334461A1

  公开（公告）日：2013-12-19

  Provided are a polymerizable liquid crystal composition, a coating material, a medium, and a polarizing device each produced using a polymerizable liquid crystal compound and a colorant and each capable of producing polarized light suitable for polarizing devices, and also a novel naphtholactam derivative, a novel coumarin derivative, a novel Nile Red derivative, and a novel anthracene derivative each suitable for use as the colorant. Specifically provided are a polymerizable liquid crystal composition containing (A) at least one liquid crystal compound having a polymerizable functional group, (B) at least one colorant, and (C) a polymerization initiator, and a novel naphtholactam derivative of formula (IV′), a novel coumarin derivative of formula (VI′), a novel Nile Red derivative of formula (VII′), and a novel anthracene derivative of formula (VIII′) each suitable for use as the colorant (B).

  提供了一种可聚合的液晶组合物、涂料材料、介质和极化装置，每种都使用了聚合液晶化合物和颜料，并且能够产生适合于极化装置的偏振光，还提供了一种新型萘内酰胺衍生物、一种新型香豆素衍生物、一种新型尼罗红衍生物和一种新型蒽衍生物，每种都适用于用作颜料。具体提供了一种聚合液晶组合物，包含（A）至少一种具有聚合功能基团的液晶化合物，（B）至少一种颜料，和（C）聚合引发剂，以及一种适用于用作颜料（B）的新型萘内酰胺衍生物（IV′）, 一种新型香豆素衍生物（VI′）, 一种新型尼罗红衍生物（VII′）和一种新型蒽衍生物（VIII′）。
• POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, POLARIZED LIGHT-EMITTING COATING MATERIAL, NOVEL NAPHTHOLACTAM DERIVATIVE, NOVEL COUMARIN DERIVATIVE, NOVEL NILE RED DERIVATIVE, AND NOVEL ANTHRACENE DERIVATIVE
  申请人：Adeka Corporation

  公开号：EP2695930A1

  公开（公告）日：2014-02-12

  Provided are a polymerizable liquid crystal composition, a coating material, a medium, and a polarizing device each produced using a Polymerizable liquid crystal compound and a colorant and each capable of producing polarized light suitable for polarizing devices, and also a novel naphtholactam derivative, a novel coumarin derivative, a novel Nile Red derivative, and a novel anthracene derivative each suitable for use as the colorant. Specifically provided are a polymerizable liquid crystal composition containing (A) at least one liquid crystal compound having a polymerizable functional group, (B) at least one colorant, and (C) a polymerization initiator, and a novel naphtholactam derivative of formula (IV'), a novel coumarin derivative of formula (VI'), a novel Nile Red derivative of formula (VII'), and a novel anthracene derivative of formula (VIII') each suitable for use as the colorant (B).

  本发明提供了一种可聚合液晶组合物、一种涂层材料、一种介质和一种偏振装置，每种组合物都使用一种可聚合液晶化合物和一种着色剂生产，并且每种组合物都能够产生适用于偏振装置的偏振光，还提供了一种新型萘内酰胺衍生物、一种新型香豆素衍生物、一种新型尼罗河红衍生物和一种新型蒽衍生物，每种衍生物都适用于用作着色剂。具体提供了一种可聚合液晶组合物，该组合物包含（A）至少一种具有可聚合官能团的液晶化合物、（B）至少一种着色剂和（C）一种聚合引发剂，以及适合用作着色剂（B）的式（IV'）的新型萘内酰胺衍生物、式（VI'）的新型香豆素衍生物、式（VII'）的新型尼罗红衍生物和式（VIII'）的新型蒽衍生物。
• Dokunichin et al., Zhurnal Obshchei Khimii, 1959, vol. 29, p. 2742,2744;engl.Ausg.S.2709
  作者：Dokunichin et al.

  DOI：——

  日期：——
• JPH10204060A
  申请人：——

  公开号：JPH10204060A

  公开（公告）日：1998-08-04