4-(chlorodimethylsilyl)-2-methylbutan-2-yl 2-bromo-2-methylpropanoate | 1224964-93-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 4-(chlorodimethylsilyl)-2-methylbutan-2-yl 2-bromo-2-methylpropanoate
• 英文别名: [4-[Chloro(dimethyl)silyl]-2-methylbutan-2-yl] 2-bromo-2-methylpropanoate；[4-[chloro(dimethyl)silyl]-2-methylbutan-2-yl] 2-bromo-2-methylpropanoate
• CAS: 1224964-93-5
• 化学式: C₁₁H₂₂BrClO₂Si
• 分子量: 329.737
• InChiKey: YLIFACJYQWPFOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.32
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二甲基一氯硅烷 、 2-methylpent-4-en-2-yl 2-bromo-2-methylpropanoate 在 hydrogen-hexachloroplatinate(IV) hexahydrate 作用下， 以96.4%的产率得到4-(chlorodimethylsilyl)-2-methylbutan-2-yl 2-bromo-2-methylpropanoate
  参考文献：
  名称：

  Patterning of a Surface Immobilized ATRP Initiator with an Inkjet Printer

  摘要：

  A new technique for patterning polymer brushes on the micrometer scale has been developed in which an inkjet printer was used to deposit droplets of acid on a surface-immobilized initiator for atom transfer radical polymerization (ATRP). The acid cleaved an ester bond in the ATRP initiator in a saponification reaction. As a result. the ATRP initiator was rendered inactive. To control the degree of defunctionalization, a new initiator containing a weak ester bond was derived from a tertiary alcohol. Comparison to an established ATRP initiator, derived from a primary alcohol, showed that the novel initiator was defunctionalized with a higher efficiency. Control of the reaction time allowed to partially defunctionalize the initiator molecules, leading to control of grafting densities within the written patterns.

  DOI：

  10.1021/ma902836n

文献信息

• Patterning of a Surface Immobilized ATRP Initiator with an Inkjet Printer
  作者：Sebastian G. J. Emmerling、Laura B. N. Langer、Sascha A. Pihan、Philipp Lellig、Jochen S. Gutmann

  DOI：10.1021/ma902836n

  日期：2010.6.8

  A new technique for patterning polymer brushes on the micrometer scale has been developed in which an inkjet printer was used to deposit droplets of acid on a surface-immobilized initiator for atom transfer radical polymerization (ATRP). The acid cleaved an ester bond in the ATRP initiator in a saponification reaction. As a result. the ATRP initiator was rendered inactive. To control the degree of defunctionalization, a new initiator containing a weak ester bond was derived from a tertiary alcohol. Comparison to an established ATRP initiator, derived from a primary alcohol, showed that the novel initiator was defunctionalized with a higher efficiency. Control of the reaction time allowed to partially defunctionalize the initiator molecules, leading to control of grafting densities within the written patterns.