3-methylbenzonaphtho<2,3-d>thiophene | 83656-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-methylbenzonaphtho<2,3-d>thiophene
• 英文别名: Benzo(b)naphtho(2,3-d)thiophene, 3-methyl-；3-methylnaphtho[2,3-b][1]benzothiole
• CAS: 83656-86-4
• 化学式: C₁₇H₁₂S
• 分子量: 248.348
• InChiKey: ADVOIMLBBCTUOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-bromo-2-decalone 、 3-甲基苯硫酚 以10%的产率得到
  参考文献：
  名称：

  PRATAP, RAM;TOMINAGA, YOSHINORI;CASTLE, R. N.;LEE, M. L., J. HETEROCYCL. CHEM., 1982, 19, N 4, 865-869

  摘要：

  DOI：

文献信息

• AMINOANTHRACENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT FORMED USING SAME
  申请人：Mizutani Sayaka

  公开号：US20120299473A1

  公开（公告）日：2012-11-29

  There are provided an aminoanthracene derivative having an end substituent, such as a dibenzofuran ring, that is bonded at a position other than the 2-position in the formula (1) to anthracene through a nitrogen atom, and an organic electroluminescent device containing a cathode and an anode, and therebetween one or plural organic thin film layers containing at least a light emitting layer, at least one layer of the organic thin film layers containing the aminoanthracene derivative. The organic electroluminescent device has a long lifetime and a high luminous efficiency. (In the formula, R 1 , m and Ar 1 to Ar 4 have the meanings described in claim 1 .)

  提供了一种氨基蒽衍生物，具有末端取代基，例如通过氮原子与蒽结合在公式（1）中的2-位置以外的位置的二苯并呋喃环，并且含有阴极和阳极的有机电致发光器件，以及在其中的至少一个或多个含有至少一个发光层的有机薄膜层，有机薄膜层中的至少一层含有氨基蒽衍生物。有机电致发光器件具有长寿命和高发光效率。（在公式中，R1、m和Ar1到Ar4具有权利要求1中描述的含义。）
• [EN] NEW SUBSTITUTED BENZONAPHTHATHIOPHENE COMPOUNDS FOR ORGANIC ELECTRONICS<br/>[FR] NOUVEAUX COMPOSÉS BENZONAPHTATHIOPHÈNES SUBSTITUÉS POUR ÉLÉMENTS ÉLECTRONIQUES ORGANIQUES
  申请人：BASF SE

  公开号：WO2019076709A1

  公开（公告）日：2019-04-25

  The present invention provides compounds of formulae (1) (2) wherein R1and R2are C1-30alkyl, C2-3O-alkenyl, C2-30-alkynyl, C5-7-cycloalkyl, C6-14-aryl or 5 to 14 membered heteroaryl, wherein C1-30-alkyl, C2-3O-alkenyl and C2-3O-alkynyl can be substituted with one or more substituents selected from the group consisting of halogen, phenyl, O-C1-20-alkyl, O-C2-20-alkenyl and O- C2-2O-alkynyl, and wherein C5-7-cycloalkyl, C6-14-aryl and 5 to 14 membered heteroaryl can be substituted with one or more substituents selected from the group consisting of halogen, C1-20alkyl, C2-2O-alkenyl, C2-2O-alkynyl, O-C1-20-alkyl, O-C2-2o-alkenyl and O-C2-2o-alkynyl, Ra, Rb, Rcand Rdare independently and at each occurrence selected from the group consisting of C1-30alkyl, C2-30-alkenyl, C2-30-alkynyl, C6-14-aryl and 5 to 14 membered heteroaryl, wherein C1-30-alkyl, C2-3o-alkenyl and C2-3o-alkynyl can be substituted with one or more substituents selected from the group consisting of halogen, phenyl, O-C1-20-alkyl, O-C2-20-alkenyl and O- C2-20-alkynyl, and wherein C5-7-cycloalkyl, C6-14-aryl and 5 to 14 membered heteroaryl can be substituted with one or more substituents selected from the group consisting of halogen, C1-20alkyl, C2-2o-alkenyl, C2-20-alkynyl, O-C1-20-alkyl, O-C2-20-alkenyl and O-C2-2o-alkynyl, n and o are independently 0, 1, 2, 3, 4 or 5, and m and p are independently 0, 1, 2 or 3, and to electronic device comprising the compounds of formulae 1 or 2.

  本发明提供了公式（1）（2）的化合物，其中R1和R2为C1-30烷基，C2-3O-烯基，C2-30炔基，C5-7环烷基，C6-14芳基或5至14个成员的杂芳基，其中C1-30烷基，C2-3O-烯基和C2-3O-炔基可以被选自卤素，苯基，O-C1-20-烷基，O-C2-20-烯基和O-C2-2O-炔基的一种或多种取代基所取代，而C5-7环烷基，C6-14芳基和5至14个成员的杂芳基可以被选自卤素，C1-20烷基，C2-2O-烯基，C2-2O-炔基，O-C1-20-烷基，O-C2-2O-烯基和O-C2-2O-炔基的一种或多种取代基所取代，Ra，Rb，Rc和Rd分别独立地在每次出现时从C1-30烷基，C2-30-烯基，C2-30-炔基，C6-14芳基和5至14个成员的杂芳基中选取，其中C1-30烷基，C2-3O-烯基和C2-3O-炔基可以被选自卤素，苯基，O-C1-20-烷基，O-C2-20-烯基和O- C2-20-炔基的一种或多种取代基所取代，而C5-7环烷基，C6-14芳基和5至14个成员的杂芳基可以被选自卤素，C1-20烷基，C2-2O-烯基，C2-20-炔基，O-C1-20-烷基，O-C2-20-烯基和O-C2-2o-炔基的一种或多种取代基所取代，n和o分别独立地为0、1、2、3、4或5，而m和p分别独立地为0、1、2或3，并且包括公式1或2的化合物的电子设备。
• Organic Compound, Light-Emitting Device, Light-Emitting Apparatus, Electronic Device, Display Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20210139445A1

  公开（公告）日：2021-05-13

  A novel organic compound is provided. Alternatively, an organic compound that exhibits light emission with favorable chromaticity is provided. Alternatively, an organic compound that exhibits blue light emission with favorable chromaticity is provided. Alternatively, a light-emitting device with favorable emission efficiency is provided. Alternatively, an organic compound having a high carrier-transport property is provided. Alternatively, an organic compound with favorable reliability is provided. An organic compound having at least one amino group in which any one of a substituted or unsubstituted dibenzofuranyl group, a substituted or unsubstituted dibenzothiophenyl group, and a substituted or unsubstituted carbazolyl group is bonded to any one of a substituted or unsubstituted naphthobisbenzofuran skeleton, a substituted or unsubstituted naphthobisbenzothiophene skeleton, and a substituted or unsubstituted naphthobenzothienobenzofuran skeleton is provided.

  提供了一种新型有机化合物。或者提供一种表现出有利色度的光发射的有机化合物。或者提供一种表现出有利色度的蓝光发射的有机化合物。或者提供一种具有良好发射效率的发光装置。或者提供一种具有高载流子传输性能的有机化合物。或者提供一种具有良好可靠性的有机化合物。提供了一种有机化合物，其中任何一种取代或未取代的二苯并呋喃基团，取代或未取代的二苯并噻吩基团和取代或未取代的咔唑基团中的至少一个氨基与取代或未取代的萘并苯并呋喃骨架、取代或未取代的萘并苯并噻吩骨架和取代或未取代的萘苯并噻吩苯并呋喃骨架中的任何一个键合。
• Substituted benzonaphthathiophene compounds for organic electronics
  申请人：Clap Co., Ltd.

  公开号：US11355715B2

  公开（公告）日：2022-06-07

  The present invention provides compounds of formulae (1) (2) wherein R1 and R2 are C1-30alkyl, C2-3O-alkenyl, C2-30-alkynyl, C5-7-cycloalkyl, C6-14-aryl or 5 to 14 membered heteroaryl, wherein C1-30-alkyl, C2-3O-alkenyl and C2-3O-alkynyl can be substituted with one or more substituents selected from the group consisting of halogen, phenyl, O—C1-20-alkyl, O—C2-20-alkenyl and O—C2-2O-alkynyl, and wherein C5-7-cycloalkyl, C6-14-aryl and 5 to 14 membered heteroaryl can be substituted with one or more substituents selected from the group consisting of halogen, C1-20alkyl, C2-2O-alkenyl, C2-2O-alkynyl, O—C1-20-alkyl, O—C2-2o-alkenyl and O—C2-2o-alkynyl, Ra, Rb, Rc and Rd are independently and at each occurrence selected from the group consisting of C1-30alkyl, C2-30-alkenyl, C2-30-alkynyl, C6-14-aryl and 5 to 14 membered heteroaryl, wherein C1-30-alkyl, C2-3o-alkenyl and C2-3o-alkynyl can be substituted with one or more substituents selected from the group consisting of halogen, phenyl, O—C1-20-alkyl, O—C2-20-alkenyl and O—C2-20-alkynyl, and wherein C5-7-cycloalkyl, C6-14-aryl and 5 to 14 membered heteroaryl can be substituted with one or more substituents selected from the group consisting of halogen, C1-20alkyl, C2-2o-alkenyl, C2-20-alkynyl, O—C1-20-alkyl, O—C2-20-alkenyl and O—C2-2o-alkynyl, n and o are independently 0, 1, 2, 3, 4 or 5, and m and p are independently 0, 1, 2 or 3, and to electronic device comprising the compounds of formulae 1 or 2.

  本发明提供了式(1)(2)化合物，其中 R1 和 R2 是 C1-30-烷基、C2-3O-烯基、C2-30-炔基、C5-7-环烷基、C6-14-芳基或 5 至 14 个成员的杂芳基，其中 C1-30-烷基、C2-3O-烯基和 C2-3O-炔基可以被一个或多个选自卤素、苯基、O-C1-20-烷基、O-C2-20-烯基和 O-C2-2O-alkynyl 组成的组的取代基取代、其中，C5-7-环烷基、C6-14-芳基和 5-14 位杂芳基可被一个或多个选自卤素、C1-20-烷基、C2-2O-烯基、C2-2O-炔基、O-C1-20-烷基、O-C2-2-烯基和 O-C2-2-炔基组成的组的取代基取代、C2-30-烯基、C2-30-炔基、C6-14-芳基和 5-14 位杂芳基组成的组，其中 C1-30- 烷基、C2-3-烯基和 C2-3o- 烷炔基可被一个或多个选自卤素、苯基、O-C1-20-烷基、O-C2-20-烯基和 O-C2-20-炔基组成的组的取代基取代，且其中 C5-7-Cycloalkyl、C1-20-烷基、C2-2-烯基、C2-20-炔基、O-C1-20-烷基、O-C2-20-烯基和 O-C2-2-炔基组成的组中，n 和 o 独立地为 0、1、2、3、4 或 5，m 和 p 独立地为 0、1、2 或 3。
• Pratap, Ram; Tominaga, Yoshinori; Castle, Raymond N., Journal of Heterocyclic Chemistry, 1982, vol. 19, p. 865 - 869
  作者：Pratap, Ram、Tominaga, Yoshinori、Castle, Raymond N.、Lee, Milton L.

  DOI：——

  日期：——