Polymer scale preventive agent, polymerization vessel for preventing polymer scale deposition, and process of producing polymer using said vessel
申请人:SHIN-ETSU CHEMICAL CO., LTD.
公开号:EP0482593A1
公开(公告)日:1992-04-29
A polymer scale preventive agent for use in polymerization of a monomer having an ethylenic double bond, comprising (A) a nitrogen-containing organic compound having at least five continuous conjugated π bonds, (B) an anionic organic compound having at least one group selected from the group consisting of the sulfonic acid group and the carboxylic group and having at least five continuous conjugated π bonds, and (C) a vinylpyrrolidone-based polymer. The agent is used for forming a coating on the inner wall, etc. of a polymerization vessel. Deposition of polymer scale can be effectively prevented not only in the liquid phase area but also in the vicinity of the interface between the gas and liquid phases. Products formed from polymer obtained have very few fish eyes.
一种聚合物防垢剂,用于具有乙烯双键的单体的聚合,包括:(A) 至少具有五个连续共轭 π 键的含氮有机化合物;(B) 至少具有一个从磺酸基和羧酸基组成的组中选出的基团且至少具有五个连续共轭 π 键的阴离子有机化合物;以及 (C) 乙烯基吡咯烷酮基聚合物。该剂用于在聚合容器的内壁等处形成涂层。不仅在液相区域,而且在气相和液相界面附近都能有效防止聚合物垢的沉积。由聚合物形成的产品很少有鱼眼。