萘-1-基丁-3-烯酸酯 | 93359-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 萘-1-基丁-3-烯酸酯
• 英文名称: Naphthalen-1-yl but-3-enoate
• CAS: 93359-76-3
• 化学式: C₁₄H₁₂O₂
• 分子量: 212.248
• InChiKey: ZZKWNQXKZTWETE-UHFFFAOYSA-N

物化性质

• 沸点：
  350.7±21.0 °C(Predicted)
• 密度：
  1.121±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  萘-1-基丁-3-烯酸酯 以 异辛烷 为溶剂， 生成 萘酚
  参考文献：
  名称：

  萘-乙烯基非共轭双发色体系的光化学反应

  摘要：

  2-（1-萘基）乙基乙烯基醚经历分子内1,2-光环加成，而2-萘基异构体产生的产物反映二聚化和乙炔元素的损失：与这种多样的光化学相一致，添加了2,3-二氢吡喃萘仅产生1，2-，1'，2'区域异构体。

  DOI：

  10.1016/s0040-4039(01)81322-8

文献信息

• Method for production of carbon black graft polymer
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0749991A2

  公开（公告）日：1996-12-27

  A method for the production of a carbon black graft polymer by the reaction of carbon black and a polymer (A) having an epoxy group and/or a thioepoxy group, which method is characterized by the fact that the reaction of carbon black and the polymer (A) is carried out by means of a continuous kneading device and the polymer (A) fed to the continuous kneading device is in such a state that the effective pendant number (Peff) represented by the following formula falls in the range of 0.5 ∼ 1.3 per moleculePeff = Mn/(E - Ac) (wherein Mn represents the number average molecular weight of the polymer (A), E the number or mols of the epoxy group and/or the thioepoxy group per g of the polymer (A), and Ac the number of mols of the epoxy- or thioepoxy-reactive group per g off the polymer (A)).

  一种通过炭黑与具有环氧基和/或硫代环氧基的聚合物（A）反应生产炭黑接枝聚合物的方法，其特征在于炭黑与聚合物（A）的反应是通过连续捏合装置进行的，加入连续捏合装置的聚合物（A）处于如下状态，即由下式表示的有效悬垂数（Peff）在每分子 0.Peff = Mn/(E - Ac) (其中 Mn 代表聚合物（A）的平均分子量，E 代表每克聚合物（A）中环氧基和/或硫代环氧基的摩尔数，Ac 代表每克聚合物（A）中环氧基或硫代环氧基反应基的摩尔数）。
• LUBRICANT COMPOSITION AND ANTIOXIDANT COMPOSITION
  申请人：Nippon Oil Corporation

  公开号：EP1803799A1

  公开（公告）日：2007-07-04

  The lubricating oil composition of the present invention comprises at least one species of aromatic constituent selected from the following (a1) to (a5): (a1) a lubricating base oil comprising a polycyclic aromatic content of 0.01 % by mass or more based on the total amount of base oil (a2) a lubricating base oil comprising a total aromatic content of 20 to 100 % by mass based on the total amount of base oil (a3) an aromatic solvent (a4) at least one species of polycyclic aromatic compound selected from alkyl naphthalene and compounds having three or more aromatic rings, and (a5) an aromatic compound having a nitrogen atom, an oxygen atom or a sulfur atom; and an organic molybdenum compound.

  本发明的润滑油组合物包含至少一种选自以下(a1)至(a5)的芳香族成分： (a1) 润滑油基础油，其多环芳烃含量为基础油总量的 0.01%（质量百分比）或更 高 (a2) 总芳烃含量为 20%至 100%（以基础油总量计）的润滑基础油 (a3) 一种芳香族溶剂 (a4) 至少一种多环芳烃化合物，选自烷基萘和具有三个或三个以上芳香环的化合物， 以及 (a5) 具有一个氮原子、一个氧原子或一个硫原子的芳香族化合物； 和一种有机钼化合物。
• LUBRICANT COMPOSITION
  申请人：Nippon Oil Corporation

  公开号：EP1820840A1

  公开（公告）日：2007-08-22

  The lubricating oil composition of the present invention comprises a base oil for lubricating oil, (A) at least one species selected from the phosphorus compounds represented by the following General Formula (1) or (2) as well as metal salts (excluding molybdenum salts) and amine salts thereof, and (B) an organic molybdenum compound not containing sulfur as a constituent element (in the formula, R1 and R4 represent hydrocarbon groups having 1 to 30 carbons, R2, R3, R5 and R6 represent hydrogen atoms or hydrocarbon groups having 1 to 30 carbons, X1 to X7 represent oxygen atoms or sulfur atoms, and n represents 0 or 1).

  本发明的润滑油组合物包括润滑油基础油、(A) 至少一种选自以下通式(1)或(2)所代表的磷化合物及其金属盐（不包括钼盐）和胺盐、(B) 不以硫为组成元素的有机钼化合物（式中，R1 和 R4 代表碳原子数为 1 至 30 的烃基，R2、R3、R5 和 R6 代表氢原子或碳原子数为 1 至 30 的烃基，X1 至 X7 代表氧原子或硫原子，n 代表 0 或 1）。
• LUBRICATING OIL COMPOSITION
  申请人：Nippon Oil Corporation

  公开号：EP1835013A1

  公开（公告）日：2007-09-19

  The present invention provide a lubricant composition comprising a lubricant base oil, wherein said lubricant composition contains 0.08% by mass or less of zinc dithiophosphate or no zinc dithiophosphate as phosphorus amount for total amount of said lubricant composition, contacts metallic materials containing lead, and contains at least a kind of additive selected from a group consisting of following (A) ~ (D) : (A) organomolybdenum compounds (except molybdenum dithiophosphate); (B) borate ester and/or derivatives thereof; (C) organomolybdenum compounds, and borate ester and/or derivatives thereof; and (D) organomolybdenum compounds, and borated alkyl or alkenyl succinimide.

  本发明提供一种润滑油组合物，包括润滑油基础油，其中所述润滑油组合物含有质量分数为0.08%或以下的二硫代磷酸锌或不含磷量为所述润滑油组合物总量的二硫代磷酸锌，接触含铅的金属材料，并含有至少一种选自以下(A)～(D)组成的组的添加剂： (A) 有机钼化合物（二硫代磷酸钼除外）； (B) 硼酸酯及／或其衍生物 (C) 有機鉬化合物及硼酸酯及／或其衍生物；及 (D) 有机钼化合物和硼化烷基或烯基琥珀酰亚胺。
• Catalytic decarboxylative cross-ketonisation of aryl- and alkylcarboxylic acids using iron catalysts
  申请人：Cognis IP Management GmbH

  公开号：EP2468708B1

  公开（公告）日：2016-11-09